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Double-walled carbon nanotubes (DWCNTs) have been found to be promising nano-materials for nano-mechanical and nano-electrical devices due to their double-walled structures. Modifying DWCNTs would be one of the key technologies for device construction. We demonstrate engineering the geometry of DWCNTs by etching with Ar plasma. The characterization by atomic force rnicroscopy indicates that single atomic carbon layers could be removed from DWCNTs by Ar plasma. The etching effect is further investigated by electrical measurements on DWCNT field-effect transistors, which allow us to study the interwall screen effect as well. 相似文献
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Synthesis of nitrogen-doped single-walled carbon nanotubes and monitoring of doping by Raman spectroscopy
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Nitrogen-doped single-walled carbon nanotubes (CNx-SWNTs) with tunable dopant concentrations were synthesized by chemical vapor deposition (CVD), and their structure and elemental composition were characterized by using transmission electron microscopy (TEM) in combination with electron energy loss spectroscopy (EELS). By comparing the Raman spectra of pristine and doped nanotubes, we observed the doping-induced Raman G band phonon stiffening and 2D band phonon softening, both of which reflect doping-induced renormalization of the electron and phonon energies in the nan- otubes and behave as expected in accord with the n-type doping effect. On the basis of first principles calculations of the distribution of delocalized carrier density in both the pristine and doped nanotubes, we show how the n-type doping occurs when nitrogen heteroatoms are substitutionally incorporated into the honeycomb tube-shell carbon lattice. 相似文献
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The recent development of synthesis processes to assemble graphene sheets into porous three-dimensional (3D)macroscopic structures are reviewed, including our efforts on 3D graphene structures. Mechanisms for building 3D graphene architectures and their composite materials are also summarized. The functional systems based on 3D graphene architectures provide a significant enhancement in the efficacy due to their unique structures and properties. 相似文献
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当带有光学成像探测制导系统的高速飞行器在大气层内飞行时,光学窗口与来流之间会形成复杂的凹腔绕流流场,产生气动光学效应。建立了求解超声速流场的高精度LES/RANS混合算法模型,研究了超声速流动条件下的Settles三维凹腔流动;在计算得到精确流场数据的基础上,研究了凹腔剪切层区域的光学传输效应。结果表明,凹腔流动的剪切层结构将引起光线抖动,导致严重的波面畸变,明显降低光强斯特雷尔(Strehl)比,严重影响光学传输性能,进而大大降低光学制导精度。 相似文献
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