Anti-markovnikov N-H and O-H additions to electron-deficient olefins catalyzed by well-defined Cu(I) anilido, ethoxide, and phenoxide systems

The monomeric Cu(I) complexes (IPr)Cu(Z) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, Z = NHPh, OEt, or OPh) react with YH (Y = PhNH, PhCH2NH, EtO, or PhO) to catalytically add Y-H bonds across the C=C bond of electron-deficient olefins to yield anti-Markovnikov organic products. Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. Preliminary studies implicate an intermediate in which the C-Y bond forms through a nucleophilic addition pathway.     

A facility for the production of iodine-123 by spallation of caesium

A facility for the continuous production of iodine-123 by spallation of elemental caesium by 482 MeV protons has been in operation at a TRIUMF beam dump for about 2 years. Radioxenon from the target is efficiently trapped on alumina which is subsequently used to remove the¹²¹Te decay product. The yield is 100 mCi/h from a 20 gm/cm² target at 10 μA. Impurities are¹²⁵I<2% and¹²¹Te<0.2% at 27 hours after end of production. The¹²³I consists mainly of iodide along with significant iodate impurity. The product is used extensively in Canadian clinics for thyroid analyses and for labelling radiopharmaceuticals.     

Susceptibility of electro-optic components to degradation in a space environment

Possible causes of degradation of electro-optic systems operating in a space environment include not only the effects of radiation but also the effects of temperature, temperature cycling, atomic oxygen effects (for low-Earth orbits), micrometeoroid impacts, and contamination effects. For the majority of electro-optic components, the radiation environment in space does not present a significant problem. For a few components, or for electro-optic systems that must operate in a high radiation environment, special precautions must be observed. The effects of radiation, as well as other problems of the space environment, on electro-optic components, including recent results from the LDEF satellite experiments and some later measurements, are reviewed. Guidelines for materials and component selection shielding are presented.     

Excited state production and temperature measurement in a heavy ion reaction

An effective temperature inferred from the slope of kinetic energy spectra of the emitted fragments is not reflected in the relative populations of excited states of the emitted nuclei. We found that the excited state populations of ⁶Li, ⁷Li and ⁷Be emitted near 90° in the lab from the reaction of 490 MeV ¹⁴N with Ag are significantly lower than those expected on the basis of their effective temperature.     

Separation of thallium-201 from lead-201 using N-benzylaniline

A procedure is described for the liquid extraction of ingrown²⁰¹Tl from its precursor²⁰¹Pb using N-benzylaniline. The yield for a double extraction averaged 95.9±3.2% for thallium; 2.9±4.2% for lead. Yields for back extraction into acetic acid averaged 93.7±1.5%.     

Anti-Markovnikov hydroamination and hydrothiolation of electron-deficient vinylarenes catalyzed by well-defined monomeric copper(I) amido and thiolate complexes

Monomeric Cu(I) amido and thiolate complexes that are supported by the N-heterocyclic carbene ligand 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) catalyze the hydroamination and hydrothiolation of electron-deficient vinylarenes with reactivity patterns that are consistent with an intermolecular nucleophilic addition of the amido/thiolate ligand of (IPr)Cu(XR) (X = NH or S; R = Ph, CH2Ph) to free vinylarene.     

Mach stem hysteresis: Experiments addressing a novel explanation of clumpy astrophysical jet emission

Recent time-series observations of shock waves in stellar jets taken with the Hubble Space Telescope reveal localized bright knots that persist over nearly 15 years. While some of these features represent shock fronts caused by variable velocities in the flow, others appear at the intersection points between distinct bow shocks. Theoretically, when the angle between two intersecting shocks exceeds a certain critical value, a third shock (Mach stem) should form. Because Mach stems form perpendicular to the direction of flow, incoming particles encounter a normal shock instead of an oblique one, which results in brighter emission at this location. To study this phenomenon in a controlled laboratory setting, we have carried out experiments on the Omega laser aimed at understanding the formation, growth, and destruction of Mach stems in the warm dense plasma regime. Our experimental results indicate how the growth rate depends upon included angle, and numerical simulations indicate that it may be possible to stabilize an already-formed Mach stem below the critical angle when certain conditions are satisfied.