γ-Fe_2O_3/NiO核-壳纳米花的合成、微结构与磁性

利用溶剂热/热分解的方法合成出微结构可控的γ-Fe_2O_3/NiO核-壳结构纳米花.分析表明NiO壳层是由单晶结构的纳米片构成,这些纳米片不规则地镶嵌在γ-Fe_2O_3核心的表面.Fe3O4/Ni(OH)_2前驱体的煅烧时间对γ-Fe_2O_3/NiO核-壳体系的晶粒生长、NiO相含量和壳层致密度均有很大的影响.振动样品磁强计和超导量子干涉仪的测试分析表明,尺寸效应、NiO相含量和铁磁-反铁磁界面耦合效应是决定γ-Fe_2O_3/NiO核-壳纳米花磁性能的重要因素.随着NiO相含量的增加,磁化强度减小,矫顽力增大.在5 K下,γ-Fe_2O_3/NiO核-壳纳米花表现出一定的交换偏置效应(H_E=46 Oe),这来自于(亚)铁磁性γ-Fe_2O_3和反铁磁性NiO之间的耦合相互作用.与此同时,这种交换耦合效应也进一步提高了样品的矫顽力(H_C=288 Oe).     

Multiple sign reversals of the exchange bias field in polycrystalline SmCr_（0.9）Fe_（0.1）O_3

We synthesize the perovskite compound Sm Cr0.9Fe0.1O3 by the sol–gel method and investigate its exchange bias properties through thermomagnetic and isothermal magnetization measurements. The sign reversals of the exchange bias field are observed at the magnetization compensation temperatures 29.6 K and 96.2 K. It is demonstrated that the occurrence of the exchange bias originates from the antiferromagnetic coupling between the Cr-rich and Fe–Cr regions, of which the net magnetization is temperature-dependent. These results imply that there are potential applications in single systems with sign reversals of both magnetization and exchange bias.     

二非正交纯态相混合的concurrence

导出了两量子比特中二非正交纯态相混合的concurrence 的明显表达式, 并作了验证. 推算表明，正交情形下的concurrence公式可以直接推广到非正交的情形. 讨论了两纯态相混合的最大纠缠混合态和一些重要特殊情形. 关键词： 量子纠缠 纯态 混合态 concurrence     

Multiferroicity in B-site ordered double perovskite Y2MnCrO6

Double perovskite manganite Y2MnCrO6 ceramic Novel multiferroic properties are displayed with respect is synthesized and its multiferroic properties are investigated. to other multiferroics, such as high ferroelectric phase transi- tion temperature, and the coexistence of ferrimagnetism and ferroelectricity. Moreover, the ferroelectric polarization of Y2MnCrO6 below the magnetic phase temperature can be effectively tuned by an external magnetic field, showing a re- markable magnetoelectric effect. These results open an effective avenue to explore magnetic multiferroics with spontaneous magnetization and ferroelectricity, as well as a high ferroelectric transition temperature.     

高效蓝色磷光铱配合物的合成、表征与发光性能研究

设计与合成了一个新颖的以二(2-二苯基磷基)苯基醚(POP)为辅助配体、2-苯基吡啶(PPY)为第一配体的蓝色磷光铱配合物[Ir(ppy)2(POP)]PF6.配合物[Ir(ppy)2(POP)]PF6的晶体结构表明金属铱采取扭曲的八面体配位构型,C,C原子采取顺式构象,N,N原子采取反式构象.配合物在聚集态下展示了明亮的蓝光发射,发射主峰位于490 nm,在464 nm处有一个小的肩峰;此外,400 nm处有一个弱的发射带,通过测试配合物的激发态寿命和密度泛函理论计算,该发射是来自于配体的T1→S0的跃迁,属于荧光;而490 nm处的发射则属磷光.