钙钛矿/硅异质结叠层太阳电池:光学模拟的研究进展

近几年,钙钛矿/硅异质结叠层太阳电池发展迅速,效率已经从13.7%提升到29.1%.由于叠层电池器件的制作工艺复杂,而叠层太阳电池中的光学损失对转换效率的影响很大,所以通过光学模拟进而获得高效电池至关重要.本文首先从商业软件和自建模型两方面概述了光学模拟的方法,接着从反射损失和寄生吸收两方面针对光学模拟研究进展进行了总结和分析,最后指出了叠层电池光学模拟过程中需要注意的问题.钙钛矿/硅异质结叠层太阳电池的转换效率极限最高可达40%,具备很大的提升空间,结合模拟工作的研究,叠层电池的发展将会取得更大的进步.     

Form invariance and conserved quantities of Nielsen equations of relativistic variable mass nonholonomic systems

In this paper, the definition and criterion of the form invariance of Nielsen equations for relativistic variable mass nonholonomic systems are given. The relation between the form invariance and the Noether symmetry is studied.Finally, we give an example to illustrate the application of the result.     

非完整力学系统Raitzin正则方程的形式不变性

研究非完整力学系统Raitzin正则方程的形式不变性。建立系统的Raitzin正则方程。给出在无限小变换下系统形式不变性的定义和判据。得到系统的守恒量与形式不变性之间的关系并举例说明结果的应用。     

准坐标下完整力学系统的非Noether守恒量——Hojman定理的推广

利用时间不变的无限小变换下的Lie对称性，研究准坐标下完整力学系统的一类新守恒量.建立系统的运动微分方程，给出无限小变换下的Lie对称性确定方程.将Hojman定理推广，并举例说明结果的应用. 关键词： 准坐标 完整力学系统 Lie对称性 非Noether守恒量 Hojman定理     

Integrating factors and conservation theorems of constrained Birkhoffian systems

In this paper the conservation theorems of the constrained Birkhoffian systems are studied by using the method of integrating factors. The differential equations of motion of the system are written. The definition of integrating factors is given for the system. The necessary conditions for the existence of the conserved quantity for the system are studied. The conservation theorem and its inverse for the system are established. Finally, an example is given to illustrate the application of the results.     

事件空间中非完整非保守系统的守恒量存在定理及其逆定理

提出了事件空间中非完整非保守系统守恒定律构成的一般途径.首先，列写系统的运动微分方程，给出积分因子的定义.其次，详细地研究了守恒量存在的必要条件，并建立了事件空间中非完整非保守系统的守恒量存在定理及其逆定理.最后，举例说明结果的应用. 关键词： 事件空间 非完整非保守系统 积分因子 守恒定理     

Exact invariants and adiabatic invariants of Raitzin＇s canonical equations of motion for a nonlinear nonholonomic mechanical system

The exact invariants and the adiabatic invariants of Raitzin＇s canonical equations of motion for a nonlinear nonholonomic mechanical system are studied. The relations between the invariants and the symmetries of the system are established. Based on the concept of higher-order adiabatic invariant of a mechanical system under the action of a small perturbation, the forms of the exact invariants and adiabatic invariants and the conditions for their existence are proved. Finally, the inverse problem of the perturbation to symmetries of the system is studied and an example is also given to illustrate the application of the results.     

Integrating factors and conservation theorems for Hamilton‘s canonical equations of motion of variable mass nonholonmic nonconservative dynamical systems

We present a general approach to the construction of conservation laws for variable mass noholonmic nonconservative systems.First,we give the definition of integrating factors,and we study in detail the necessary conditions for the existence of the conserved quantities,Then,we establish the conservatioin theorem and its inverse theorem for Hamilton‘s canonical equations of motion of variable mass nonholonomic nonocnservative dynamical systems.Finally,we give an example to illustrate the application of the results.     

超高压对蛋白质的影响

在现有的超高压对蛋白质影响研究的基础上,详细地总结了超高压对蛋白质的分子体积、非共价键和分子结构的影响。在超高压作用下,蛋白质的分子体积被压缩变小;压力通过改变蛋白质分子的氢键、离子键、水合作用和疏水相互作用来影响蛋白质结构;低于800MPa的压力会造成蛋白质分子的二级、三级和四级结构的改变,其中四级结构对压力最敏感,三级结构次之,二级结构的改变较小;高于8GPa的压力会影响蛋白质分子的一级结构。     

金属氧化物修饰对介孔纳米TiO2电极的染料敏化太阳能电池电化学性能的影响

将介孔TiO₂纳米粒子(m-TiO₂)多孔膜电极浸入相应的金属硝酸盐的500 oC热处理修饰金属氧化物(如Mg、ZnO、Al₂O₃或NiO).结果表明,金属氧化物修饰均可形成能垒对m-TiO₂膜电极的界面电荷传输过程产生影响,但外加偏压下其膜内电子传输和界面电荷复合均明显依赖于修饰氧化物的种类及其存在形态. 金属氧化物修饰的膜电极在电子传输和界面复合方面的变化与DSSCs的电流-电压特性曲线的变化规律具有明显的相关性,可不同程度地提高电池的光电压,而MgO、ZnO和NiO修饰的电池效率分别提高了23%、13%和6%. 上述结果表明调控电池的本征参数可以改善TiO₂-基DSSCs的性能.