High contrast all-optical diode based on direction-dependent optical bistability within asymmetric ring cavity

We propose a simple all-optical diode which is comprised of an asymmetric ring cavity containing a two-level atomic ensemble. Attributed to spatial symmetry breaking of the ring cavity, direction-dependent optical bistability is obtained in a classical bistable system. Therefore, a giant optical non-reciprocity is generated, which guarantees an all-optical diode with a high contrast up to 22 d B. Furthermore, its application as an all-optical logic AND gate is also discussed.     

聚合型铝氢化物(AlH3)n(n=1-3)的几何结构与振动光谱的研究

采用不同方法B3P86、B3LYP、B3PW91和MP2,结合Dunning的相关一致基组cc-PVTZ,对聚合型铝氢化物(AlH3)n(n=1-3)分子的可能几何构型进行优化计算,通过比较计算结果,发现密度泛函DFT中的方法B3P86计算的能量最低．本文采用B3P86方法得出最稳定构型的几何参数、电子结构、振动频率等性质参数,并给出最稳定结构的总能量(ET)、结合能(EBT)、平均结合能(Eav)、电离势(EIP)、能隙(Eg)、费米能级(EF)和差分吸附氢原子能(Ediff)．结果表明：三种铝氢化物分子基态都为1重态,电子态都为 ; AlH3分子的最稳定几何构型为 的平面三角形结构;Al2H6为对称性乙烯式 立体结构,H-Al之间生成氢桥式三中心双电子键;Al3H9为 立体结构,也生成氢桥式三中心双电子键,但三个氢桥三中心双电子键彼此隔离．最后分析了三种氢化物的红外和拉曼光谱、平均结合能、电离势、能隙和费米能级等特性,说明(AlH3)n(n=1-3)三分子中Al3H9最稳定,H-Al桥键键长比端键更长,红外光谱强度最大,差分吸附氢原子能最大,具有较强的储氢性能．     

CH自由基在外电场中的分子结构和势能函数

运用密度泛函B3P86方法,结合Dunning的相关一致五重基cc-PV5Z,获得了CH自由基分子在不同外电场中的键长、偶极矩和振动频率等物理性质参数.通过分析物理性质参数的变化,判断离解电场所处的范围,设置合适的参数扫描该范围的单点能获得势能曲线.结果表明物理性质参数和势能值随外电场的变化而变化,且反向电场中变化幅度较大.利用Morse势模型拟合无外场下势能函数,得到的拟合参数与实验值吻合较好,采用偶极近似构建外电场下的势能函数模型,编制程序拟合对应的势能函数,得出拟合参数,进而计算临界离解电场参量,结果与数值计算值较为一致,说明构建的模型是可靠和准确的.这为分析外场下分子光谱、动力学特性和分子Stark效应冷却囚禁提供重要的理论和实验参考.     

非线性介观电路中的崩塌与回复现象

对非线性介观电路中电流的量子动力学行为进行研究.研究表明:由于非线性双向二极管的影响,使得在非线性介观电路中电流的平均值随时间变化存在被调制的现象.即在非线性介观电路中电流的平均值随时间变化存在周期性的崩塌与回复现象,并讨论了参数的变化对这种调制的现象的影响.     

含时磁共振系统的精确解和绝热近似解

在瞬时本征态完备基矢下,把一个经典含时磁共振系统的薛定谔方程转化为二阶常系数微分方程,实现了该量子系统的精确求解.利用该系统的精确解,讨论了绝热近似的精确程度,非常清晰地刻画了绝热近似解和精确解在量子态分布概率上的差异.结果表明,若系统初态制备于某个瞬时本征态上,系统保持在该瞬时本征态的概率介于0.888 9～1之间,...     

Single-photon interconnector composed of two individual one-dimensional nano-waveguides and a single emitter

Recently, theoretical and experimental nano-sized fundamental devices for optical circuits have been proposed at the single-photon level. The assembly of a realistic optical circuit is now a reality. In this work, we introduce a single-photon interconnector composed of two individual nanowires and an optical N-type four-level emitter that can turn the optical connection on and off optically. Because of dipole-induced transmission at the single-photon level, a single photon can travel between the two nanowires reciprocally, which guarantees its application as an all-optical interconnector.     

Manipulation of nonreciprocal unconventional photon blockade in a cavity-driven system composed of an asymmetrical cavity and two atoms with weak dipole-dipole interaction

We present a work of manipulating collective unconventional photon blockade (UCPB) and nonreciprocal UCPB (NUCPB) in a cavity-driven system composed of an asymmetrical single-mode cavity and two interacting identical two-level atoms (TLAs). When the atoms do not interact directly, the frequency and intensity restrictions of collective UCPB can be specified, and a giant NUCPB exists due to the splitting of optimal atom-cavity coupling strength in proper parameter regime. However, if a weak atom-atom interaction which provides a new and feeble quantum interference pathway to UCPB is taken into account, two restrictions of UCPB are combined complexly, which are rigorous to be matched simultaneously. Due to the push-and-pull effect induced by weak dipole-dipole interaction, the UCPB regime is compressed more or less. NUCPB is improved as a higher contrast is present when the two complex UCPB restrictions are matched, while it is suppressed when the restrictions are mismatched. In general, whether NUCPB is suppressed or promoted depends on its working parameters. Our findings show a prospective access to produce giant quantum nonreciprocity by a couple of weakly interacting atoms.     

Molecular properties and potential energy function model of BH under external electric field

Using the density functional B3P86/cc-PV5Z method, the geometric structure of BH molecule under different external electric fields is optimized, and the bond lengths, dipole moments, vibration frequencies, and other physical properties parameters are obtained. On the basis of setting appropriate parameters, scanning single point energies are obtained by the same method and the potential energy curves under different external fields are also obtained. These results show that the physical property parameters and potential energy curves may change with external electric field, especially in the case of reverse direction electric field. The potential energy function without external electric field is fitted by Morse potential, and the fitting parameters are obtained which are in good agreement with experimental values. In order to obtain the critical dissociation electric parameter, the dipole approximation is adopted to construct a potential model fitting the corresponding potential energy curve of the external electric field. It is found that the fitted critical dissociation electric parameter is consistent with numerical calculation, so that the constructed model is reliable and accurate. These results will provide important theoretical and experimental reference for further studying the molecular spectrum, dynamics, and molecular cooling with Stark effect.     

基于定量相分析的固溶度测定

为了解决固溶度测定周期长、测定工作量较大的问题,提出了基于定量相分析的固溶度测定方法.该方法通过最小二乘法拟合多相区样品的物相定量分析结果和样品组元成分,可以快速得出固溶体的固溶度.在物相定量分析精确度高和组元成分精确的情况下,能很好地得出固溶度;若物相定量分析精确度不是很高,也可以快速得出固溶度的范围.     

聚合型铝氢化物(AlH3)n(n=1-3)的几何结构与振动光谱的研究

采用不同方法B3P86、B3LYP、B3PW91和MP2,结合Dunning的相关一致基组cc-PVTZ,对聚合型铝氢化物(AlH3)n(n=1-3)分子的可能几何构型进行优化计算,通过比较计算结果,发现密度泛函DFT中的方法B3P86计算的能量最低．本文采用B3P86方法得出最稳定构型的几何参数、电子结构、振动频率等性质参数,并给出最稳定结构的总能量(ET)、结合能(EBT)、平均结合能(Eav)、电离势(EIP)、能隙(Eg)、费米能级(EF)和差分吸附氢原子能(Ediff)．结果表明：三种铝氢化物分子基态都为1重态,电子态都为 ; AlH3分子的最稳定几何构型为 的平面三角形结构;Al2H6为对称性乙烯式 立体结构,H-Al之间生成氢桥式三中心双电子键;Al3H9为 立体结构,也生成氢桥式三中心双电子键,但三个氢桥三中心双电子键彼此隔离．最后分析了三种氢化物的红外和拉曼光谱、平均结合能、电离势、能隙和费米能级等特性,说明(AlH3)n(n=1-3)三分子中Al3H9最稳定,H-Al桥键键长比端键更长,红外光谱强度最大,差分吸附氢原子能最大,具有较强的储氢性能．