Control of reaction channels of CsI molecule by ultra-short laser pulse

The influence of the ultra-short pulse wavelength on the populations in the three electronic states of CsI molecule is investigated using the time-dependent wave packet method. The calculated results show that the populations in the two excited states approach to the maxima at the wavelengths of 369 nm and 297 nm, respectively. The photodissociation reaction channels of the CsI molecule can be chosen by controlling the pump pulse wavelength.     

Theoretical Study of the Influence of Femtosecond Laser Wavelength on the Evolution of a Double-Minimum Electronic Excited State Wave Packet for NaRb

Employing the two-state model and the time-dependent wave packet method, the influence of femtosecond laser wavelength on the evolution of the double-minimum electronic excited state wave packet is numerically investigated. For different laser wavelengths, evolutions of the double-minimum electronic excited state wave packet with time and internuclear distance are different. One can control the evolution of the wave packet by varying the laser wavelength appropriately, which will benefit the light manipulation of atomic and molecular processes. Furthermore, study of the dynamics of the NaRb molecule may yield clues to creating an ultracold molecule.     

激光场强度对NO电子态粒子数布居影响的理论研究

用含时波包方法研究了激光场强度对NO各电子态上粒子数布居的影响.在计算中,采用了四态模型.利用分裂算符傅里叶变换方法求解Schrdinger方程,得到各个电子态的波函数,从而求得各个电子态上粒子数的布居.计算结果表明,不同强度的抽运光对各个电子态上粒子数布居会产生不同的影响.通过改变激光强度可以实现对电离产率的控制,这种思想对实现原子分子过程的激光操控具有重要意义.