排序方式: 共有27条查询结果,搜索用时 15 毫秒
1.
采用溶剂扩散法制备了锰(Ⅲ)的两个单核配合物[Mn(Miao)2(H2O)2]ClO4(1)和[Mn(Miao)2(DMF)2]ClO4(2)(HMiao=1-甲基-2-咪唑醛肟,DMF=N,N-二甲基甲酰胺)的晶体.X射线衍射单晶结构表明:两种配合物均属三斜晶系,空间群Pi锰与配体形成变形的八面体结构.采用Gaussian 03W程序计算了HMiao配体的电荷密度,理论计算与实际配位形式完全吻合.测定了两种锰配合物在DMF溶液中的电化学性质,循环伏安法表明两配合物均存在较好的氧化还原性,其氧化还原峰分别为0.75和0.70V,-0.32和-0.50 V,是Mn(Ⅲ)和Mn(Ⅱ)之间的相互转化. 相似文献
2.
SIMULATION OF OCCUPATION FUNCTION FOR THERMALLY STIMULATED CONDUCTIVITY IN AMORPHOUS SEMICONDUCTORS 下载免费PDF全文
The occupation functions for the general condition f(E,T), for the high field approx-imation (HTSC) fH(E,T) and for the steady state photoconductivity (SSPC) fP(E,T) in the thermally stimulated conductivity (TSC) of amorphous semiconductors have been inves-tigated. It was found that the occupation function f(E,T) in TSC is in excellent agreement with the occupation function in SSPC fP(E,T) under the condition of σTSC(T) = σP(T).There is a large difference between fP(E,T) and fH(E,T), which can be much reduced by introducing an effective attempt to escape frequency νeff in the calculation of fH (E, T). The results show that the mobility-lifetime product (μτ) in TSC obtained from SSPC measure-ments under the above condition is valid. For high field approximation TSC, the simulated νeff is found to be temperature dependent. 相似文献
3.
一种高温超导磁悬浮装置 总被引:1,自引:0,他引:1
本文介绍一个基于倒挂吸引式(EMS)原理的高温超导磁悬浮试验装置.这个装置由高温超导磁体、单臂梁金属导轨、位置传感器、控制电路等组成.绕制超导磁体线圈所用的是Bi-2223/Ag高温超导线材.超导磁体工作在激磁电流为3.2A时,在5mm的空气间隙中产生0.21T的磁通密度,与单臂梁金属导轨可产生72N的垂直悬浮力.通过引入压控电流源,利用常规的超前一滞后校正实现了该磁悬浮装置的稳定悬浮和鲁棒控制,在负载变化87.5%的情况下仍能实现超导磁悬浮装置的稳定悬浮.该试验装置首次验证了高温超导线圈的可控性问题,为进一步探索高温超导线圈用于磁悬浮轨道交通系统的可行性打下了基础. 相似文献
4.
农村初中化学替代实验研究(Ⅰ)──部分常用仪器简易制作示例周环波,库宗军(湖北孝感师范专科学校化学系432100)初中化学实验教学对帮助学生形成化学概念,理解和巩固化学理论知识,培养学生对化学科学兴趣,培养学生的观察能力和科学思维方法及对学生综合动手... 相似文献
5.
铜取代Dawson结构杂多钨磷酸电荷转移配合物的合成与性质研究 总被引:4,自引:1,他引:3
Two new charge-transfer complexes, (DMAH)10[CuP2W17O62]·DMF·2H2O and (DMAH)14[Cu2P2W16O62] have been prepared in aqueous solution from N,N′-dimethylaniline(DMA) and copper substituted polyoxotungstates with Dawson Structure, and characterized by elemental analysis, ICP, TG, IR, diffusion reflectance electronic spectra, polarography, and CV. The results indicate that the structure of anion has little change after the charge-transfer complexes are formed, but the characteristic vibrational bands have some red shift or blue shift. The charge transfer takes place under sunlight. There is a new absorption band at 625 nm in the solid reflectance electronic spectra of the complexes, it is ascribed to the IVCT (W(V)→W(Ⅵ) band of the reduced anion [CuP2W17O62]10-. The conductivities at room temperature of title complexes are 3.6×10-9 S·cm-1 and 5.4×10-9 S·cm-1, respectively. Both of them are weak semiconductors. 相似文献
6.
7.
8.
9.
遗传算法具有很强的自适应性、鲁棒性和全局搜索能力,但其局部搜索能力相对较弱,计算后期易出现进化缓慢、过早收敛等问题,蚁群算法是近几年迅速发展起来的一种新的全局优化算法,具有正反馈机制,但是计算初期由于信息素差别小,初始收敛速度较慢.本文将这两种优化方法结合起来,充分发挥各自的优势,形成了遗传-蚁群混合算法,并选用测试函数对算法的优化性能作了对比计算,最后以高温超导匀场磁体为实际应用目标,以绕制磁体所用超导带长度为目标函数对磁体结构进行优化设计,优化方案比原始方案节省7.32%的超导带材用量. 相似文献
10.
氯化钆与L-酪氨酸和甘氨酸三元固态配合物的热化学及热分解动力学研究 总被引:6,自引:0,他引:6
合成表征了氯化钆与L 酪氨酸和甘氨酸形成的三元固态配合物Gd(Tyr) (Gly) 3 Cl3 ·3H2 O .用具有恒温环境的溶解 -反应热量计 ,测定了配位反应GdCl3 ·6H2 O (s) +Tyr (s) +3Gly (s) =Gd(Tyr) (Gly) 3 Cl3 ·3H2 O (s) +3H2 O (l)在 2 98.15K时的反应焓为 ( 9.45 1± 0 .468)kJ·mol-1 .计算得配合物Gd(Tyr) (Gly) 3 Cl3 ·3H2 O (s)在 2 98.15K时的标准摩尔生成焓为ΔfH m =-( 4 2 69.7± 2 .3 )kJ·mol-1 .并用热分析手段对配合物进行了非等温热分解动力学研究 ,推断配合物第二步热分解反应机理为二级化学反应 ,其动力学方程为 :dα/dT =(A/β)exp( -E/RT) ( 1-α) 2 ,求得分解反应的表观活化能为E =2 15 .17kJ·mol-1 ,指前因子为 10 1 8.71 s-1 . 相似文献