全文获取类型
收费全文 | 4295篇 |
免费 | 79篇 |
国内免费 | 17篇 |
专业分类
化学 | 2956篇 |
晶体学 | 20篇 |
力学 | 72篇 |
数学 | 946篇 |
物理学 | 397篇 |
出版年
2019年 | 41篇 |
2016年 | 73篇 |
2015年 | 52篇 |
2014年 | 37篇 |
2013年 | 117篇 |
2012年 | 94篇 |
2011年 | 144篇 |
2010年 | 106篇 |
2009年 | 126篇 |
2008年 | 149篇 |
2007年 | 146篇 |
2006年 | 161篇 |
2005年 | 141篇 |
2004年 | 112篇 |
2003年 | 112篇 |
2002年 | 108篇 |
2001年 | 31篇 |
2000年 | 32篇 |
1999年 | 32篇 |
1998年 | 34篇 |
1997年 | 42篇 |
1996年 | 61篇 |
1995年 | 77篇 |
1994年 | 50篇 |
1993年 | 68篇 |
1992年 | 92篇 |
1991年 | 90篇 |
1990年 | 77篇 |
1989年 | 67篇 |
1988年 | 61篇 |
1987年 | 61篇 |
1986年 | 60篇 |
1985年 | 80篇 |
1984年 | 91篇 |
1983年 | 79篇 |
1982年 | 77篇 |
1981年 | 105篇 |
1980年 | 60篇 |
1979年 | 77篇 |
1978年 | 72篇 |
1977年 | 94篇 |
1976年 | 65篇 |
1975年 | 82篇 |
1974年 | 85篇 |
1973年 | 66篇 |
1972年 | 53篇 |
1971年 | 48篇 |
1970年 | 39篇 |
1966年 | 29篇 |
1962年 | 29篇 |
排序方式: 共有4391条查询结果,搜索用时 187 毫秒
1.
2.
3.
4.
Dr. Julian Brunner Britta Maier Rose Rosenberg Sebastian Sturm Prof. Dr. Helmut Cölfen Dr. Elena V. Sturm 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(66):15242-15248
Applications in the fields of materials science and nanotechnology increasingly demand monodisperse nanoparticles in size and shape. Up to now, no general purification procedure exists to thoroughly narrow the size and shape distributions of nanoparticles. Here, we show by analytical ultracentrifugation (AUC) as an absolute and quantitative high-resolution method that multiple recrystallizations of nanocrystals to mesocrystals is a very efficient tool to generate nanocrystals with an excellent and so-far unsurpassed size-distribution (PDIc=1.0001) and shape. Similar to the crystallization of molecular building blocks, nonclassical recrystallization removes “colloidal” impurities (i.e., nanoparticles, which are different in shape and size from the majority) by assembling them into a mesocrystal. In the case of nanocrystals, this assembly can be size- and shape-selective, since mesocrystals show both long-range packing ordering and preferable crystallographic orientation of nanocrystals. Besides the generation of highly monodisperse nanoparticles, these findings provide highly relevant insights into the crystallization of mesocrystals. 相似文献
5.
Martin Zacharias 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(18):6028-6033
Sac7d is a small, thermostable protein that induces large helical deformations in DNA upon association. Starting from multiple initial placements of the unbound Sac7d structure relative to a B‐DNA oligonucleotide, molecular dynamics (MD) simulations were employed to directly follow several successful binding events at atomic resolution that resulted in structures in close agreement with the native complex geometry. The final native complex formed rapidly within tenths of nanoseconds and included simultaneous large‐scale kinking, groove opening, twisting, and intercalation in the target DNA. The simulations indicate that the complex formation process involves initial non‐native contacts that helped in reaching the final bound state, with residues intercalated at the center of the kinked DNA. It was also possible to identify several long‐lived trapped intermediate states of the binding process and to follow sliding processes of Sac7d along the DNA minor groove. 相似文献
6.
Dr. Mathias Paul Eric Detmar Dr. Maria Schlangen Dr. Martin Breugst Dr. Jörg-Martin Neudörfl Prof. Dr. Dr. Helmut Schwarz Prof. Dr. Albrecht Berkessel Prof. Dr. Mathias Schäfer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(10):2511-2518
N-Heterocyclic carbenes (NHCs, :C ) can interact with azolium salts ( C−H+ ) by either forming a hydrogen-bonded aggregate ( CHC+ ) or a covalent C−C bond ( CCH+ ). In this study, the intramolecular NHC–azolium salt interactions of aromatic imidazolin-2-ylidenes and saturated imidazolidin-2-ylidenes have been investigated in the gas phase by traveling wave ion mobility mass spectrometry (TW IMS) and DFT calculations. The TW IMS experiments provided evidence for the formation of these important intermediates in the gas phase, and they identified the predominant aggregation mode (hydrogen bond vs. covalent C−C) as a function of the nature of the interacting carbene–azolium pairs. 相似文献
7.
8.
9.
Dual stimuli‐responsive polyamines derived from modified N‐vinylpyrrolidones through CuAAC click chemistry 下载免费PDF全文
Anselmo del Prado Rodrigo Navarro Pavel Levkin Alberto Gallardo Carlos Elvira Helmut Reinecke 《Journal of polymer science. Part A, Polymer chemistry》2016,54(8):1098-1108
The synthesis via copper(I)‐catalyzed azide alkyne cycloaddition (CuAAC) of three new monomer derivatives of N‐vinyl‐2‐pyrrolidone (VP) carrying cyclic pyrrolidine, piperidine, and piperazine groups and the corresponding copolymers with unmodified VP is shown. The systems bearing pyrrolidine and piperidine displayed both thermo‐ and pH‐response, which has not been reported previously for a polymer with polyvinylpyrrolidone (PVP) backbone. A broad modulation of the LCST with the copolymer composition and pH was observed in a temperature range 0–100 °C. The polymers carrying piperazine exhibited broad buffering regions and no thermosensitivity. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1098–1108 相似文献
10.