Four-Step Spin Crossover in a New Cyano-Bridged Iron-Silver Coordination Polymer

Spin-crossover complexes with multistep transitions attract much attention due to their potential applications as multi-switches and for data storage. A four-step spin crossover is observed in the new iron(II)-based cyanometallic guest-free framework compound Fe(2-ethoxypyrazine)₂{Ag(CN)₂}₂ during the transition from the low-spin to the high-spin state. A reverse process occurs in three steps. Crystallographic studies reveal an associated stepwise evolution of the crystal structures. Multiple transitions in the reported complex originate from distinct Fe^II sites which exist due to the packing of the ligand with a bulky substituent.     

Low- and high-energy solutions of nonlinear elliptic oscillatory problems

In this Note, we study the existence of low- or high-energy solutions for a class of elliptic problems containing a nonlinear term that oscillates either near the origin or at infinity. We point out the competition effect between the oscillatory nonlinearity, a polynomial growth term, and the values of a real parameter. The proofs combine related variational methods.     

Nonhomogeneous Hemivariational Inequalities with Indefinite Potential and Robin Boundary Condition

We consider a nonlinear, nonhomogeneous Robin problem with an indefinite potential and a nonsmooth primitive in the reaction term. In fact, the right-hand side of the problem (reaction term) is the Clarke subdifferential of a locally Lipschitz integrand. We assume that asymptotically this term is resonant with respect the principal eigenvalue (from the left). We prove the existence of three nontrivial smooth solutions, two of constant sign and the third nodal. We also show the existence of extremal constant sign solutions. The tools come from nonsmooth critical point theory and from global optimization (direct method).     

A sharp eigenvalue theorem for fractional elliptic equations

The invisibility graph I(X) of a set X ? R ^d is a (possibly infinite) graph whose vertices are the points of X and two vertices are connected by an edge if and only if the straight-line segment connecting the two corresponding points is not fully contained in X. We consider the following three parameters of a set X: the clique number ω(I(X)), the chromatic number χ(I(X)) and the convexity number γ(X), which is the minimum number of convex subsets of X that cover X.We settle a conjecture of Matou?ek and Valtr claiming that for every planar set X, γ(X) can be bounded in terms of χ(I(X)). As a part of the proof we show that a disc with n one-point holes near its boundary has χ(I(X)) ≥ log log(n) but ω(I(X)) = 3.We also find sets X in R⁵ with χ(X) = 2, but γ(X) arbitrarily large.     

Synthesis,characterization of nanosized CoAl<Subscript>2</Subscript>O<Subscript>4</Subscript> and its electrocatalytic activity for enhanced sensing application

Nanosized cobalt aluminate (CoAl₂O₄) was prepared by thermolysis of heteronuclear coordination compound, namely [Al₂Co(C₂O₄)₄(OH₂)₆]. The synthesized precursor was characterized by chemical analysis, vibrational spectra and thermal analysis. The cobalt aluminate obtained after a heating treatment of the precursor at 700 °C was characterized by IR, XRD, TEM coupled with SAED measurements. Two types of carbon-based electrodes, glassy carbon and boron-doped diamond electrodes were decorated with the obtained cobalt aluminate in order to enhance the electroanalytical performance for the tetracycline (TC) detection in the aqueous solutions. Cyclic voltammetry technique was used to determine the effect of the nanosized CoAl₂O₄ on the electrochemical oxidation of TC and as consequence, for TC detection at both carbon-based electrodes. The obtained cobalt aluminate exhibited the electrocatalytic activity toward TC detection in direct relation with the type of the carbon substrate, which allowed enhancing the electroanalytical parameters of TC detection in the aqueous solution.     

Abelian and Tauberian results for the one-dimensional modified Stockwell transforms

The aim of this paper is to study the asymptotic behavior of one- dimensional modified Stockwell transform of a tempered distribution signal through the quasiasymptotic behavior at origin or infinity of the signal itself. More precisely, we give some Abelian results which mean that we derive the asymptotic properties of the S-transform of a tempered signal from the quasiasymptotic properties of the signal itself and we do also the opposite. So, we also give some Tauberian results which describe some quasiasymptotic properties of the tempered signal by means of the asymptotic properties of its Stockwell transform.     

Resolvent estimates and smoothing for homogeneous partial differential operators on graded Lie groups

By using commutator methods, we show uniform resolvent estimates and obtain globally smooth operators for self-adjoint injective homogeneous operators H on graded groups, including Rockland operators, sublaplacians, and many others. Left or right invariance is not required. Typically the globally smooth operator has the form T = V|H|^1∕2, where V only depends on the homogeneous structure of the group through Sobolev spaces, the homogeneous dimension and the minimal and maximal dilation weights. For stratified groups improvements are obtained, by using a Hardy-type inequality. Some of the results involve refined estimates in terms of real interpolation spaces and are valid in an abstract setting. Even for the commutative group ?^N some new classes of partial differential operators are treated.     

On a rigidity result of singularities

The aim of this note is to prove, in the spirit of a rigidity result for isolated singularities of Schlessinger see Schlessinger (Invent Math 14:17–26, 1971) or also Kleiman and Landolfi (Compositio Math 23:407–434, 1971), a variant of a rigidity criterion for arbitrary singularities (Theorem 2.1 below). The proof of this result does not use Schlessinger’s Deformation Theory [Schlessinger (Trans Am Math Soc 130:208–222, 1968) and Schlessinger (Invent Math 14:17–26, 1971)]. Instead it makes use of Local Grothendieck-Lefschetz Theory, see (Grothendieck 1968, Éxposé 9, Proposition 1.4, page 106) and a Lemma of Zariski, see (Zariski, Am J Math 87:507–536, 1965, Lemma 4, page 526). I hope that this proof, although works only in characteristic zero, might also have some interest in its own.