Synthesis of the Three Mixed-ligand Metal Complexes and One Organic Salt of 3,5-Dinitrobenzoic Acid for Biopharmaceutical Optimization Through Monoethanolamine: Structures and DFT Studies of Complexes

Journal of Chemical Crystallography - The simplest derivatives of benzoic acid show a wide spectrum of the biological action mostly being poor water soluble. In order to demonstrate on example of...     

Polymorphic Transformations in the K0.945Ag0.055NO3 Single Crystal

Crystallography Reports - The polymorphic transformations in K0.945Ag0.055NO3 are studied by optical spectroscopy and X-ray diffraction. It is established that one structural transformation occurs...     

Negatron effects in CdSe1 − x Te x and ZnS1−x Se x films

Various negatron effects in films of alloys of II–VI compounds deposited from solutions as a function of the deposition mode and heat treatment are studied. It is found that the negative photocapacitance effect, which was first discovered in ZnS_1?x Se _x films, and the slowly relaxing negative photoelectric effects, which are caused by the transition of electrons located in a nanoscale surface layer from the shallow energy levels of trapping centers to deeper levels with a lower polarizability and by the presence of nanoscale clusters in these materials, which play the role of a “reservoir” for minority charge carriers, occur according to a single mechanism. A model to explain the basic laws of negative photoconductivity in CdSe_{1 ? x} Te _x films deposited from a solution is proposed. Negative residual conductivity is explained in terms of double-barrier relief model, while negative differential photoconductivity is attributed to the presence of nanoscale electric domains.     

Reactions of massive nuclei for the synthesis of heavy and superheavy nuclei

We study the effect of the entrance channel and the shell structure of reacting massive nuclei on the fusion mechanism and the formation of evaporation residues of heavy and superheavy nuclei. In the framework of the combined dinuclear system concept and advanced statistical model, we analyze the reactions ³²S+¹⁸²W, ⁴⁸Ti+¹⁶⁶Er and ⁶⁰Ni+¹⁵⁴Sm leading to ²¹⁴Th^*, and the reactions ⁴⁸Ca+²⁴⁸Cm and the ⁴⁸Ca+²⁴⁹Cf leading to the ²⁹⁶116 and ²⁹⁷118 compound nuclei, respectively.     

Dynamics of capture and fusion in heavy ion collisions

The effect of entrance channel on decrease of the complete fusion cross sections and on the yield of reaction products are associated with the quasifission which depends on the mass asymmetry and shell structure of colliding nuclei. In reactions of massive projectile and target nuclei, the competition between complete fusion and quasifission appears at the stage of compound nucleus formation, in addition to the increase of the fission probability. It is shown that the yield of quasifission products may be symmetric or asymmetric in dependence on peculiarities of shell structure of reaction fragments. Marima of mass or charge distributions are connected with the peculiarities of shell structure of reaction fragments.     

Eligibility of spherical-well approximation for calculations of nucleon-transfer matrix elements

Single-particle matrix elements of nucleon transfer were calculated by the Woods-Saxon potential wave functions. The results are compared with the ones calculated by the spherical-well approximation. The eligibility of the approximation of the mean field of nuclei by the spherical well to study the initial stage of nuclear reactions at heavy-ion collisions is demonstrated. The text was submitted by the authors in English.     

X-ray structural investigation of alkaloids. III. Molecular structure and absolute configuration of (+)-excelsine

By a complete x-ray structural investigation, the structural formula of (−)-pseudokopsinine has been refined and its absolute configuration has been determined.     

Effect of metal and solvent on kinetics of metalation of fluorene by anthracene anion-radicals

Conclusions The contact ion pairs of the anthracene anion-radicals containing the cations of the alkali metals (Li⁺, Na⁺, K⁺) are more reactive in the reaction with fluorene than are the ion pairs that are separated by a solvent.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 215–216, January, 1973.