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1.
Optical Review - Based on the scintillation index of Airy beam and exponentiated Weibull channel model, analytical expressions of outage probability for free-space optical (FSO) communication links... 相似文献
2.
自适应光学校正技术可有效提升固体板条激光器的光束质量,但随着激光器输出功率的提升,输出光束口径逐渐增加,系统体积逐渐增大,自适应光学校正系统的设计难度也增加了。因此,在满足自适应光学校正系统中共轭探测等需求的前提下,统筹优化系统的尺寸参数,同时实现波前相位、光束质量评估等多参数的检测具有一定的研究意义。本文在系统整体尺寸为350 mm×180 mm×220 mm(长×宽×高)的条件下,研究实现了板条激光器输出160 mm×120 mm矩形光束多参数的检测。针对探测口径大、筒长限制、长出瞳距等技术要求,首先,利用双高斯初始结构的消像差特点,结合非球面技术,采用大倍率光束压缩后分光探测的设计方案,实现多参数的同时探测。其次,基于摄远成像和共轭成像等原理,确定系统初始参数。接着,建立仿真模型分析系统的成像质量和公差,为实验的搭建提供依据。最后,搭建实验平台验证设计结果。结果表明:所设计系统可在满足物像共轭、尺寸约束等条件下,实现对大口径矩形光束的共轭波前探测、光强均匀度检测和光束质量评估。实验测得被测光束β因子为1.24倍衍射极限,均匀度为73.8%,满足技术指标要求。 相似文献
3.
JETP Letters - To explore the diluted magnetic semiconductors for spintronic applications, we have studied N doped Y2O3 employing density functional theory (DFT). It has been observed that the... 相似文献
4.
Diastereo‐ and Enantioselective Palladium‐Catalyzed Dearomative [3+2] Cycloaddition of 3‐Nitroindoles 下载免费PDF全文
Diastereo‐ and enantioselective cycloaddition of 3‐nitroindoles with vinyl aziridine was realized under Pd‐catalysis using commercially available Walphos as the ligand, affording pyrroloindolines in high yields with high diastereo‐ and enantioselectivities. The reaction can be scaled up to a gram scale and the reaction products are easily converted to amino pyrroloindoline and other pyrroloindoline derivatives. 相似文献
5.
Cover Feature: [CH3NH3]4Ga4SbS9S0.28O0.72H: A Three‐Dimensionally Open‐Framework Heterometallic Chalcogenidoantimonate Exhibiting Ni2+ Ion‐Exchange Property (Chem. Asian J. 6/2018) 下载免费PDF全文
Dr. Bo Zhang Wei‐An Li Yi‐Yu Liao Chen Zhang Dr. Mei‐Ling Feng Prof. Dr. Xiao‐Ying Huang 《化学:亚洲杂志》2018,13(6):585-585
6.
A Multi‐Stimuli‐Responsive Oxazine Molecular Switch: A Strategy for the Design of Electrochromic Materials 下载免费PDF全文
Xiaojun Wang Chang Gu Hongzhi Zheng Dr. Yu‐Mo Zhang Prof. Sean Xiao‐An Zhang 《化学:亚洲杂志》2018,13(9):1206-1212
A multi‐state and multi‐stimuli‐responsive oxazine molecular switch that combines an electro‐base property and sensitive base/acid‐responsive properties was designed and synthesized. The multi‐state structures of the molecular switch, with different colors, were predicted by comparing the optical properties with reference molecules and confirmed by using NMR spectroscopy. The color‐switching mechanism under stimulation with acids and bases was investigated by using DFT calculations. Three single states can be obtained and the switching is unidirectional under acid and base stimulation. The electrochromic phenomenon of the molecular switch, which combines its electro‐base and base‐sensitive properties, was demonstrated. An electrochromic device that exhibited good electrochromic properties with excellent reversibility (2000 cycles) and high coloration efficiency (804 cm2 C?1) was successfully constructed. 相似文献
7.
8.
Piperazine‐functionalized nickel ferrite (NiFe2O4) nanoparticles were synthesized as recoverable heterogeneous base catalysts using a routine method. The synthesized materials were characterized using various spectroscopic techniques such as infrared, X‐ray diffraction, scanning electron microscopy, energy‐dispersive X‐ray, thermogravimetry analysis, and vibrating sample magnetometry. Catalytic efficiency was investigated in the synthesis of 2‐amino‐4H‐chromene derivatives via a one‐pot three component reaction of aldehyde and malononitrile with β or α‐naphthol/5‐methyle resorcinol under solvent‐free conditions with good to high yields. This method is operationally simple and has several advantages such as good to high yield, short reaction times, solvent‐free conditions, and easy synthesis. Moreover, the catalyst was recovered easily using an external magnet and reused three times without distinctive loss in catalytic activity. 相似文献
9.
An experimentally feasible strong coupling system between a spin ensemble and a superconducting qubit is studied. The coupling strength can be exponentially enhanced by applying the squeezing transformations to the system. By means of the two spin ensembles commonly coupled to a superconducting qubit, a set of universal nonadiabatic holonomic single‐qubit quantum gates can be realized in a decoherence‐free subspace. Furthermore, this proposal is robust with respect to decay of the system parameters, and it is experimentally feasible with currently available technology. 相似文献
10.
Chi‐Shin Wang Yu‐Chen Wei Kai‐Hsin Chang Pi‐Tai Chou Yao‐Ting Wu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(30):10264-10268
Indeno[1,2‐b]fluorene‐based [2,2]cyclophanes with 4n/4n and 4n/[4n+2] π‐electron systems were prepared, and their structures were identified by X‐ray crystallography. With short π–π distances around 3.0 Å, [2.2](5,11)indeno[1,2‐b]fluorenophane and its precursor [2.2](5,11)indeno[1,2‐b]fluorene‐6,12‐dionophane exhibit remarkable transannular interactions, leading to their unusual electrochemical and photophysical properties. With the aid of femtosecond transient absorption spectroscopy, the transition from the monomeric excited state to the redshifted H‐type dimeric state was first observed, correlating to the calculated excitonic energy splitting and the steady‐state absorption spectra induced by charge‐transfer‐mediated superexchange interaction. 相似文献