Structural evolution study of additions of Sb_2S_3 and CdS into GeS_2 chalcogenide glass by Raman spectroscopy

The structures of pseudo-binary GeS_2–Sb_2S_3, GeS_2–CdS, Sb_2S_3–CdS, and pseudo-ternary GeS_2–Sb_2S_3–CdS chalcogenide systems are systematically investigated by Raman spectroscopy. It is shown that a small number of [S_3Ge–GeS_3]structural units(SUs) and-S-S-/S8 groups exist simultaneously in GeS_2 glass which has a three-dimensional continuous network backbone consisting of cross-linked corner-sharing and edge-sharing [GeS_4] tetrahedra. When Sb_2S_3 is added into GeS_2 glass, the network backbone becomes interconnected [GeS_4] tetrahedra and [SbS_3] pyramids. Moreover, Ge atoms in[S_3Ge–GeS_3] SUs tend to capture S atoms from Sb_2S_3, leading to the formation of [S_2Sb–SbS_2] SUs. When CdS is added into GeS_2 glass, [Cd_4GeS_6] polyhedra are formed, resulting in a strong crystallization tendency. In addition, Ge atoms in[S_3Ge–GeS_3] SUs tend to capture S atoms from CdS, resulting in the dissolution of Ge–Ge bond. Co-melting of Sb_2S_3 or CdS with GeS_2 reduces the viscosity of the melt and improves the homogeneity of the glass. The GeS_2 glass can only dissolve up to 10-mol% CdS without crystallization. In comparison, GeS_2–Sb_2S_3 glasses can dissolve up to 20-mol% CdS,implying that Sb_2S_3 could delay the construction of [Cd_4GeS_6] polyhedron and increase the dissolving amount of CdS in the glass.     

基于Etendue和显色特性的内窥镜LED照明系统的设计

根据内窥镜的使用要求,以Etendue的分析为基础,提供了一种内窥镜光纤照明系统。采用多个白光LED (W-LED)作为光源,提高了光通量,并对W-LED缺陷波段进行补色,通过移动补色光中心波长位置和调节光强度,有效地提高了显色指数。采用环形光纤,改善了光场角分布和白光与青色光的混光。给出了理论分析与计算、光学系统的优化设计与仿真的结果。实验得到了远场175.421m的光能量和87.7的显色指数,完全可以满足内窥镜照明系统的使用要求。     

LED广色域投影显示系统实时色域校准的研究

针对LED广色域投影显示系统中色域过大带来颜色失真的问题,在时序工作方式中,采用在一个基色光工作时,同时加入一定比例的其他基色光作为辅助光,将该基色光的色品坐标移到所需位置的色域校准方法。另外,为了避免LED一致性差异和环境温度变化及工作时间对LED主波长和色品坐标造成的影响,提出利用一组XYZ色度传感器实时测量并反馈三基色LED色品坐标的方法。该方法通过对色域校准算法编程实现实时色域校准,达到了正确显示颜色的目的。     

Mid-infrared luminescence of Dy~(3+)-doped Ga_2S_3–Sb_2S_3–CsI chalcohalide glasses

The mid-infrared(MIR) luminescent properties of Dy~(3+) ions in a new chalcohalide glass host, Ga_2S_3–Sb_2S_3–CsI,are investigated; and the suitability of the doped glass for MIR fiber lasers is evaluated. The Dy~(3+)-doped chalcohalide glasses exhibit good thermal stability and intense MIR emissions around 2.96 μm and 4.41 μm. These emissions show quantum efficiencies(η) as high as ~60%, and have relatively large stimulated emission cross sections(σem). The low phonon energy(~307 cm~(-1)) of the host glass accounts for the intense MIR emissions, as well as the high η. These favorable thermal and emission properties make the Dy~(3+)-doped Ga_2S_3–Sb_2S_3–CsI glasses promising materials for MIR fiber amplifiers or lasers.