全文获取类型
收费全文 | 525篇 |
免费 | 23篇 |
专业分类
化学 | 342篇 |
晶体学 | 4篇 |
力学 | 6篇 |
数学 | 33篇 |
物理学 | 163篇 |
出版年
2023年 | 4篇 |
2021年 | 10篇 |
2020年 | 11篇 |
2019年 | 8篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 10篇 |
2015年 | 9篇 |
2014年 | 17篇 |
2013年 | 18篇 |
2012年 | 28篇 |
2011年 | 38篇 |
2010年 | 15篇 |
2009年 | 9篇 |
2008年 | 19篇 |
2007年 | 20篇 |
2006年 | 30篇 |
2005年 | 19篇 |
2004年 | 20篇 |
2003年 | 16篇 |
2002年 | 24篇 |
2001年 | 10篇 |
2000年 | 13篇 |
1999年 | 6篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 11篇 |
1993年 | 8篇 |
1992年 | 4篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1988年 | 9篇 |
1986年 | 7篇 |
1985年 | 4篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1981年 | 6篇 |
1978年 | 8篇 |
1977年 | 9篇 |
1976年 | 11篇 |
1975年 | 11篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1972年 | 4篇 |
1971年 | 4篇 |
1970年 | 5篇 |
1968年 | 4篇 |
1966年 | 5篇 |
1965年 | 5篇 |
排序方式: 共有548条查询结果,搜索用时 15 毫秒
1.
Andrew P. Bassom Peter A. Clarkson C. K. Law J. Bryce McLeod 《Archive for Rational Mechanics and Analysis》1998,143(3):241-271
In this work we propose a new method for investigating connection problems for the class of nonlinear second‐order differential
equations known as the Painlevé equations. Such problems can be characterized by the question as to how the asymptotic behaviours
of solutions are related as the independent variable is allowed to pass towards infinity along different directions in the
complex plane. Connection problems have been previously tackled by a variety of methods. Frequently these are based on the
ideas of isomonodromic deformation and the matching of WKB solutions. However, the implementation of these methods often tends
to be heuristic in nature and so the task of rigorising the process is complicated. The method we propose here develops uniform
approximations to solutions. This removes the need to match solutions, is rigorous, and can lead to the solution of connection
problems with minimal computational effort. Our method relies on finding uniform approximations of differ
ential equations of the generic form as the complex‐valued parameter . The details of the treatment rely heavily on the locations of the zeros of the function F in this limit. If they are isolated, then a uniform approximation to solutions can be derived in terms of Airy functions
of suitable argument. On the other hand, if two of the zeros of F coalesce as , then an approximation can be derived in terms of parabolic cylinder functions. In this paper we discuss both cases, but
illustrate our technique in action by applying the parabolic cylinder case to the “classical” connection problem associated
with the second Painlevé transcendent. Future papers will show how the technique can be applied with very little change to
the other Painlevé equations, and to the wider problem of the asymptotic behavio
ur of the general solution to any of these equations.
(Accepted May 15, 1997) 相似文献
2.
3.
New Experimental Insight into the Nature of Metal−Metal Bonds in Digallium Compounds: J Coupling between Quadrupolar Nuclei 下载免费PDF全文
Dr. Libor Kobera Scott A. Southern Dr. Gyandshwar Kumar Rao Prof. Dr. Darrin S. Richeson Prof. Dr. David L. Bryce 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(28):9565-9573
Multiple bonding between atoms is of ongoing fundamental and applied interest. Here, we report a multinuclear (1H, 13C, and 71Ga) solid‐state magnetic resonance spectroscopic study of digallium compounds which have been proposed, albeit somewhat controversially, to contain single, double, and triple Ga?Ga bonds. Of particular relevance to the nature of these bonds, we have carried out two‐dimensional 71Ga J/D‐resolved NMR experiments which provide a direct measurement of J(71Ga,71Ga) spin–spin coupling constants across the gallium?gallium bonds. When placed in the context of clear‐cut experimental data for analogous singly, doubly, and triply bonded carbon spin pairs or boron spin pairs, the 71Ga NMR data clearly support the notion of a different bonding paradigm in the gallium systems. Our findings are consistent with an increasing role across the purported gallane–gallene–gallyne series for classical and/or slipped π‐type bonding orbitals. 相似文献
4.
Nathael Gozlan Cyril Roberto Paul-Marie Samson Prasad Tetali 《Probability Theory and Related Fields》2014,160(1-2):47-94
We introduce the notion of an interpolating path on the set of probability measures on finite graphs. Using this notion, we first prove a displacement convexity property of entropy along such a path and derive Prékopa-Leindler type inequalities, a Talagrand transport-entropy inequality, certain HWI type as well as log-Sobolev type inequalities in discrete settings. To illustrate through examples, we apply our results to the complete graph and to the hypercube for which our results are optimal—by passing to the limit, we recover the classical log-Sobolev inequality for the standard Gaussian measure with the optimal constant. 相似文献
5.
6.
Heather E. Grandelli Bryce Stickle Abby Whittington Erdogan Kiran 《Journal of inclusion phenomena and macrocyclic chemistry》2013,77(1-4):269-277
Inclusion complex formation between β-cyclodextrin and Naproxen was investigated using differential scanning calorimetry (DSC) as a function of the β-cyclodextrin-to-Naproxen molar ratio, ranging from 0:5:1 to 5:1. When these mixtures are heated above the melting temperature of Naproxen, an exothermic peak is observed at a temperature slightly higher than the melting peak of Naproxen. This peak, which has not been previously reported, has been interpreted as an exothermic energy of inclusion complex formation. The magnitude of this complex formation peak was found to be dependent upon the composition of the β-cyclodextrin and Naproxen mixture and increased in magnitude to a maximum value at a β-cyclodextrin:Naproxen molar ratio of 2:1. In addition, Naproxen recrystallization and re-melting peaks seen in the cooling and re-heating scans, respectively, decreased in magnitude with increasing molar ratio and totally disappeared for the mixture with 5:1 of β-cyclodextrin to Naproxen ratio indicative of complete inclusion of Naproxen in the cyclodextrin cavities. Complete inclusion was further reflected by the disappearance of key Naproxen peaks in Fourier transform infrared spectra of samples recovered from DSC experiments. The large excess of β-cyclodextrin needed to fully complex the Naproxen was found to be due to slow kinetics. Increasing the hold time after the initial melting led to inclusion efficiencies up to 95 % even for the 2:1 mixture. These experiments suggest that ratios of β-cyclodextrin:Naproxen 2:1 or greater facilitate the process by increasing the presence of cyclodextrin molecules in the close proximity of the drug molecules and lead to high inclusion efficiencies. 相似文献
7.
Harshanie Abeywardena Aaron R. Jex Simon M. Firestone Sandra McPhee Nicole Driessen Anson V. Koehler Shane R. Haydon Georg von Samson‐Himmelstjerna Melita A. Stevens Robin B. Gasser 《Electrophoresis》2013,34(15):2259-2267
In the present study, we undertook a molecular epidemiological survey of Cryptosporidium and Giardia in calves on three dairy and two beef farms within an open drinking water catchment area (Melbourne, Australia). Faecal samples (n = 474) were collected from calves at two time points (5 months apart) and tested using a PCR‐based mutation scanning‐targeted sequencing phylogenetic approach, employing regions within the genes of small subunit (SSU) of ribosomal RNA (designated partial SSU), 60 kDa glycoprotein (pgp60) and triose phosphate isomerase (ptpi) as genetic markers. Using partial SSU, the C. bovis, C. parvum, C. ryanae and a new genotype of Cryptosporidium were characterised from totals of 74 (15.6%), 35 (7.3%), 37 (7.8%) and 9 (1.9%) samples, respectively. Using pgp60, C. parvum genotype IIa subgenotype A18G3R1 was detected in 29 samples. Using ptpi, G. duodenalis assemblages A and E were detected in totals of 10 (2.1%) and 130 (27.4%) samples, respectively. The present study showed that a considerable proportion of dairy and beef calves in this open water catchment region excreted Cryptosporidium (i.e. subgenotype IIaA18G3R1) and Giardia (e.g. assemblage A) that are consistent with those infecting humans, inferring that they are of zoonotic importance. Future work should focus on exploring, in a temporal and spatial way, whether these parasites occur in the environment and water of the catchment reservoir. 相似文献
8.
Oligosiloxane Functionalized with Pendant (1,3‐Bis(9‐carbazolyl)benzene) (mCP) for Solution‐Processed Organic Electronics 下载免费PDF全文
Dr. Dianming Sun Dr. Zhaomin Yang Dr. Zhongjie Ren Dr. Huihui Li Prof. Martin R. Bryce Prof. Dongge Ma Prof. Shouke Yan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(49):16233-16241
A new oligosiloxane derivative (ODCzMSi) functionalized with the well‐known 1,3‐bis(9‐carbazolyl)benzene (mCP) pendant moiety, directly linked to the silicon atom of the oligosiloxane backbone, has been synthesized and characterized. Compared to mCP, the attachment of the oligosiloxane chain significantly improves the thermal and morphological stabilities with a high decomposition temperature (Td=540 °C) and glass transition temperature (Tg=142 °C). The silicon–oxygen linkage of ODCzMSi disrupts the backbone conjugation and maintains a high triplet energy level (ET=3.0 eV). A phosphorescent organic light‐emitting diode (PhOLED) using iridium bis(4,6‐difluorophenyl)pyridinato‐N,C2 picolinate (FIrpic) as the emitter and ODCzMSi as the host shows a relatively low turn‐on voltage of 5.0 V for solution‐processed PhOLEDs, maximum external quantum efficiency of 9.2 %, and maximum current efficiency of 17.7 cd A?1. The overall performance of this device is competitive with the best reported solution‐processed blue PhOLEDs. Memory devices using ODCzMSi as an active layer exhibit non‐volatile write‐once read‐many‐times (WORM) characteristics with high stability in retention time up to 104 s and a low switch on voltage. This switching behaviour is explained by different stable conformations of ODCzMSi with high or low conductivity states which are obtained under the action of electric field through a π–π stacking alignment of the pendant aromatic groups. These results with both PhOLEDs and memory devices demonstrate that this oligosiloxane–mCP hybrid structure is promising and versatile for high performance solution‐processed optoelectronic applications. 相似文献
9.
10.
Chao Wang Felix S. Kim Guoqiang Ren Yongqian Xu Yi Pang Samson A. Jenekhe Li Jia 《Journal of polymer science. Part A, Polymer chemistry》2010,48(21):4681-4690
Head‐to‐tail regioregular poly(3‐heptanoylthiophene) (PHOT) was synthesized by Ni‐catalyzed polycondensation of the 2,2‐dimethyl‐1,3‐propanediol‐protected Grignard monomer followed by deprotection. Cyclic voltammetric (CV) study demonstrates that the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) of PHOT are 0.5 eV lower in energy than those of the head‐to‐tail poly(3‐hexylthiophene) (HT‐P3HT). Their optical band gaps are essentially the same. Incomplete photoluminescence (PL) quenching was observed in thin films of the 1:1 blend of PHOT and HT‐P3HT. PHOT displayed a glass transition at ~269 °C and decomposed at ~300 °C according to differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Wide‐angle X‐ray diffraction (WAXD) study showed that PHOT exists in a not highly ordered state in solid films especially in the π‐stacking direction. Only p‐channel activity was observed in field‐effect transistors (FETs) for PHOT. The hole mobility was on the order of 10?4 cm2 V?1 s?1. Photovoltaic devices with an active layer of 1:1 blend of PHOT and PC71BM had a power conversion efficiency (PCE) of ~0.5%. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献