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1.
Christopher B. Kelly Kyle M. Lambert Michael A. Mercadante John M. Ovian Prof. William F. Bailey Prof. Nicholas E. Leadbeater 《Angewandte Chemie (International ed. in English)》2015,54(14):4241-4245
A scalable, high yielding, rapid route to access an array of nitriles from aldehydes mediated by an oxoammonium salt (4‐acetylamino‐2,2,6,6‐tetramethylpiperidine‐1‐oxoammonium tetrafluoroborate) and hexamethyldisilazane (HMDS) as an ammonia surrogate has been developed. The reaction likely involves two distinct chemical transformations: reversible silyl‐imine formation between HMDS and an aldehyde, followed by oxidation mediated by the oxoammonium salt and desilylation to furnish a nitrile. The spent oxidant can be easily recovered and used to regenerate the oxoammonium salt oxidant. 相似文献
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Hyung-gyu Jun Thomas R. Way Bjrn Lfgren Mats Landstrm Alvin C. Bailey Eddie C. Burt Timothy P. McDonald 《Journal of Terramechanics》2004,41(4):209-222
A Trelleborg Twin 421 Mark II 600/55-26.5 steel-reinforced bias-ply forwarder drive tire at inflation pressures of 100 and 240 kPa and dynamic loads of 23.9 and 40 kN was used at 5% travel reduction on a firm clay soil. Effects of dynamic load and inflation pressure on soil–tire contact pressures were determined using six pressure transducers mounted on the tire tread. Three were mounted on the face of a lug and three at corresponding locations on the undertread. Contact angles increased with decreases in inflation pressure and increases in dynamic load. Contact pressures on a lug at the edge of the tire increased as dynamic load increased. Mean and peak pressures on the undertread generally were less than those on a lug. The peak pressures on a lug occurred forward of the axle in nearly all combinations of dynamic load, inflation pressure, and pressure sensor location, and peak pressures on the undertread occurred to the rear of the axle in most of the combinations. Ratios of the peak contact pressure to the inflation pressure ranged from 0 at the edge of the undertread for three combinations of dynamic load and inflation pressure to 8.39 for the pressure sensor on a lug, near the tire centerline, when the tire was underinflated. At constant dynamic load, net traction and tractive efficiency decreased as inflation pressure increased. 相似文献
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In this work, certain peculiarities of the dynamics of pressure waves in a liquid containing bubbles are studied. The specification of a model of bubbly liquids with regard to acoustic damping of the bubbles is considered. Our theoretical results are compared with experimental ones.Received: 30 June 2002, Accepted: 2 February 2003, Published online: 11 June 2003 相似文献
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Matthew Thompson Carolyn Carkner Adrian Bailey Nicholas J. Mosey Nadia Kapernaum 《Liquid crystals》2013,40(9):1246-1260
Two sterically equivalent series of phenoxy-terminated 5-alkoxy-2-(4-alkoxyphenyl)pyrimidine liquid crystals were synthesised, and their mesogenic properties were characterised by polarised optical microscopy and differential scanning calorimetry (DSC). The phenoxy end-group causes a significant increase in melting point and inhibits – at least partially – the mesomorphism of these materials relative to the parent isomers; in most cases, the broad enantiotropic SmC phase formed by the parent isomers is suppressed by the addition of the phenoxy end-group. However, detailed analyses by small-angle X-ray scattering and monodomain 2D X-ray scattering suggest that these compounds form a SmA phase with a partially intercalated bilayer structure in which the phenoxy end-groups are nanosegregated. Such an intercalated bilayer structure might enable the tuning of smectogenic properties by appropriate substitution of the phenoxy end-groups. 相似文献
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A. Anghel T. L. Bailey G. Bison B. Blau L. J. Broussard S. M. Clayton C. Cude-Woods M. Daum A. Hawari N. Hild P. Huffman T. M. Ito K. Kirch E. Korobkina B. Lauss K. Leung E. M. Lutz M. Makela G. Medlin C. L. Morris R. W. Pattie D. Ries A. Saunders P. Schmidt-Wellenburg V. Talanov A. R. Young B. Wehring C. White M. Wohlmuther G. Zsigmond 《The European Physical Journal A - Hadrons and Nuclei》2018,54(9):148
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Jennifer T. Duong Mark J. Bailey Teresa E. Pick Patrick M. McBride Evelyn L. Rosen Raffaella Buonsanti Delia J. Milliron Brett A. Helms 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3719-3727
Water‐dispersible, polymer‐wrapped nanocrystals are highly sought after for use in biology and chemistry, from nanomedicine to catalysis. The hydrophobicity of their native ligand shell, however, is a significant barrier to their aqueous transfer as single particles. Ligand exchange with hydrophilic small molecules or, alternatively, wrapping over native ligands with amphiphilic polymers is widely employed for aqueous transfer; however, purification can be quite cumbersome. We report here a general two‐step method whereby reactive stripping of native ligands is first carried out using trialkyloxonium salts to reveal a bare nanocrystal surface. This is followed by chemically directed immobilization of a hydrophilic polymer coating. Polyacrylic acids, with side‐chain grafts or functional end groups, were found to be extremely versatile in this regard. The resulting polymer‐wrapped nanocrystal dispersions retained much of the compact size of their bare nanocrystal precursors, highlighting the unique role of monomer side‐chain functionality to serve as effective, conformal ligation motifs. As such, they are well poised for applications where tailored chemical functionality at the nanocrystal's periphery or improved access to their surfaces is desirable. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
10.
Abigail C. Bailey 《代数通讯》2017,45(6):2662-2672
We extend the definition of a piecewise Noetherian ring to the noncommutative case, and investigate various properties of such rings. In particular, we show that a ring with Krull dimension is piecewise Noetherian. Certain fully bounded piecewise Noetherian rings have Gabriel dimension and exhibit the Gabriel correspondence between prime ideals and indecomposable injective modules. 相似文献