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Achieving precise control over the synthesis and properties of porous nanostructured materials has been garnering considerable recent research attention. In the work presented here, nickel oxalate nanostructures with controllable shapes were synthesized through a simple and facile wet-chemistry route without any surfactant. An interesting shape evolution process from 2D nanoflakes to 1D nanorods has been illustrated on the basis of time-dependent experimental studies. Subsequent calcination at 380 °C yielded porous NiO nanostructures that retained the morphologies of their predecessors. The phase composition, morphology, and structure of the as-obtained products were studied by various tools. Electrochemical properties of the NiO electrodes were carried out using cyclic voltammetry and galvanostatic charge–discharge measurements by a three-electrode system. Electrochemical studies reveal that the as-prepared mesoporous NiO nanostructures have good specific capacitance and exhibit excellent capacity retention for more than 1,000 cycles due to its porous character and morphology. The results suggest that mesoporous NiO nanostructures are a promising supercapacitor electrode material. 相似文献
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Nanoflakes-built pyrite FeS2 microspheres were synthesized through a simple solvothermal process in mixed solvents of N, N-dimethytformamide and ethylene
glycol without using any surfactant. Both the composition of the solvents and urea were key factors for the formation of the
uniform products. It was found that the flake-like intermediate products transformed into FeS2 nanoflakes in situ in the early stage and Ostwald ripening growth mechanism would contribute to the uniformity of the final
products. Electrochemical studies revealed that the nanoflakes-built pyrite FeS2 microspheres exhibited large lithium storage capacities. This method can be easily controlled and is expected to be extendable
to the fabrication of other metal chalcogenides with controlled shape and structure. 相似文献
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