Phthalocyanines containing macrocyclic and azo chromophores in the molecule

4-[(Z)-(R)-Diazenyl]phthalonitriles and cobalt phthalocyanines on their basis are synthesized and their electron absorption spectra are studied.     

Synthesis of tetraarm stars with polyetherimide-polyether block copolymer arms

Russian Chemical Bulletin - The method of one-stage catalytic polycyclocondensation according to the B4 + AB scheme was used to synthesize new tetraarm star-shaped oligoimides (SOIs) with terminal...     

Synthesis of chalcones from 3-formyl-substituted pyrrolo[3,4-<Emphasis Type="Italic">f</Emphasis>]indole-5,7-diones

General methods to access new 3-formyl-substituted 1-methoxypyrrolo[3,4-f]indole-5,7-diones were developed. The synthesized 3-formylindoles react with heterocyclic aceto-phenones under acid-catalyzed conditions to give different chalcones.     

Synthesis of substituted 3-acyl-1-hydroxyindoles and azoles on their basis

A general approach to the synthesis of new 3-acetyl-substituted pyrrolo[3,4-f]indole-5,7-diones, 3-[3-(dimethylamino)acryloyl]-1-methoxypyrrolo[3,4-f]indole-5,7-diones and similar indole-5,6-dicarbonitriles has been developed. Dimethylaminoacryloyl derivatives synthesized on their basis regioselectively reacted with hydrazine hydrochlorides and hydroxylamine with the formation of the corresponding 5-substituted azoles.     

The role of molecular-kinetic and thermal factors in inhibition of steady detonation

It was experimentally shown that the reaction of the combustion of hydrogen–air mixtures in a detonation wave virtually completely (with an accuracy of 1%) occurs by a branched-chain mechanism; it is this mechanism that determines the characteristics of the detonation wave.     

Saturation kinetics and relative reactivity of the double bonds of alicyclic dienes in their hydrogenation

The kinetics of the liquid-phase hydrogenation of cyclodienes with various structures (endo-tricyclo[ 5.2.1.0^2,6]decadiene-3,8 and cis,cis-1,5-cyclooctadiene) by hydrogen over a finely dispersed 1%Pd/C catalyst at atmospheric pressure has been studied. The catalyst provides the possibility for successive saturation of the double bonds of the dienes. The reactivities of the cyclodienes determined by their electron-donating properties have been compared. The solvent nature is the determining factor in the ratio of hydrogen absorption rates in the case of successive saturation of the double bonds of the hydrocarbons. The hydrogenation kinetics of cyclic dienes, including dicyclopentadiene, can be modeled using the Langmuir–Hinshelwood equation when the process is carried out in a perfectly mixed flow reactor.     

Nonlinear spectral problem for a self-adjoint vector differential equation

We consider a spectral problem that is nonlinear in the spectral parameter for a self-adjoint vector differential equation of order 2n. The boundary conditions depend on the spectral parameter and are self-adjoint as well. Under some conditions of monotonicity of the input data with respect to the spectral parameter, we present a method for counting the eigenvalues of the problem in a given interval. If the boundary conditions are independent of the spectral parameter, then we define the notion of number of an eigenvalue and give a method for computing this number as well as the set of numbers of all eigenvalues in a given interval. For an equation considered on an unbounded interval, under some additional assumptions, we present a method for approximating the original singular problem by a problem on a finite interval.     

STRUCTURE AND CATALYTIC PROPERTIES OF PALLADIUM(II) (ACETYLACETONATO- κ2O,O′)BIS(TRIS(DIETHYLAMINO)PHOSPHINE) TETRAFLUOROBORATE

Journal of Structural Chemistry - The structure of complex [Pd(acac){P(NEt2)3}2]BF4 (I) is determined by XRD. In the crystal structure of I, the coordination sphere of palladium is characterized by...