Synthesis of 2D Germanane (GeH): a New,Fast, and Facile Approach

Germanane (GeH), a germanium analogue of graphane, has recently attracted considerable interest because its remarkable combination of properties makes it an extremely suitable candidate to be used as 2D material for field effect devices, photovoltaics, and photocatalysis. Up to now, the synthesis of GeH has been conducted by substituting Ca by H in a β‐CaGe₂ layered Zintl phase through topochemical deintercalation in aqueous HCl. This reaction is generally slow and takes place over 6 to 14 days. The new and facile protocol presented here allows to synthesize GeH at room temperature in a significantly shorter time (a few minutes), which renders this method highly attractive for technological applications. The GeH produced with this method is highly pure and has a band gap (E_g) close to 1.4 eV, a lower value than that reported for germanane synthesized using HCl, which is promising for incorporation of GeH in solar cells.     

A non-singular continuum theory of dislocations

We develop a non-singular, self-consistent framework for computing the stress field and the total elastic energy of a general dislocation microstructure. The expressions are self-consistent in that the driving force defined as the negative derivative of the total energy with respect to the dislocation position, is equal to the force produced by stress, through the Peach-Koehler formula. The singularity intrinsic to the classical continuum theory is removed here by spreading the Burgers vector isotropically about every point on the dislocation line using a spreading function characterized by a single parameter a, the spreading radius. A particular form of the spreading function chosen here leads to simple analytic formulations for stress produced by straight dislocation segments, segment self and interaction energies, and forces on the segments. For any value a>0, the total energy and the stress remain finite everywhere, including on the dislocation lines themselves. Furthermore, the well-known singular expressions are recovered for a=0. The value of the spreading radius a can be selected for numerical convenience, to reduce the stiffness of the dislocation equations of motion. Alternatively, a can be chosen to match the atomistic and continuum energies of dislocation configurations.     

Self-similar fluid-dynamic limits for the Broadwell system

This report discusses a new approach for the resolution of the fluid-dynamic limit for the Broadwell system of the kinetic theory of gases, appropriate in the case of Riemann, Maxwellian data. Since the formal limiting system is expected to have self-similar solutions, we are motivated to replace the Knudsen number in the Broadwell model so that the resulting model admits self-similar solutions =x/t and then let go to zero. The limiting procedure is justified and the resulting limit is a solution of the Riemann problem for the fluid-dynamic limit equations. A class of Riemann data for which this program can be carried out is exhibited. Furthermore, it is shown that for the Carleman model the complete program can be done successfully for arbitrary Riemann data.     

Wave interactions and variation estimates for self-similar zero-viscosity limits in systems of conservation laws

We consider the problem of self-similar zero-viscosity limits for systems ofN conservation laws. First, we give general conditions so that the resulting boundary-value problem admits solutions. The obtained existence theory covers a large class of systems, in particular the class of symmetric hyperbolic systems. Second, we show that if the system is strictly hyperbolic and the Riemann data are sufficiently close, then the resulting family of solutions is of uniformly bounded variation and oscillation. Third, we construct solutions of the Riemann problem via self-similar zero-viscosity limits and study the structure of the emerging solution and the relation of self-similar zero-viscosity limits and shock profiles. The emerging solution consists ofN wave fans separated by constant states. Each wave fan is associated with one of the characteristic fields and consists of a rarefaction, a shock, or an alternating sequence of shocks and rarefactions so that each shock adjacent to a rarefaction on one side is a contact discontinuity on that side. At shocks, the solutions of the self-similar zero-viscosity problem have the internal structure of a traveling wave.     

Dependence of noise induced effects on state preparation in multiqubit systems

The perturbation of multiqubit systems by an external noise can induce various effects like decoherence, stochastic resonance and anti-resonance, and noise-shielding. We investigate how the appearance of these effects on disentanglement time depends on the initial preparation of the systems. We present results for 2-, 3- and 4-qubit chains in various arrangements and observe a clear dependence on the combination of initial geometry of the state space and the placement of noise. Finally, we see that temperature can play a constructive role for the control of these noise induced effects.     

Students’ mathematical work on absolute value: focusing on conceptions,errors and obstacles

ZDM – Mathematics Education - This study investigates students’ conceptions of absolute value (AV), their performance in various items on AV, their errors in these items and the...     

PLMA‐b‐POEGMA amphiphilic block copolymers: Synthesis and self‐assembly in aqueous media

The synthesis and self‐assembly properties in aqueous solutions of novel amphiphilic block copolymers composed of one hydrophobic poly (lauryl methacrylate), (PLMA) block and one hydrophilic poly (oligo ethylene glycol methacrylate) (POEGMA) block are reported. The block copolymers were prepared by RAFT polymerization and were molecularly characterized by size exclusion chromatography, NMR and FT‐IR spectroscopy, and DSC. The PLMA‐b‐POEGMA amphiphilic block copolymers self‐assemble in nanosized complex nanostructures resembling compound micelles when inserted in aqueous media, as supported by light scattering and TEM measurements. The encapsulation and release of the model, hydrophobic, nonsteroidal anti‐inflammatory drug indomethacin in the polymeric micelles is also investigated. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 155–163