Bi-1212相和Bi-1222相铜氧化合物的合成和超导电性

对名义组份为(Bi_(1-x),M_x)Sr_2YCu_2O_y(x=0.6—0.7)的样品,当M=Cd,Ni和Zn时合成了Bi-1212相材料,实验发现Cd占据Bi位,可以稳定单BiO层,高压氧下退火,在32K出现超导转变,而Zn和Ni进入CuO平面,占据Cu位,破坏了材料的超导电性。用Cd稳定单BiO层还能够合成Bi-1222相化合物,它的固溶范围比Bi-1212大,对这一现像进行了结构上的分析。在不同氧压退火处理下的Bi-1222相样品,电阻随氧压增大而变小,但在4.2K以上未观察到超导转变。 关键词：     

CRYSTAL STRUCTURE INVESTIGATION OF VANADYL COMPLEXES OF TRIDENTATE LIGAND (Ⅰ)——THE CRYSTAL STRUCTURES OF BIS[(1-(2,4-PENTANE- DIONATO(NITROBENZOYL) HYDRAZONE)-2- ETHOXY)OXOVANADIUM] AND BIS-[(1-(2, 4-PENTANEDIONATO-(3-NITROBENZOYL) HYDRAZONE)-2- METHO

The title complexes were obtained by the reactions of bis(2,4-pentanedionato)oxovanadium VO(Acac)_2 and m-nitrophenylhydrazide m-NO_2PhCONHNH_2 in the media EtOH and MeOH respectively. The compound (Ⅰ) crystallizes in the space group PT with unit cell dimensions a=8.123(2), b=10.409(5), c=10.822(4), α=65.78(3)°, β=85.50(3)°,γ=89.04(3)°. The compound (Ⅱ) crystallizes in the space group P2_1/a with unit cell dimensions a=7.745(2), b=19.164(5), c=10.787(4), β=107.87(2)°. The resuhs of structural analyses show that the two compounds have the same characteristics: the tridentate ligand formed by condensation occupies three of the four equatorial positions of vanadium and the rest equatorial position is occupied by alkoxy group RO~-. As RO~-group also bridges the sixth coordinated position of each vanadium atom, it brings about the formation of the new type binuclear complexes of vanadium.     

(Bi,Cd)Sr_2(Ln,Ce)_nCu_2O_y超导体及界面反应的光电子能谱研究

用光电子能谱研究了(Bi.Cd)Sr_2(Ln,Ce)_(?)Cu_2O_y的电子结构,以及其与铝之间的反应.芯能级结果表明:(Bi,Cd)Sr_2(Ln,Ce)_(?)Cu_2O_y系列中n=1,2和3三种材料的结果基本一致,并且类似其它超导材料中相同元素的芯能级结果.在(Bi,Cd)Sr_2(Ln,Ce)_(?)Cu_2O_y与铝的界面处,铝与(Bi,Cd)Sr_2(Ln,Ce)_(?)Cu_2O_y中的元素发生强烈反应,Bi—O,Sr—O和Cu—O键受到破坏,铜的价态从+2变为+1,并且同时伴随着超 关键词：     

ELECTRONIC STRUCTURE OF THE T*-TYPE SUPERCONDUCTORS (Bi0.5Sr1.5)(Y, Ce)2Cu2Oy STUDIED BY PHOTOELECTRON SPECTROSCOPY

The electronic structure of T^*-type compounds (Bi_0.5Sr_1.5)(Y_2-xCe_x)Cu₂O_y has been studied by X-ray photoelectron spectroscopy. From analysis of the results, it was found that cation deficiency in Ce⁴⁺ introduced holes to conduction planes in the T^* phase as in the p-type infinite layer compounds. Some Cu ions in the sample without cation-deficiency contained two-oxygen coordination, which resulted in the incompleteness of the CuO₂ sheets. Bi ions in the T^* phase cuprates take exact valence of 3_{+, Pb ions cannot replace them due to the too large an ionic radius of Pb²⁺/Pb⁴⁺.}     

常压下Hg系1201相超导铜氧化合物的合成

本首次报道常压下Ｈｇ系１２０１相超导铜氧化合物的制备，方法简便，制备样品质量较好，超导转变温度达９４Ｋ。作还进行一步讨论了１２０１相常压下制备的最佳成相条件及其物相的稳定性。     

三齿配体酰(氧)钒配合物的晶体结构研究——Ⅰ.双聚{1-(2,4-戊二酮-(3-硝基苯甲酰)-单腙-2-乙氧基合氧钒(Ⅳ)}和双聚{1-(2,4-戊二酮-(3-硝基苯甲酰)-单腙-2-甲氧基合氧钒(Ⅳ)的晶体结构

以二乙酰丙酮氧钒VO(Acac)_2与间硝基苯甲酰肼m-NO_2PhCONHNH_2分别在乙醇和甲醇中反应,得[VO(C_(12)H_(12)N_3O_4)(C_2H_5O)]_2(Ⅰ)和[VO(C_(12)H_(12)N_3O_4)(CH_3O)]_2(Ⅱ)两种晶体。晶体(Ⅰ)属空间群P(?),晶胞参数a=8.123(2),b=10.409(5),c=10.822(4),α=65.78(3)°,β=85.50(3)°,r=89.04(3)°。晶体(Ⅱ)属空间群P2_1/a,a=7.745(2),b=19.164(5),c=10.787(4),β=107.87(2)°。两个晶体均具有共同的结构特征:通过缩合形成的三齿配体占据四个赤道配位位置中的三个,男一个赤道配位位置由醇氧基RO~-所补充而RO~-中的氧原子又兼作桥氧向另一个钒原子的第六位配位,从而导致文献中未报道过的新型双核钒配合物的形成。     

SYNTHESIS AT AMBIENT PRESSURE AND SUPERCONDUCTIVITY OF Hg-DOPED TI-BASED DOUBLE [(T1, Hg)-O]-LAYERED CDPHATES

The Hg-doped T1-based 2201 and 2212 phase layered cuprates have been successfully syn-thesized at ambient pressure and identified by X-ray powder diffraction and electron diffraction analysis. Compared with pure T1-based 2212 phase compound, there are indications that the corresponding Hg-doped T1-based compound (T1_1.8Hg_0.2)Ba₂CaCu₂O_z exhibits much higher T_c (> 132K).     

并合形成的类星体丰度及其演化

大量的观测事实揭示了类星体现象与天体间强引力相互作用或并合之间的关联 .假定类星体是由大质量天体相互碰撞和进一步并合形成的 ,采用暗物质模型对其在不同红移处的空间数密度进行了估算 .功率谱指数n =1的标准CDM模型中 ,类星体寿命t_Q=2 - 4× 10⁸a的计算结果与最新的观测数据很好地符合.对于n <1的CDM模型和混合暗物质模型,高红移处生成的类星体数密度偏低.     

大气信道对空-地光通信的影响分析

大气随机信道对激光传输性能的影响是制约空-地激光通信的重要因素之一，因此开展对大气信道的研究对实现空-地激光通信具有非常重要的意义。对激光在大气中传输特性的研究，有助于了解激光通过大气信道传输时所产生变化的特征、规律和在空-地激光通信系统设计中寻找到合理的解决方案并很好地修正、补偿其对通信链路的影响。本文对激光在大气信道中的基本传输特性及大气随机信道对激光通信的影响进行了研究，同时提出了一些相应的解决途径。     

T*相超导体(Bi,Sr)2(Y,Ce)2Cu2Oy的性质研究

研究了T^*相超导体（Bi，Sr）₂（Y，Ce）₂Cu₂O_y的成相规律，发现缓冷对T^*相单相样品的制备是有利的．淬火样品的主相物质为Ce₂Y₂O₇，完全不含T^*相结构．在室温到熔化温度的范围，热分析未观察到结构相变．在240—460℃，相对每个Cu原子超导体失氧约0.1个氧．氧气中烧结并缓冷到室温的样品在30K出现零电阻现象 关键词：