CdTe纳米晶与苯丙氨酸相互作用的研究

以巯基乙酸为稳定剂,在水相中合成了CdTe纳米晶,通过考察红外光谱、紫外光谱和光致发光光谱的变化,确定了苯丙氨酸(Phe)对CdTe纳米晶的光致发光效率以及稳定性的影响.结果表明苯丙氨酸与CdTe纳米晶之间存在着较强的相互作用,这种作用导致CdTe纳米晶的发光强度增大,稳定性增强,苯丙氨酸不仅是配位剂,它同时又起到了稳定剂的作用,并初步确认这种加强和稳定作用来自于苯丙氨酸和CdTe纳米晶之间所形成的配位键和静电作用以及苯丙氨酸与巯基乙酸之间形成的氢键.此外,苯丙氨酸的特殊结构对防止纳米晶的聚集有很大作用.     

电极活性材料精细结构与MH-Ni电池性能关系研究的一些进展

为了更深入地研究正负极活性材料精细结构与MH-Ni电池性能之间的关系,本文在介绍了简单而较适用的处理X射线衍射数据的方法之后,系统综述了电池活化前后、循环过程中正负极活性物质结构和微结构与电池性能之间关系研究的一些进展.主要包括:(1)具有适当晶粒大小和较大层错几率的βNi(OH)2物质,能获得较大的充放电容量;(2)没有观测到MH/Ni电池在充放电过程中有β-Ni(OH)2 β-NiOOH的相变,只有满充和过充电时才发生部份β-Ni(OH)2 γNiOOH的相变;MH/Ni电池的物理导电机制是在正负极活性物质中嵌入和脱嵌的氢离子形成固相质子在电极间定向运动.(3)循环性能的衰减、内阻、容量的变化与正负极活性物质的微结构变化有良好对应关系.微结构变化消耗电解液,并改变电解液的性能.正极、负极和电解液三者的共同作用是循环性能衰减的主导原因.(4)正极添加剂与电池性能之间的关系.由于正极添加剂Lu2O3和CaF2能抑制正极活性物质的微晶细化、减缓总的层错几率降低,对于储氢合金能抑制品粒增大,特别能抑制A(0H)3和B的析出,故能提高了电池的循环性能和寿命.(5)电池储存前后的容量衰减和内阻增加是其在储存过程中CoOOH析出和晶粒细化双重作用的结果.     

Design and FPGA implementation of multi-wing chaotic switched systems based on a quadratic transformation

Based on a quadratic transformation and a switching function,a novel multi-wing chaotic switched system is proposed.First,a 4-wing chaotic system is constructed from a 2-wing chaotic system on the basis of a quadratic transformation.Then,a switching function is designed and by adjusting the switching function,the number and the distribution of the saddle-focus equilibrium points of the switched system can be regulated.Thus,a set of chaotic switched systems,which can produce 6-to-8-12-16-wing attractors,are generated.The Lyapunov exponent spectra,bifurcation diagrams,and Poincarémaps are given to verify the existence of the chaotic attractors.Besides,the digital circuit of the multi-wing chaotic switched system is designed by using the Verilog HDL fixed-point algorithm and the state machine control.Finally,the multi-wing chaotic attractors are demonstrated via FPGA platform.The experimental results show that the number of the wings of the chaotic attractors can be expanded more effectively with the combination of the quadratic transformation and the switching function methods.     

Design and FPGA implementation of a memristor-based multi-scroll hyperchaotic system

A novel memristor-based multi-scroll hyperchaotic system is proposed. Based on a voltage-controlled memristor and a modulating sine nonlinear function, a novel method is proposed to generate the multi-scroll hyperchaotic attractors. Firstly, a multi-scroll chaotic system is constructed from a three-dimensional chaotic system by designing a modulating sine nonlinear function. Then, a voltage-controlled memristor is introduced into the above-designed multi-scroll chaotic system. Thus, a memristor-based multi-scroll hyperchaotic system is generated, and this hyperchaotic system can produce various coexisting hyperchaotic attractors with different topological structures. Moreover, different number of scrolls and different topological attractors can be obtained by varying the initial conditions of this system without changing the system parameters. The Lyapunov exponents, bifurcation diagrams and basins of attraction are given to analyze the dynamical characteristics of the multi-scroll hyperchaotic system. Besides, the field programmable gate array (FPGA) based digital implementation of the memristor-based multi-scroll hyperchaotic system is carried out. The experimental results of the FPGA-based digital circuit are displayed on the oscilloscope.     

线性变换的右拟线性内逆的存在性

引入线性空间中线性变换的拟线性内逆的概念,给出拟线性内逆存在的充要条件,同时给出拟线性内逆与拟线性可补的对应关系.     

N-(溴代-2-吡咯甲酰基)氨基酸甲酯的合成

在室温条件下, 2-三氯乙酰基吡咯经溴代反应, 再与氨基酸甲酯反应得到一系列N-(溴代-2-吡咯甲酰基)氨基酸甲酯, 收率为64.8%～92.2%. 通过元素分析, ¹H NMR, IR和MS对产物结构进行了表征, 培养了N-(1-甲基-4,5-二溴-2-吡咯甲酰基)甘氨酸甲酯的单晶并进行单晶X射线衍射分析. 初步活性试验表明, 目标产物对金黄色葡萄球菌、粪链球菌等五种细菌有一定的抑制作用.     

Defects and hyperfine interactions in binary Fe-Al alloys studied by positron annihilation and Mössbauer spectroscopies

The defects, the behavior of 3d electrons and the hyperfine interactions in binary Fe-Al alloys with different Al contents have been studied by measurements of positron lifetime spectra, coincidence Doppler broadening spectra of positron annihilation radiation and Mössbauer spectra. The results show that on increasing the Al content in Fe-Al alloys, the mean positron lifetime of the alloys increase, while the mean electron density of the alloys decrease. The increase of Al content in binary Fe-Al alloys will decrease the amount of unpaired 3d electrons; as a consequence the probability of positron annihilation with 3d electrons and the hyperfine field decrease rapidly. Mössbauer spectra of binary Fe-Al alloys with Al content less than 25 at.% show discrete sextets and these alloys make a ferromagnetic contribution at room temperature. The Mössbauer spectrum of Fe₇₀Al₃₀ shows a broad singlet. As Al content higher than 40 at.%, the Mössbauer spectra of these alloys are singlet, that is, the alloys are paramagnetic. The behavior of a 3d electron and its effect on the hyperfine field of the binary Fe-Al alloy has been discussed.     

基于光谱指数法的植被含水量遥感定量监测及分析

在分析植被光谱特征与光谱和植被水分相关性的基础上,初步确定几个波段或波段组合为植被含水量的光谱指数.利用数据对植被含水量FMC(Fuel Moisture Content)与上述水份光谱指数分别建立最优函数关系.通过分析不同光谱指数的关系及其相对误差,确定以1600 nm和820 nm处反射率的比值SR作为建立本研究区植被含水量模型的特征参数;并利用实测光谱反射率与植被含水量建立SR与FMC之间的模型关系.根据植被含水量模型、ETM和ASTER遥感数据.在IDL7.0开发平台下实现研究区植被含水量的定量反演,并利用区内实测数据和本底调查数据对反演结果进行了综合评价与分析.结果表明,光谱指数SR可以较好地剔除环境背景以及冠层结构等外界因素的影响,植被含水量遥感反演精度较高,能真实反映研究区植被含水量的时空变化规律与特征.     

修正的F展开法和推广的KdV方程新的孤波解和精确解

对F展开法进行了修正，附加含任意常数的负指数项，解决了精确解的奇点问题.用此方法讨论推广的KdV方程的周期波解.在特别情形下，获得了新的Jacobi椭圆函数精确解、孤波解和三角函数解. 关键词： 齐次平衡原则 F展开法 推广的KdV方程 孤波解     

MH/Ni电池充放电过程导电物理机制的研究

借助X射线衍射等方法, 研究了MH/Ni电池在充放电过程中电极活性材料β-Ni(OH)2和AB5合金的结构和微结构变化, 进而讨论了两种电极活性材料在充放电过程中的物理行为和导电的物理机制. 研究发现, 在充电过程中确实未观测到β-Ni(OH)2→β-NiOOH的相变, 只有在满充和过充时, 才发生部分β-Ni(OH)2转变成γ-NiOOH, 且一直是β-Ni(OH)2和γ-NiOOH两相共存; 在充电过程不是由β-Ni(OH)2→β-NiOOH相变来提供氢离子, 而是由氢原子离开β-Ni(OH)2的点阵位置提供氢离子; 在负极这一边, 开始时氢原子是以间隙式嵌入AB5点阵形成固溶体, 只有当AB5因氢原子的嵌入使其体积变化达一定百分数后才析出AB5Hx氢化物. 这些过程使电极活性材料的微结构也发生变化, 而且这种变化不是完全可逆的. 简言之, MH/Ni电池的物理导电机制是在正负极活性材料中嵌入和脱嵌的氢离子在电极间的定向迁移运动.