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1.
Dr. Carla Carrera Dr. Eleonora Cavallari Dr. Giuseppe Digilio Dr. Oksana Bondar Prof. Silvio Aime Dr. Francesca Reineri 《Chemphyschem》2021,22(11):1042-1048
An efficient synthesis of vinyl-[1-13C]pyruvate has been reported, from which 13C hyperpolarized (HP) ethyl-[1-13C]pyruvate has been obtained by means of ParaHydrogen Induced Polarization (PHIP). Due to the intrinsic lability of pyruvate, which leads quickly to degradation of the reaction mixture even under mild reaction conditions, the vinyl-ester has been synthesized through the intermediacy of a more stable ketal derivative. 13C and 1H hyperpolarizations of ethyl-[1-13C]pyruvate, hydrogenated using ParaHydrogen, have been compared to those observed on the more widely used allyl-derivative. It has been demonstrated that the spin order transfer from ParaHydrogen protons to 13C, is more efficient on the ethyl than on the allyl-esterdue to the larger J-couplings involved. The main requirements needed for the biological application of this HP product have been met, i. e. an aqueous solution of the product at high concentration (40 mM) with a good 13C polarization level (4.8 %) has been obtained. The in vitro metabolic transformation of the HP ethyl-[1-13C]pyruvate, catalyzed by an esterase, has been observed. This substrate appears to be a good candidate for in vivo metabolic investigations using PHIP hyperpolarized probes. 相似文献
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Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis
Dr. Damien Dambournet Dr. Karena W Chapman Dr. Mathieu Duttine Dr. Olaf Borkiewicz Dr. Peter J Chupas Dr. Henri Groult 《ChemistryOpen》2015,4(4):443-447
The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties. 相似文献
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Experimental dependences of the doubly charged ion yield N 2+ on the laser radiation intensity F are analyzed for the case of ion formation by the two-electron mechanism. It is shown that the region where the dependence N 2+(F) is characterized by the degree of nonlinearity K≈2.5 corresponds to the saturation of the process of doubly charged ion formation. This region is described well by theoretical calculations performed for Gaussian laser beams. 相似文献
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A. E. Blinov V. E. Blinov A. E. Bondar A. D. Bukin V. R. Groshev S. G. Klimenko G. M. Kolachev A. P. Onuchin V. S. Panin I. Ya. Protopopov A. G. Shamov V. A. Sidorov Yu. I. Skovpen A. N. Skrinsky V. A. Tayursky V. I. Telnov Yu. A. Tikhonov G. M. Tumaikin A. E. Undrus A. I. Vorobiov V. N. Zhilich 《Zeitschrift fur Physik C Particles and Fields》1992,53(1):33-39
The process γγ→π+π? was measured using the detector MD-1 at VEPP-4. The two-photon reactionse + e ?, μ+ μ? and π+ π? pair production were separated using scintillation counters, Cherenkov counters and shower-range chambers. A radiation widthГ γγ(f 2(1270))=3.1±0.35±0.35 keV was obtained. 相似文献
7.
Labour scheduling plays an important and critical role in Sainsburys day to day operations and profitability. The integrated
workforce management solution for Sainsburys is an intelligent solution for the operational deployment of human resources,
integrated business forecasting, generation and calculation of workload and staff scheduling. The workforce management technology
has provided Sainsburys with a fully web-based and centralised system that produces optimised schedules for all employees
satisfying the forecasted demand of work with granularity of fifteen minutes. The system is configured to respect all operational
and business requirements as well as employee contractual constraints. This paper introduces the workforce management solution
system designed, developed and implemented for Sainsburys. We concentrate on two modelling structures, namely the work pattern
model and optimisation model, and briefly discuss the optimisation process. 相似文献
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