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排序方式: 共有173条查询结果,搜索用时 140 毫秒
1.
Bulk superconducting samples of type Tl0.5Pb0.5Sr1.6Ba0.4CaCu2−x
Ru
x
O7−δ, (Tl, Pb)/Sr-1212, with 0.0 ≤ x ≤ 0.525 were prepared by the conventional one-step solid-state reaction technique. The prepared samples were investigated
using X-ray powder diffraction, electrical resistivity and electron paramagnetic resonance (EPR) measurements. Enhancement
of the phase formation, superconducting transition temperature T
c and hole carriers concentration P was observed up to x = 0.075. For x > 0.075, a reverse trend was observed. EPR spectra were measured at different temperatures (120–290 K) for all prepared samples.
The number of spins N participating in the resonance and the paramagnetic susceptibility χ were calculated as a function of both Ru-content and
temperature. N and χ increased as the Ru-content increased. A linear relationship between logN and 1/T was established, from which the activation energy E
a was calculated as a function of the Ru-content. The temperature dependence of χ was fitted according to Curie–Weiss type
of magnetic behavior. Curie constant C, Curie temperature θ, the effective magnetic moment μ and the electronic specific heat γ were estimated as a function of the Ru-content. 相似文献
2.
Rodion Yu. IliashenkoNikolay Yu. Gorobets Andrey O. Doroshenko 《Tetrahedron letters》2011,52(39):5086-5089
Two new unsymmetric derivatives of 1,2-bis-(5-phenyloxazol-2-yl)benzene (ortho-POPOP) were synthesized via microwave-assisted nucleophilic substitution of fluorine which appears to be significantly more efficient compared with conventional thermal activation. The compounds synthesized are characterized by high fluorescence Stokes shifts (6000-11,000 cm−1) in solvents of various polarity, intermediate-to-high fluorescence quantum yields and lifetimes in the range of several nanoseconds. 相似文献
3.
4.
Published data and the author's own results on the creation of organic luminophores with anomalously high fluorescence Stokes' shifts are reviewed. 相似文献
5.
6.
Denis A. Svechkarev Ilya V. Bukatich Andrey O. Doroshenko 《Journal of photochemistry and photobiology. A, Chemistry》2008,200(2-3):426-431
Two novel 1,3,5-triphenyl-2-pyrazoline moiety containing derivatives of 3-hydroxychromone were synthesized and studied by 1H NMR, absorption and fluorescence spectroscopy. The prospects of practical application of these compounds exhibiting high solvatofluorochromism into analytical chemistry and biophysics as effective ratiometric polarity probes were discussed proceeding from the data on their fluorescent properties. 相似文献
7.
Sanzhizhapov D. B. Tonevitskii Yu. V. Mognonov D. M. Doroshenko Yu. E. 《Russian Journal of Applied Chemistry》2003,76(4):619-622
New polyimidates were prepared from bisphenols and mono- and dicarboxylic acid imidoyl chlorides. The structures of the polymers were determined, and their physicochemical, chemical, and thermal properties were studied. The possibility of preparing film and compression materials with good mechanical characteristics from these polymers was examined. 相似文献
8.
T. A. Podrugina A. S. Pavlova I. A. Doroshenko V. A. Kuz’min A. A. Kostyukov A. A. Shtil’ 《Russian Chemical Bulletin》2018,67(5):806-814
A method for the synthesis of a series of symmetric and asymmetric conformationally fixed tricarbocyanines was developed based on benzоindolenine containing ethyl phosphonate and diethyl phosphonate groups in the linker at the quaternary nitrogen atom of the indolenine fragment. The polymethine chain meso position was modified by nucleophilic substitution of chlorine with O- and N-nucleophiles. Their absorption and fluorescence spectra were recorded, the possibility of further use of phosphonate-substituted tricarbocyanines as biomarkers was demonstrated. The dark cytotoxicity of synthesized compounds was studied, the possibility of their accumulation in HCT116, MCF7 cancer cells was shown. 相似文献
9.
A. D. Avrorin A. V. Avrorin V. M. Aynutdinov R. Bannash I. A. Belolaptikov D. Yu. Bogorodsky V. B. Brudanin N. M. Budnev A. R. Gafarov O. N. Gaponenko K. V. Golubkov T. I. Gress I. A. Danilchenko Zh. -A. M. Dzhilkibaev G. V. Domogatsky A. A. Doroshenko A. N. Dyachok V. A. Zhukov A. V. Zagorodnikov V. L. Zurbanov K. G. Kebkal O. G. Kebkal A. V. Kozhin K. V. Konischev A. V. Korobchenko F. K. Koshel A. P. Koshechkin V. F. Kulepov D. A. Kuleshov V. I. Ljashuk M. B. Milenin R. A. Mirgazov E. R. Osipova A. I. Panfilov L. V. Pan’kov E. N. Pliskovsky M. I. Rozanov E. V. Rjabov A. V. Skurihin A. A. Smagina O. V. Suvorova V. A. Tabolenko B. A. Tarashansky S. V. Fialkovsky Z. Honz B. A. Shaybonov A. A. Sheifler M. D. Shelepov S. A. Yakovlev 《Physics of Particles and Nuclei Letters》2016,13(6):737-746
In April 2015, the first cluster of Baikal-GVD was deployed in Lake Baikal and put into operation. It comprises eight strings. Each string consists of 24 optical modules. An optical module is a detection element of Baikal-GVD; it includes a Hamamatsu R7081-100 photomultiplier tube with a high quantum sensitivity. We describe the design of the optical module, the front-end electronics, and the laboratory characterization and calibration. 相似文献
10.