全文获取类型
收费全文 | 3614篇 |
免费 | 152篇 |
国内免费 | 6篇 |
专业分类
化学 | 2369篇 |
晶体学 | 80篇 |
力学 | 126篇 |
数学 | 328篇 |
物理学 | 869篇 |
出版年
2023年 | 38篇 |
2022年 | 39篇 |
2021年 | 74篇 |
2020年 | 76篇 |
2019年 | 93篇 |
2018年 | 86篇 |
2017年 | 76篇 |
2016年 | 126篇 |
2015年 | 107篇 |
2014年 | 133篇 |
2013年 | 303篇 |
2012年 | 237篇 |
2011年 | 233篇 |
2010年 | 157篇 |
2009年 | 145篇 |
2008年 | 182篇 |
2007年 | 176篇 |
2006年 | 132篇 |
2005年 | 136篇 |
2004年 | 113篇 |
2003年 | 90篇 |
2002年 | 88篇 |
2001年 | 44篇 |
2000年 | 33篇 |
1999年 | 28篇 |
1998年 | 23篇 |
1997年 | 23篇 |
1996年 | 38篇 |
1995年 | 34篇 |
1994年 | 24篇 |
1993年 | 35篇 |
1992年 | 34篇 |
1991年 | 24篇 |
1990年 | 27篇 |
1989年 | 33篇 |
1988年 | 30篇 |
1987年 | 23篇 |
1986年 | 29篇 |
1985年 | 25篇 |
1984年 | 34篇 |
1983年 | 25篇 |
1982年 | 26篇 |
1981年 | 34篇 |
1980年 | 27篇 |
1979年 | 32篇 |
1978年 | 22篇 |
1977年 | 33篇 |
1976年 | 20篇 |
1975年 | 22篇 |
1974年 | 21篇 |
排序方式: 共有3772条查询结果,搜索用时 93 毫秒
1.
Seema Prasad 《Molecular Crystals and Liquid Crystals》2018,665(1):52-63
Molecular structure and vibrational spectroscopic studies of higher homologous series nematogenic p-n-alkylbenzoic acids (nBAC) that have 6 (6BAC) and 7 (7BAC) carbon atoms in the alkyl chain have been investigated using the Density Functional Becke3-Lee-Yang-Parr (B3LYP) level with the basis set 6-31++G (d.p) and Hartree Fock (HF) with the same basis set. The observed vibrational spectra has been resolved and assigned in detail for comparision with both the molecules. These results indicate that DFT and HF values are slightly different at both the levels. A comparision of chemical reactivity such as HOMO (EH), LUMO (EL) energies, energy gap (Eg), ionization energy (I), electron affinity (A), electro negativity (χ), chemical hardness (η), electronic chemical potential (μ), electrophilicity index (ω), and softness (S) has been made. It has been observed that the decrement has occurred in the energy band gap value of isolated molecule with increment in alkyl chain length. This provides valuable information regarding enhancing the stability of liquid crystal materials by maintaining the conductivity. 相似文献
2.
Shweta Bhagat Minhajul Arfeen Gourav Das Neha Patel Prasad V. Bharatam 《Journal of computational chemistry》2019,40(5):726-733
Carbocyclic carbenes (CCCs) are a class of nucleophilic carbenes which are very similar to N-heterocyclic carbenes (NHCs) in terms of their reactivity, but they do not contain a stabilizing heteroatom in their cyclic ring system. In this study, 17 representative known CCCs and 34 newly designed CCCs are evaluated using quantum chemical methods, and the results are compared in terms of their stability, nucleophilicity, and proton affinity (PA) parameters. The results are divided on the basis of ring size of the known and reported CCCs. The stability, nucleophilicity, PA, complexation energy, and bond strength–related parameters were estimated using M06/6-311++G(d,p) method. The results indicated that the CCCs known in the literature are strong σ-electron donating species and have considerable π-accepting properties. This study led to the design and identification of a few new CCCs with dimethylamine and diaminomethynyl substituents which can be singlet stable and are substantially nucleophilic. © 2018 Wiley Periodicals, Inc. 相似文献
3.
An efficient synthetic strategy has been developed for the synthesis of the tri, tetrasaccharide block and pentasaccharide corresponding to the capsular polysaccharide of Streptococcus pneumonia serotype 18C as their 2-aminoethyl glycosides. A one-pot glycosylation-deprotection, sequential glycosylations strategy has been adopted for the construction of the fragments and pentasaccharide derivative, which were then transformed into target compound after a series of functional group transformations. The synthetic method relies on the use of p-methoxybenzyl ether as an in situ-removable protecting group to reduce the number of reaction steps significantly. Here H2SO4-silica has been used successfully as a promoter for all glycosylation reaction. In addition, the synthetic target also contained a free amino group at its reducing end, facilitating its conjugation with other molecules for various biological studies and applications. 相似文献
4.
5.
Yunqi Li Dr. Bishnu Prasad Bastakoti Prof. Yusuke Yamauchi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8038-8042
Hollow bioactive glass spheres with mesoporous shells were prepared by using dual soft templates, a diblock co‐polymer poly(styrene‐b‐acrylic acid) (PS‐b‐PAA) and a cationic surfactant cetyltrimethylammonium bromide (CTAB). Hollow mesoporous bioactive glass (HMBG) spheres comprise the large hollow interior with vertical mesochannels in shell, which realize large uptake of drugs and their sustained release. The formation of hydroxyapatite layer on the surface of HMBG particles shows the clear evidence for promising application in bone regeneration. 相似文献
6.
7.
Host–Guest Chemistry between Perylene Diimide (PDI) Derivatives and 18‐Crown‐6: Enhancement in Luminescence Quantum Yield and Electrical Conductivity 下载免费PDF全文
P. Lasitha Prof. Dr. Edamana Prasad 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(30):10558-10564
Perylene diimide (PDI) derivatives exhibit a high propensity for aggregation, which causes the aggregation‐induced quenching of emission from the system. Host–guest chemistry is one of the best‐known methods for preventing aggregation through the encapsulation of guest molecules. Herein we report the use of 18‐crown‐6 (18‐C‐6) as a host system to disaggregate suitably substituted PDI derivatives in methanol. 18‐C‐6 formed complexes with amino‐substituted PDIs in methanol, which led to disaggregation and enhanced emission from the systems. Furthermore, the embedding of the PDI ? 18‐C‐6 complexes in poly(vinyl alcohol) (PVA) films generated remarkably high emission quantum yields (60–70 %) from the PDI derivatives. More importantly, the host–guest systems were tested for their ability to conduct electricity in PVA films. The electrical conductivities of the self‐assembled systems in PVA were measured by electrochemical impedance spectroscopy (EIS) and the highest conductivity observed was 2.42×10?5 S cm?1. 相似文献
8.
Self‐Assembly and Gelation of Poly(aryl ether) Dendrons Containing Hydrazide Units: Factors Controlling the Formation of Helical Structures 下载免费PDF全文
Partha Malakar Prof. Dr. Edamana Prasad 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(13):5093-5100
Self‐assembly of AB2 and AB3 type low molecular weight poly(aryl ether) dendrons that contain hydrazide units were used to investigate mechanistic aspects of helical structure formation during self‐assembly. The results suggest that there are three important aspects that control helical structure formation in such systems with acyl hydrazide/hydrazone linkage: i) J‐type aggregation, ii) the hydrogen‐bond donor/acceptor ability of the solvent, and iii) the dielectric constant of the solvent. The monomer units self‐assemble to form dimer structures through hydrogen‐bonding and further assembly of the hydrogen‐bonded dimers leads to macroscopic chirality in the present case. Dimer formation was confirmed by NMR spectroscopy and by mass spectrometry. The self‐assembly in the system was driven by hydrogen‐bonding and π–π stacking interactions. The morphology of the aggregates formed was examined by scanning electron microscopy, and the analysis suggests that aprotic solvent systems facilitate helical fibre formation, whereas introduction of protic solvents results in the formation of flat ribbons. This detailed mechanistic study suggests that the self‐assembly follows a nucleation–elongation model to form helical structures, rather than the isodesmic model. 相似文献
9.
Angshuman Ghosh Soumen Kumar Dubey Dr. Maxcimilan Patra Jishu Mandal Narendra Nath Ghosh Priyanka Das Arpita Bhowmick Dr. Keka Sarkar Dr. Suprabhat Mukherjee Rajat Saha Dr. Subham Bhattacharjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(63):e202201621
We have shown solvent- and substrate-dependent chiral inversion of a few glycoconjugate supramolecules. (Z)-F-Gluco, in which d -glucosamine has been attached chemically to Cbz-protected l -phenylalanine at the C terminus, forms a self-healing hydrogel through intertwining of the nanofibers wherein the gelators undergo lamellar packing in the β-sheet secondary structures with a single chiral handedness. Dihybrid (Z)-F-gluco nanocomposite gel was prepared by in-situ formation of silver nanoparticles AgNPs in the gel; this enhances the mechanical properties of the composite gel through physical crosslinking without altering the packing pattern. In contrast, (Z)-L-gluco bearing an l -leucine moiety does not form a hydrogel but an organogel. Interestingly, the chiral handedness of the aggregates of (Z)-L-gluco can be reversed by choosing suitable solvents. In addition to self-healing behavior, (Z)-L-gluco gel revealed shape persistency. Further, (Z)-F-gluco hydrogel is benign, nontoxic, non-immunogenic, and non-allergenic in animal cells. AgNP-loaded (Z)-F-gluco hydrogel showed antibacterial activity against both Gram-positive and Gram-negative bacteria. 相似文献
10.
Biplab Kumar Mandal 《Molecular physics》2020,118(14)
Density functional theory (DFT) of freezing has been used to investigate the freezing transitions in a system of colloidal particles confined to a two-dimensional plane. The particles interact via a model Hertzian type potential of varying softness. The pair-correlation functions (PCFs) needed as input structural information in DFT are calculated by solving hypernetted chain (HNC) integral equation theory. The PCFs thus obtained have been compared with those obtained through experiment and simulations and are found to be in good qualitative agreement. We found that the PCFs are sensitive to the softness of the potential: showing splitting of pair-correlation peak in the harder case and anomalous non-monotonic density dependence in the softer case. Using the common tangent construction method, we have also proposed the fluid-triangular solid phase diagrams in the temperature-density plane. We found that the phase diagram exhibit solid-fluid coexistence region whose thickness decreases with the increasing temperature as well as with increasing softness of the potential. In the temperature and density range of our calculation, DFT fails to produce any reentrance in the phase diagram. 相似文献