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排序方式: 共有102条查询结果,搜索用时 31 毫秒
1.
Devin Kilminster David Allingham Alistair Mees 《Annals of the Institute of Statistical Mathematics》2002,54(1):224-233
Knowing a probability density (ideally, an invariant density) for the trajectories of a dynamical system allows many significant estimates to be made, from the well-known dynamical invariants such as Lyapunov exponents and mutual information to conditional probabilities which are potentially more suitable for prediction than the single number produced by most predictors. Densities on typical attractors have properties, such as singularity with respect to Lebesgue measure, which make standard density estimators less useful than one would hope. In this paper we present a new method of estimating densities which can smooth in a way that tends to preserve fractal structure down to some level, and that also maintains invariance. We demonstrate with applications to real and artificial data. 相似文献
2.
The Xe nuclear magnetic resonance chemical shift differences that afford the discrimination between various biological environments are of current interest for biosensor applications and medical diagnostic purposes. In many such environments the Xe signal appears close to that in water. We calculate average Xe chemical shifts (relative to the free Xe atom) in solution in eleven liquids: water, isobutane, perfluoro-isobutane, n-butane, n-pentane, neopentane, perfluoroneopentane, n-hexane, n-octane, n-perfluorooctane, and perfluorooctyl bromide. The latter is a liquid used for intravenous Xe delivery. We calculate quantum mechanically the Xe shielding response in Xe-molecule van der Waals complexes, from which calculations we develop Xe (atomic site) interpolating functions that reproduce the ab initio Xe shielding response in the complex. By assuming additivity, these Xe-site shielding functions can be used to calculate the shielding for any configuration of such molecules around Xe. The averaging over configurations is done via molecular dynamics (MD). The simulations were carried out using a MD technique that one of us had developed previously for the simulation of Henry's constants of gases dissolved in liquids. It is based on separating a gaseous compartment in the MD system from the solvent using a semipermeable membrane that is permeable only to the gas molecules. We reproduce the experimental trends in the Xe chemical shifts in n-alkanes with increasing number of carbons and the large chemical shift difference between Xe in water and in perfluorooctyl bromide. We also reproduce the trend for a given solvent of decreasing Xe chemical shift with increasing temperature. We predict chemical shift differences between Xe in alkanes vs their perfluoro counterparts. 相似文献
3.
Pyrolysis—mass spectrometry (Py—MS) as a taxonomic tool was applied to a series of atmospheric particulate samples. Seven pure and mixed source samples were individually pyrolyzed at 450°C directly into a mass spectrometer. The resulting spectra were summed and analyzed using an Euclidian Distance calculated from an n-dimensional array of peak intensity values weighted utilizing a Fisher ratioing procedure. The results of this study indicate that Py—MS can be used to distinguish various atmospheric particulate sources. 相似文献
4.
The reaction between hydroxylamine and cyclohexanedione in the presence of palladium ions has been made the basis of the precipitation of bis(1,2-cyclohexanedionedioximato)palladium(II) from homogeneous solution. The procedure provides a means of separating palladium from Cu(II), Co(II), Ni(II) and Pt(IV), and is a simple, rapid and accurate method for determining palladium. 相似文献
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6.
This paper describes a method for nickel catalyzed intramolecular C–H arylation using aryl pivalates as electrophiles. The transformation is efficient for the synthesis of diverse electronically and sterically differentiated dibenzofurans. Additionally, the method could be expanded toward the synthesis of carbazoles. Preliminary mechanistic studies of the transformation are also described. 相似文献
7.
Constructions for Terraces and R‐Sequencings,Including a Proof That Bailey's Conjecture Holds for Abelian Groups 下载免费PDF全文
Every abelian group of even order with a noncyclic Sylow 2‐subgroup is known to be R‐sequenceable except possibly when the Sylow 2‐subgroup has order 8. We construct an R‐sequencing for many groups with elementary abelian Sylow 2‐subgroups of order 8 and use this to show that all such groups of order other than 8 also have terraces. This completes the proof of Bailey's Conjecture in the abelian case: all abelian groups other than the noncyclic elementary abelian 2‐groups have terraces. For odd orders it is known that abelian groups are R‐sequenceable except possibly those with noncyclic Sylow 3‐subgroups. We show how the theory of narcissistic terraces can be exploited to find R‐sequencings for many such groups, including infinitely many groups with each possible of Sylow 3‐subgroup type of exponent at most 312 and all groups whose Sylow 3‐subgroups are of the form or . 相似文献
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9.
We investigate the odd and even character of the shielding response in a chiral molecule (modeled by a Ne8 helix) when subjected to a chiral potential. We establish that the diastereomeric splittings are a measure of odd powers of Vodd. Implications for diastereomeric, splittings of Xe in handed cages with handed tethers are discussed. 相似文献
10.
Carolyn Ferguson Steven L Hardy David F Werner Stanley M Hileman Timothy M DeLorey Gregg E Homanics 《BMC neuroscience》2007,8(1):85