X-ray absorption near the edge structure and x-ray photoelectron spectroscopy studies on pyrite prepared by thermally sulfurizing iron films

This paper reports how pyrite films were prepared by thermal sulfurization of magnetron sputtered iron films and characterized by x-ray absorption near edge structure spectra and x-ray photoelectron spectroscopy on a 4B9B beam line at the Beijing Synchrotron Radiation Facility. The band gap of the pyrite agrees well with the optical band gap obtained by a spectrophotometer. The octahedral symmetry of pyrite leads to the splitting of the d orbit into t_{\rm 2g} and e_{\rm g} levels. The high spin and low spin states were analysed through the difference of electron exchange interaction and the orbital crystal field. Only when the crystal field splitting is higher than 1.5 eV, the two weak peaks above the white lines can appear, and this was approved by experiments in the present work.     

分子筛振动装填密度实验研究

实验研究了粒径分布范围在1.3mm～3.0mm之间的分子筛在振动装填过程中,各种振动参数包括振动频率、振动幅度和振动时间等对分子筛装填密度的影响,并得到最佳的振动装填工艺参数。结果表明,随着频率和振幅增大,装填密度先增加后减小,存在最佳值。在本文实验条件下,频率和振幅的最佳值分别为55Hz和0.6mm。装填密度随振动时间的增大逐渐增加并趋于定值。这些可以作为确定该粒径范围内分子筛振动装填工艺参数的基础。     

基片温度与氧分压对磁控溅射制备氧化钒薄膜的影响

采用磁控溅射工艺制备了V₂O₅薄膜.通过改变制备工艺中基片温度和氧分压两个条件，研究了薄膜的晶相组成、表观形貌以及氧化物中钒和氧元素的化合价态.当基片温度升高时，V₂O₅薄膜中颗粒结晶由细长针状转变为平行于基片的片状，V⁵⁺状态保持不变，但723 K时氧结合能向高键能态移动.氧分压较低时，薄膜表面有部分V⁴⁺态存在，但存在较多的高键能氧，此时薄膜中晶粒尺寸较小.随着氧分压的提 关键词： 氧化钒 磁控溅射 相变薄膜 X射线光电子能谱     

轴向流吸附床内流动特性的模拟研究

变压吸附过程是一个动态变压力变质量多孔介质流动与传热传质过程,揭示过程的流动特性是深入研究吸附机理的基础.基于严格质量守恒和动量守恒, 建立了吸附床内的气体流体、吸附传质的数学模型,以某轴向流快速空分制氧吸附床为研究对象, 对吸附床内全循环过程进行了模拟, 对升压吸附、降压解吸和常压清洗各个阶段的流动特性进行了详细的分析,并与空床、有料无吸附时的流动特性进行了对比.