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1.
吡喃并[4,3-b]吡喃衍生物与牛血清白蛋白作用的荧光光谱   总被引:1,自引:0,他引:1  
用荧光光谱法分析了在生理条件下一种吡喃并[4,3-b]吡喃衍生物—2-氨基-7-甲基-4-(4-硝基苯)-5-氧代-4H,5H-吡喃并[4,3-b]吡喃-3-腈与牛血清白蛋白的作用机制。求得不同温度下二者的结合常数和结合位点数,探讨了微量金属离子对实验体系结合常数的影响,并根据热力学参数确定了这种吡喃并[4,3-b]吡喃衍生物与牛血清白蛋白之间的作用力类型。根据Frster非辐射能量转移机理,测定了这种吡喃并[4,3-b]吡喃衍生物与牛血清白蛋白相互结合时,能量给体-受体间的作用距离和能量转移效率,并用同步和三维荧光技术讨论了其衍生物对牛血清白蛋白构象的影响。结果表明,吡喃并[4,3-b]吡喃衍生物主要以静态猝灭方式使牛血清白蛋白荧光强度显著降低,二者主要凭借氢键和范德华力结合。  相似文献   
2.
梁晶  吴江宁 《运筹与管理》2010,19(4):150-153,159
本文从市场中客户对企业提出的各种需求出发,建立了一个面向客户需求的知识传播网络,并通过计算机仿真模拟了企业集群在此网络中的知识传播过程,考察了集群的平均知识水平和知识方差在传播过程中的动态变化。通过仿真发现:随着时间的推移和对客户需求的满足,集群的平均知识水平呈单调递增趋势,知识传播效率呈现先增后减规律;集群知识方差在传播前期会出现剧烈震荡现象,而后期则会逐渐收敛;此外本文对市场规模以及知识维度对知识水平的影响也做了简单的考察,发现小规模市场有利于企业集群的初期发展,而过高或过低的知识维度都不利于企业集群平均知识水平的提高。  相似文献   
3.
利用稻/麦O3-FACE(Ozone-free air controlled enrichment)平台,以武运粳21和两优培九两个耐性不同的水稻品种为材料,模拟研究了近地层大气臭氧浓度升高情形下对水稻叶片气体交换和荧光参数的影响。结果表明:高臭氧浓度降低了两个品种水稻叶片的净光合速率、气孔导度以及蒸腾速率,处理76天后,武运粳21的降幅分别为:21.7%,26.64%和24.74%,两优培九的降幅分别为:25.53%,30.31%和25.48%,而对两个品种胞间CO2浓度的影响不显著;水稻叶片荧光动力学参数F0(暗下初始荧光)、ETR(表观电子传递速率)和ФPSⅡ(PSⅡ实际光化学量子产量)呈下降趋势,NPQ(非光化学猝灭系数)逐渐上升,处理76天后武运粳21和两优培九分别上升了16.37%和11.77%。臭氧的影响有一定的累积效应,随着处理时间的延长,相关指标变化幅度增大。高臭氧浓度下水稻叶片胞间CO2浓度没有显著降低,推断臭氧导致的净光合速率的降低是由非气孔限制因素引起。结果表明,两优培九比武运粳21对臭氧响应敏感。  相似文献   
4.
本文在Georgescu模糊选择函数意义下,研究了一些模糊合理性条件之间的关系及模糊选择函数的拟传递合理性。首先,给出了模糊选择函数合理性条件FA1,条件FA2与条件Fγ的定义,研究了模糊选择函数G-合理性与条件FA1之间的关系。其次对合理性条件FA2,条件FPI及条件Fδ之间的关系进行了详细的讨论。最后得出了模糊选择函数拟传递合理的三个充分条件。  相似文献   
5.
激光驱动气库材料可用于实现准等熵压缩,为了预估样品靶前表面的峰值压力及分析样品靶前表面压力随时间变化曲线,建立了一个简化的理论模型用于描述这一物理过程。激光入射在气库材料上产生冲击波,冲击波到达气库材料背表面卸载使其成为等离子体,进而在真空中自由膨胀。在膨胀的过程中,等离子体密度、温度不断降低,并堆积在样品前端使样品表面的温度、压力缓慢上升,实现准等熵压缩。将气库材料近似为多方气体,对其进行分层处理,求解得到每一层等离子体自由膨胀的解析解,进而编写程序计算多层等离子体堆积在样品前端压力随时间变化曲线。与实验上获得样品自由面粒子速度后用背积分方法获得的样品前端压力随时间变化曲线进行对比,较为吻合,表明这种模型可以用于预估样品前端压力。  相似文献   
6.
 利用经典分子动力学和第一性原理分子动力学,研究了氦在高压下的熔化曲线、状态方程和非金属-金属转变。得到了氦在温度小于4.5 eV、 密度0.3~5.0 g/cm3范围内的状态方程,并把氦的熔化曲线的压强范围拓展到了50 GPa。氦的能隙宽度曲线表明,温度大大降低了氦的金属化密度。  相似文献   
7.
Nonlinear optical frequency mixing,which describes new frequencies generation by exciting nonlinear materials with intense light field,has drawn vast interests in the field of photonic devices,material characterization,and optical imaging.Investigating and manipulating the nonlinear optical response of target materials lead us to reveal hidden physics and develop applications in optical devices.Here,we report the realization of facile manipulation of nonlinear optical responses in the example system of MoS2 monolayer by van der Waals interfacial engineering.We found that,the interfacing of monolayer graphene will weaken the exciton oscillator strength in MoS2 monolayer and correspondingly suppress the second harmonic generation(SHG)intensity to 30%under band-gap resonance excitation.While with off-resonance excitation,the SHG intensity would enhance up to 130%,which is conjectured to be induced by the interlayer excitation between MoS2 and graphene.Our investigation provides an effective method for controlling nonlinear optical properties of two-dimensional materials and therefore facilitates their future applications in optoelectronic and photonic devices.  相似文献   
8.
Chang Liu 《中国物理 B》2021,30(12):127802-127802
Improving the emission performance of colloidal quantum dots (QDs) is of paramount importance for their applications on light-emitting diodes (LEDs), displays and lasers. A highly promising approach is to tune the carrier recombination channels and lifetime by exploiting the energy transfer process. However, to achieve this precise emission optimization, quantitative modulation on energy transfer efficiency is highly desirable but still challenging. Here, we demonstrate a convenient approach to realize tunable energy transfer efficiency by forming QDs mixture with controllable donor/acceptor (D/A) ratio. With the mixing ratio ranging from 16/1 to 1/16, the energy transfer efficiency could be effectively tuned from near zero to ~70%. For the high mixing ratio of 16/1, acceptors obtain adequate energy supplied by closely surrounding donors, leading to~2.4-fold PL enhancement. While for the low mixing ratio, the ultrafast and efficient energy extraction process directly suppresses the multi-exciton and Auger recombination in the donor, bringing about a higher threshold. The facile modulation of emission performance by controllably designed mixing ratio and quantitatively tunable energy transfer efficiency will facilitate QD-based optoelectronic and photovoltaic applications.  相似文献   
9.
The electronic topology is generally related to the Berry curvature,which can induce the anomalous Hall effect in time-reversal symmetry breaking systems.Intrinsic monolayer transition metal dichalcogenides possesses two nonequivalent K and K’ valleys,having Berry curvatures with opposite signs,and thus vanishing anomalous Hall effect in this system.Here we report the experimental realization of asymmetrical distribution of Berry curvature in a single valley in monolayer WSe2 via applying uniaxial strain to break C3v symmetry.As a result,although the Berry curvature itself is still opposite in K and K’ valleys,the two valleys would contribute equally to nonzero Berry curvature dipole.Upon applying electric field E,the emergent Berry curvature dipole D would lead to an out-of-plane orbital magnetization M ∝ D·E,which further induces an anomalous Hall effect with a linear response to E2,known as nonlinear Hall effect.We show the strain modulated transport properties of nonlinear Hall effect in monolayer WSe2 with moderate hole-doping by gating.The second-harmonic Hall signals show quadratic dependence on electric field,and the corresponding orbital magnetization per current density M/J can reach as large as 60.In contrast to the conventional Rashba-Edelstein effect with in-plane spin polarization,such current-induced orbital magnetization is along the out-of-plane direction,thus promising for high-efficient electrical switching of perpendicular magnetization.  相似文献   
10.
用于冲击诊断的成像速度干涉仪   总被引:2,自引:0,他引:2       下载免费PDF全文
为了诊断测量激光驱动冲击波,研制了具有空间分辨力的成像型速度干涉仪.该干涉仪主要包括输入部分、像传递部分及干涉部分,探测光采用波长为532 nm的单纵模激光.在靶位放置一分线板,经过测量,其空间分辨力小于10μm.基于天光KrF准分子激光系统的参数,设计并自制含有烧蚀层的单台阶金属靶,利用成像型速度干涉仪测量到了金属铝...  相似文献   
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