排序方式: 共有17条查询结果,搜索用时 31 毫秒
1.
用弹性散射对多通道(e,2e)谱仪两维位置灵敏探测器的能量和动量响应函数进行了刻度,从位置灵敏探测器输出的两维位置信息中获得了弹性散射的能谱和角度谱,估计了在当前实验条件下的能量分辨和角度分辨.同时,我们用正交多项式的最小二乘法拟合得到了谱仪单路的能量和动量响应函数. 相似文献
2.
Theoretical calculation of triple differential cross sections of 3s orbital of argon in coplanar symmetric (e, 2e) reaction 总被引:1,自引:0,他引:1
The triple differential cross section for the low-energy electron impact ionization of inner-valence 3s orbital of argon has been calculated using the modified distorted wave Born approximation in coplanar symmetric energy-sharing geometry. Satisfactory agreement between theory and experiraent is achieved when the polarization and post-collisional interaction (PCI) are included in the calculations. It is shown that the polarization and PCI effects play a very important role in the case of argon at low incident energies. 相似文献
3.
Electron Momentum Distributions of the Highest Occupied Molecular Orbital of CF3Br: Delocalization of Halogen Lone-Pair Orbitals
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The highest occupied molecular orbital (HOMO) of trifluorobromomethane (CF3Br) is studied by binary (e,2e)electron momentum spectroscopy. The experimental momentum profile of the HOMO is compared with the Hartree-Fock (HF) and density functional theory (DFT-B3LYP) calculations. The calculated results largely depend on the size of basis sets rather than theoretical methods. Both the HF and DFT calculations using the 6-311 G^** basis set give a good explanation to the experiment. Delocalization of halogen lone-pair orbitals in the series molecules CF3X (X=F, Cl, Br) has been investigated. 相似文献
4.
本用自旋平均静态交换势三体扭曲波波恩近似(DWBA)计算了Li^ (1s^2)和He(1s^2)、K^ (3p^6)和Ar(3p^6)在1000eV入射能下的共面不对称(e,2e)三重微分截面(TDCS)。通过比较离子和原子靶三重微分截面的角分布,表明两体碰撞图像在离子靶的情形不成立。 相似文献
5.
用包含极化效应和后碰撞作用的扭曲波玻恩近似计算了共面不对称几何条件下Ar(3s2)的低能(e, 2e)三重微分截面,并与实验进行了比较.指出极化效应在共面不对称几何条件下Ar(3s2)的低能(e, 2e)过程中起着重要的作用. 相似文献
6.
本文用自旋平均静态交换势三体扭曲波波恩近似(DWBA)计算了Li+(1s2)和He(1s2)、K+(3p6) 和Ar(3p6)在1?000?eV入射能下的共面不对称(e, 2e)三重微分截面(TDCS).通过比较离子和原子靶三重微分截面的角分布,表明两体碰撞图像在离子靶的情形不成立. 相似文献
7.
用自旋平均静态交换势下的三体扭曲波波恩近似计算了d轨道电子(Ag+(4d10))在共面非对称几何条件下的三重微分截面, 结果表明在高入射能的条件下, 随散射电子角度θa的增加, binary峰和recoil峰分裂的个数都会增加, 电子的电离振幅会随之下降, d电子的三重微分截面比s, p电子的复杂. 相似文献
8.
Bromochlorodifluoromethane(CF2BrCl),also knownasHalon1211inindustry,isamainagent widelyusedforfiresuppressionapplicationsandhas receivedconsiderableattentionbecauseofitspotential forstratosphericozonedepletion[1,2].Thedetailed informationonpropertiesofCF2BrClmoleculesuchas ionizationpotential,chemicalbondingcharacterand electrondensitydistributionofmolecularorbitals,especiallyofthefrontiermolecularorbitals,isbelieved tobeimportantforchemicalreactionandpossible molecularrecognitionaccordingt… 相似文献
9.
用包含极化效应和后碰撞作用的扭曲波玻恩近似计算了共面不对称几何条件下Ar(3s^2)的低能(e,2e)三重微分截面,并与实验进行了比较。指出极化效应在共面不对称几何条件下Ar(3s^2)的低能(e,2e)过程中起着重要的作用。 相似文献
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