定时截尾指数模型验前多数的确定

研究在定时有替换截尾试验下，指数模型点估计的验前参数的确定方法，讨论了验前参数的有关性质并给出了确定验前参数取值适合域的方法．最后用例子说明Ｂａｙｅｓ估计“优于”经典估计．     

热辐射定律实验

量子力学和相对论是近代物理学的两大支柱。而黑体热辐射定律的研究对量子力学的创立起过特殊的作用。为了使学生对黑体辐射规律有直接的认识,我们研制了这套实验仪(暂定名:RF—1型热辐射定律实验仪),让学生方便地进行分组实验。     

Improving the precision of fluorescence lifetime measurement using a streak camera

Streak camera has high temporal resolution and high sensitivity, and is a powerful tool in biomedical study to measure fluorescence lifetime and perform fluorescence lifetime imaging. However, nonuniformity of the gain in the streak tube and nonlinearity of the sweeping speed limit the precision of fluorescence lifetime measurement, particularly when fluorescence lifetimes are short. We have constructed a two-photon excitation fluorescence lifetime measurement system that is based on a synchroscan streak camera and have developed accordingly a method to correct the effect of gain nonuniformity and nonlinearity of sweeping speed on the measurement precision. A continuous-wave laser of high stability is used to calibrate the gain of the streak camera, and a Fabry-Perot etalon is used to calibrate the nonlinearity of the sweeping speed. Fitting algorithms are used to correct the gain of the streak camera and nonlinearity of the sweeping speed respectively, which significantly improves the measurement precision of the system, as characterized through the fluorescence lifetime of the short-lived fluorescence dye, Rose Bengal. Experimental results show that the measurement fluctuation of the lifetime has been improved from more than 10% to 2% after correcting the effects of gain nonuniformity and sweeping speed nonlinearity.     

SCHWARZ ALTERNATING METHOD AND MULTIGRID METHOD

In this paper we propose and establish the convergence of several asynchronous parallel algorithms which are defined by combining the Schwarz alternating method with the multigrid method in two ways. In the first we divide the original problem into p related subproblems, then the multigrid method is used to solve these subproblems iteratively. In the second approach we regard the Schwarz iterative method as the smoothing step of multigrid method. All algorithms proposed in this paper can be used on an MIMD computer.     

Influence of coating material on laser damage threshold of TiO_2 films

The optical property,structure,surface properties(roughness and defect density)and laser-induced dam- age threshold(LIDT)of TiO_2 films deposited by electronic beam(EB)evaporation of TiO_2(rutile),TiO_2 (anatase)and TiO_2 Ta_2O_5 composite materials are comparatively studied.All films show the polycrys- talline anatase TiO_2 structure.The loose sintering state and phase transformation during evaporating TiO_2 anatase slice lead to the high surface defect density,roughness and extinction coefficient,and low LIDT of films.The TiO_2 Ta_2O_5 composite films have the lowest extinction coefficient and the highest LIDT among all samples investigated.Guidance of selecting materials for high LIDT laser mirrors is given.     

紫外新激光染料IBOP的研究

本文介绍一种新合成的化合物IBOP.经在多种染料激光器上测试表明,其激光转换效率高,光化学稳定性好,能溶于多种溶剂.性能优于DPS等相同波段的常用激光染料.IBOP在各种溶剂中的激光调谐范围为388～428nm,激光峰值波长在400nm左右.本文给出了IBOP的荧光光谱、吸收光谱、激光特性、溶剂效应和浓度效应等数据,并作了讨论.     

高效液相色谱–串联质谱法同时测定土壤中8种杀菌剂残留

建立高效液相色谱-串联质谱法同时测定土壤中戊唑醇、腈菌唑、腈苯唑、氟硅唑、三唑酮、丙环唑、烯唑醇、苯醚甲环唑8种杀菌剂残留量的方法。采用QuEChERS样品前处理方法对土壤样品进行提取、净化和富集,用电喷雾离子源、正负离子扫描,以多反应监测(MRM)模式进行定性和定量分析。在优化的实验条件下,8种杀菌剂的质量浓度在0.01~0.50 mg/L范围内与色谱峰面积均成良好的线性关系,相关系数均大于0.995,方法检出限为0.005~0.010 mg/kg。样品平均加标回收率为85.6%~102.2%,测定结果的相对标准偏差为4.6%~13.2%(n=5)。该方法操作简便,灵敏度和准确度高,满足土壤中戊唑醇等8种杀菌剂残留量的测定要求。     

含邻苯二酚基团微凝胶的合成及其硝酸根离子响应特性

刺激响应微凝胶有望用于捕获水体中硝酸根离子,并允许材料自身的再生循环使用,但如何实现高效捕获水体中硝酸根离子颇具挑战性.本工作合成了单体2,3-二羟基-N-(2-甲基烯丙基)苯甲酰胺,并将其与苯乙烯、4-氯甲基苯乙烯、二乙烯基苯共聚,制得含邻苯二酚基团微凝胶.随着硝酸根离子浓度(以氮计)在0～40.0 mg/L范围内逐渐增大,浊度法表征表明在常温22℃下微凝胶水溶液消光度呈现持续增大趋势,而动态光散射法表征表明微凝胶粒径减小,即发生收缩.色谱法表征表明,微凝胶对硝酸根离子具有较好吸附性能,最大吸附容量达54.2 mg/g,即使对低浓度硝酸根离子(≤10 mg/L)也可在10 min内达到吸附平衡,有望用于废水处理.     

微机上分子实体模型的实现

本文采用简单、快速的方法在微机上实现光照与明暗处理的分子实体模型，并给出了明暗层次丰富的分子柱状模型、球柱模型和ＣＰＫ模型的显示实例。     

GDX树脂富集－反相高效液相色谱法分离测定酚类化合物

用ＧＤＸ－５０２树脂富集的酚类化合物，经反相高效液相色谱法分离和检测，具有较好的准确度和精密度。