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We have studied the electric-field-driven motion of a polaron by solving the
time-dependent Schr\"{o}dinger equation nonadiabatically and the lattice
equation of motion simultaneously. It is found that the polaron may
experience two sequent transitions under high fields; one is the
transition from the subsonic to the supersonic state, and the other from the
supersonic to dissociated state. The acoustic mode is decoupled from the
charge when the polaron moves at a speed faster than the sound speed, and
then the optical mode is decoupled at the second transition to make the
polaron dissociate completely. 相似文献
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Organic quantum well and superlattice characteristics in quasi-one-dimensional multiblock copolymers
A tight-binding calculation was presented to describe multiblock copolymers, such as [...-(PA)x-(PPP)y-...] composed of PA (polyacetylene) and PPP (poly(p-phenylene). It is found that a copolymer has a quantum well and superlattice characteristics, and evident is the effect of the composite lengths, the interfacial couplings and the electron-phonon interactions on the electronic properties of a copolymer. The quantum tunneling, the Franz-Keldysh effect and the quantum confinement can be generated under an applied electric field. These results were compared to those of traditional inorganic quantum well and superlattice systems. 相似文献
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对20Cr13不锈钢经过1 030 ℃淬火后在不同温度下进行回火处理,分析了回火温度对20Cr13不锈钢组织硬度的影响,采用自制的旋转冲刷腐蚀试验机研究了在0.5M H2SO4液固两相流条件下,回火温度对20Cr13不锈钢冲刷腐蚀性能的影响,利用扫描电镜观察了试样冲刷腐蚀表面的微观形貌,探讨了其冲刷腐蚀机理. 结果表明:20Cr13不锈钢经淬火后250 ℃左右回火时硬度最高;经回火处理后20Cr13不锈钢冲刷腐蚀特征表现为腐蚀作用强于冲刷作用,而冲刷强烈促进腐蚀,冲刷与腐蚀的交互作用占冲刷腐蚀总失重率的80%左右. 随着回火温度的升高,20Cr13不锈钢组织由马氏体转变为屈氏体、索氏体,碳化物颗粒逐渐长大,腐蚀量增大,冲刷腐蚀总量也增大,250 ℃左右回火时,20Cr13不锈钢抗冲刷腐蚀性能最佳. 相似文献
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介绍一种由单片机控制的传感器线性校正表格自动生成系统,该系统由一个标准检测仪和一个待生成表格的检测仪组成,两个检测仪在同一压力下同时进行数据采集,通过串口通信,生成线性校正表格。 相似文献
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高效液相色谱同时测定食品中苯甲酸、山梨酸、水扬酸和糖精钠 总被引:1,自引:0,他引:1
对不同种类的食品提出了不同的试样预处理方法,并对预处理中提取各被测化合物的溶剂的选择,提取时试样溶液酸度(pH值)的选定,以及除去干扰物质的试液净化条件等因素作了较深入的试验。经预处理后的澄清试液供高效液相色谱法(HPLC)分析。分析时采用ODS C18色谱柱对被测化合物(苯甲酸、山梨酸、水杨酸及糖精钠)进行分离,所用流动相为由甲醇及0.02 mol.L-1乙酸铵溶液按9比91(体积比)混合组成的溶液。测量中用二极管阵列检测器(DAD),检测波长为230 nm,按保留时间及特征光谱图进行定性。定量测定采用外标法,测量与各化合物浓度相对应的峰面积。四种化合物的检出限均小于0.000 1 g.L-1,用标准加入法进行了回收率试验,所得结果在82.3%~109.5%之间,计算得相对标准偏差(n=8)小于10%。 相似文献
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Copolymers which are synthesized by oligomers or homopolymers have quasi-one-dimensional structures. A tight-binding model
was suggested to study the organic quantum-well properties of triblock copolymers xPA/nPPP/yPA and xPPP/nPA/yPPP consisting
of polyacetylene (PA) and poly( p-phenylene) (PPP). It was found that the electronic density in the lowest conductive state
(LUMO) could be tuned by the ratios of homopolymers and interfacial coupling. The spontaneous quantum tunneling effects will
occur in triblock copolymer xPA/nPPP/yPA with the increasing interfacial coupling. 相似文献