Partial molar volumes of methoxybenzenes in carbon tetrachloride

The partial molar volumesV° for a number of methoxybenzenes in carbon tetrachloride at 25°C have been determined. Results are in reasonable aggreement withV° values calculated by the addition of group increments to a covolume factor of 11.61 cm³-mol^?1, and subtraction of fixed amounts for structural features known to involve intramolecular overcrowding.     

Partial molar volumes of amino acid derivatives in water

The partial molar volumes at infinite dilution for a number of hydrochlorides and sodium salts of N-methyl derivatives of , -aminocarboxylic acids in water at 25°C are measured and related to their van der Waals volumes. Results indicate that 4.96±0.48 water molecules hydrate a betaine hydrochloride. Volumes of proton ionization and interaction terms are evaluated. Group contributions to the partial molar volumes are also reported.     

Extraction and analysis of phenolics in food

Phenolics are ubiquitous compounds found in all plants as their secondary metabolites. These include simple phenols, hydroxybenzoic acid and cinnamic acid derivatives, flavonoids, coumarines and tannins, among others. The extraction of phenolics from source materials is the first step involved in their analysis. While chemical methods are used for determination of total content of phenolics, chromatographic and spectrometric analyses are employed for identification and quantification of individual compounds present. This paper provides a summary of background information and methodologies used for the analysis of phenolics in foods and nutraceuticals.     

Partial molar volumes of organic compounds in water. VI. α,ω-diaminoalkane hydrochlorides

Measurements of the partial molar volumes in water at 25°C of the mono-and dihydrochlorides of the ,-diaminoalkanes, up to a chain length of 10 carbon atoms, are reported. Volumes of ionization have been determined and the electrostriction of the solvent calculated. Effects of the substituents are felt up to the -carbon atom, but thereafter are only very weak or nonexistent.     

Nonlinear signal-processing model for signal generation in multilevel two-dimensional optical storage

A two-dimensional optical storage (TwoDOS) format with binary modulation is being developed in which channel bits are arranged on a two-dimensional hexagonal lattice [W. M. J. Coene, in Optical Data Storage, Vol. 88 of OSA Trends in Optics and Photonics Series (Optical Society of America, Washington, D.C., 2003), pp. 90-92]. The aim is to increase the capacity by a factor of 2 and the data rate by a factor of 10 over third-generation Blu-ray Disc technology. Following a route similar to that used in one-dimensional conventional optical storage [Jpn. J. Appl. Phys. 42, 1074 (2003)] could lead to a further increase in capacity by the addition of another dimension to writing data, such as the use of multiple levels instead of the two levels (pit and land) used in the binary TwoDOS disk format. We present a nonlinear signal-processing model for signal waveform generation as a function of the M-ary channel symbols, as well as simulated signal readouts for multilevel TwoDOS.     

Bending analysis of thin functionally graded plates using generalized differential quadrature method

In this paper, the differential quadrature (DQ) method is presented for easy and effective analysis of isotropic functionally graded (FG) and functionally graded coated (FGC) thin plates with constant Poisson’s ratio and varying Young’s modulus in the thickness direction. The bending of FG and FGC plates under transverse loading has been studied using the polynomial differential quadrature (PDQ) and the harmonic differential quadrature (HDQ) methods. A three-dimensional elasticity solution for a moderately thick FG plate with exponential Young’s modulus is used as the benchmark. Two examples, including a thin FG rectangular plate and a thin FGC rectangular plate with sigmoidal Young’s modulus, are investigated. The numerical results of PDQ and HDQ methods reveal good agreement with other solutions. Also, it is shown that the formulations for thin FG plates and homogeneous plates are similar, except that the plane strain components of the middle surface in FG plates are not zero.     

Partial molar volumes of organic compounds in water. III. Carbohydrates

Partial molar volumes in water at 25°C have been determined for a number of carbohydrates, including mono-, di-, tri-, tetra-, penta-, hexa-, hepta-, and polysaccharides and their derivatives. The experimental values can be calculated from the van der Waals volumes of the molecules if account is taken of the shrinkage in volume caused by hydrogen-bonding of solvent molecules to the hydroxyl groups of the sugars.     

A novel bis tridentate bipyridine carboxamide ligand and its complexation to copper(II): synthesis, structure, and magnetism

A new bis tridentate ligand 2,2'-bipyridine-3,3'-[2-pyridinecarboxamide] H(2)L(1) which can bind transition metal ions has been synthesized via the condensation of 3,3'-diamino-2,2'-bipyridine together with 2-pyridine carbonyl chloride. Two copper(II) coordination compounds have been prepared and characterized: [Cu(2)(L(1))(hfac)(2)].3CH(3)CN.H(2)O (1) and [Cu(2)(L(1))Cl(2)].CH(3)CN (2). The single-crystal X-ray structures reveal that complex 1 crystallizes in the triclinic space group P1, with the unit cell parameters a = 12.7185(6) A, b = 17.3792(9) A, c = 19.4696(8) A, alpha = 110.827(2) degrees, beta = 99.890(3) degrees, gamma = 97.966(3) degrees, V = 3868.3(3) A3, Z = 4, R = 0.0321 and R(w) = 0.0826. Complex 2 crystallizes in the monoclinic space group P2(1)/n with the unit cell parameters a = 12.8622(12) A, b = 9.6100(10) A, c = 19.897(2) A, beta = 102.027(3) degrees, V = 2405.3(4) A(3), Z = 4, R = 0.0409 and R(w) = 0.1005. In both complexes the ligand is in the dianionic form and coordinates the divalent Cu(II) ions via one amido and two pyridine nitrogen donor atoms. In 1, the coordination geometry around both Cu(II) ions is best described as distorted trigonal bipyramidal where the remaining two coordination sites are satisfied by hexafluoroacetylacetonate counterions. In 2 both Cu(II )ions adopt a (4 + 1) distorted square pyramidal geometry. One copper forms a longer apical bond to an adjacent carbonyl oxygen atom, whereas the second copper is chelated to a neighboring Cu-Cl chloride ion to afford a mu-Cl-bridged dimerized [Cu(2)(L(1))Cl(2)](2) complex. The magnetic susceptibility data for 1 (2 -270 K), reveal the occurrence of weak antiferromagnetic interactions between the Cu(II) ions. In contrast, variable-temperature magnetic susceptibility measurements for 2 reveal more complex magnetic properties, with the presence of a weak antiferromagnetic exchange (J = -10.1 K) between the copper ions in each dinuclear copper complex and a stronger ferromagnetic exchange interaction (J = 32.9 K) between the Cu(II) ions of the Cu(mu-Cl)(2)Cu dimeric bridging units.