排序方式: 共有3条查询结果,搜索用时 15 毫秒
1
1.
2.
Energy transfer probability in organic electrophosphorescence device with dopant 总被引:1,自引:0,他引:1 下载免费PDF全文
Based on the energy transfer process from host to dopant in an organic
electrophosphorescent (EP) device, the expression of energy transfer
probability ($\eta )$ between the host (TPD) and guest (Ir(ppy)$_{3})$ EP
systems was proposed. The results show that: ({1}) The rate of the triplet
energy transfer ($K_{\rm HG}$ and $K_{\rm GH})$ increases exponentially with
increasing donor-acceptor molecular distance ($R$), whereas decreases as the
intermolecular distance ($R_{\rm HH})$ increases from 0.8 to 2.4 nm.
Furthermore, $K_{\rm GH}$ changes more quickly than $K_{\rm HG.}$ ({2}) The energy
transfer probability ($\eta )$ increases as $R$ reduces, and the $R_{\rm HH}$
changes can be safely neglected for $R<$0.9 nm. The situation changes for
0.9nm$ < R < 1.1$nm, $R_{\rm HH }$ ($<1$nm) plays an essential role when
$\eta $ changes
and increases with the latter. However, if $R > 1.1$nm, the transfer
probability will be below zero. Here, the energy transfer principle may be
less important, and the high electroluminescence (EL) quantum efficiency of
phosphorescent system will be attributed to the direct electron-hole
recombination in phosphorescent molecules. ({3}) The $\eta $ will increase when the
Forster radius ($R_{0})$ increases or Gibb's energy decreases. 相似文献
3.
采用多元醇法,在不同温度,不同PVP滴加速度和加入量的条件下合成了银纳米线。利用XRD,UV-Vis,SEM和TEM对银纳米线及其侧向生长过程进行了观察和分析。UV-Vis表明银纳米线在纵向生长的同时发生了侧向生长。而且表示银纳米线侧向生长的紫外吸收光谱峰在银纳米线合成后期发生了明显的红移,由384nm红移至约388nm处,表明银纳米线合成后期直径迅速增长,银纳米线发生了快速的侧向生长。SEM研究表明银纳米线直径在反应前期(15~23min)只增加了20nm,而在反应后期(23~30min)银纳米线直径增加了近150nm,SEM观察结果与UV-Vis分析结论一致。同时还发现银纳米线直径不仅与晶种大小有关而且与银线外覆盖的银层厚度有关,银源以吸附在银线侧面的小银颗粒为附着点沿其侧面多点沉积导致了银纳米线的侧向生长;降低反应液温度(165℃降至155℃),降低PVP滴加速度(67mL·h~(-1)减小到49mL·h~(-1))以及减少银纳米线合成后期PVP加入量可抑制银纳米线的侧向生长,显著提高银纳米线长径比,银纳米线直径由200nm减小至100nm左右,长度仍保持在100μm以上。 相似文献
1