全文获取类型
收费全文 | 830篇 |
免费 | 21篇 |
国内免费 | 4篇 |
专业分类
化学 | 578篇 |
晶体学 | 6篇 |
力学 | 37篇 |
数学 | 128篇 |
物理学 | 106篇 |
出版年
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 29篇 |
2020年 | 23篇 |
2019年 | 15篇 |
2018年 | 16篇 |
2017年 | 24篇 |
2016年 | 42篇 |
2015年 | 31篇 |
2014年 | 25篇 |
2013年 | 62篇 |
2012年 | 54篇 |
2011年 | 86篇 |
2010年 | 40篇 |
2009年 | 57篇 |
2008年 | 62篇 |
2007年 | 53篇 |
2006年 | 58篇 |
2005年 | 43篇 |
2004年 | 34篇 |
2003年 | 21篇 |
2002年 | 20篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 1篇 |
1996年 | 6篇 |
1995年 | 8篇 |
1994年 | 5篇 |
1992年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1985年 | 2篇 |
1979年 | 1篇 |
1961年 | 1篇 |
排序方式: 共有855条查询结果,搜索用时 17 毫秒
1.
Brandão Pedro Francisco Ramos Rui Miguel Rodrigues José António 《Analytical and bioanalytical chemistry》2018,410(26):6873-6880
Analytical and Bioanalytical Chemistry - Formaldehyde is often applied in the industrial production of different products, such as textiles, insulation materials, or cosmetics, due to its... 相似文献
2.
3.
Carlos Conceição António 《Memetic Computing》2014,6(2):113-131
The mechanical properties of composite structures are sensitive to the choice of the material systems, the distribution of laminates on the structure, and the sizing at the laminate level. This sensitivity depends on many variables. To overcome the difficulties in attaining a global solution for the optimisation problem of composite structures, a new strategy is proposed based on the hybridisation of the memetic algorithm (MA) and the selfish gene (SG) algorithm. Instead of a local search, as performed in MAs, the selfish gene (SG) theory is applied, which follows a different learning scheme in which the conventional population of the individuals is replaced by a virtual population of alleles. The proposed approach, which is called the memetic-based selfish gene algorithm (MA + SG), is a mixed model that applies multiple learning procedures to explore the synergy of different cultural transmission rules in the evolutionary process. The principal aspects of the approach are as follows: co-evolution of multiple populations, species conservation, migration rules, self-adaptive multiple crossovers, local search in hybrid crossover with local genetic improvements, controlled mutation, individual age control, and feature-based allele statistical analysis. To discuss the capabilities of the proposed approach, numerical examples are represented to compare the results of MA + SG with those obtained using genetic algorithms (GA) and MA. The numerical results of the comparison tests showed that the GA and the MA maintained long periods without the evolution of the best-fitted individual/solutions. This behaviour during evolution is associated with the slow maturation of the elite group of populations in the GA and MA approaches. This behaviour is avoided when the MA + SG proposed approach is used with computational cost benefits. 相似文献
4.
Luís Antônio Dantas Silva Fernanda Vieira Teixeira Raphael Caixeta Serpa Najla Locatelli Esteves Rayane Ramos dos Santos Eliana Martins Lima Marcílio Sérgio Soares da Cunha-Filho Adriano Antunes de Souza Araújo Stephânia Fleury Taveira Ricardo Neves Marreto 《Journal of Thermal Analysis and Calorimetry》2016,123(3):2337-2344
5.
Antônio Gomes dos Santos Neto Franciele de Matos Morawski Ana Caroline Ferreira Santos Cláudia Quintino da Rocha Roberto Batista de Lima Marília Oliveira Fonseca Goulart Clenilton Costa dos Santos Flávio Colmati Antônio Euzébio Goulart Santana Marco Aurélio Suller Garcia Auro Atsushi Tanaka 《Electroanalysis》2023,35(5):e202200390
Here, we report multiwalled carbon nanotubes (MWCNTs) functionalized with γ-cyclodextrins (γCD) as a novel electrochemical strategy for Rutin determination, showing superior performance than β-cyclodextrins (βCD) modified MWCNTs, suggesting an adequate environment for host-guest interactions. Under optimized conditions, the sensor showed a linear range of 39–975 nmol L−1 and a limit of detection of 7 nmol L−1. When tested with quercetin, catechin, and caffeine, the platform presented high selectivity with an interference response <10 %. The method was employed to quantify Rutin in spiked pharmaceutical and herbal extracts, providing recovery of 93–98.4 %. Also, HPLC-PDA confirmed the method‘s accuracy. 相似文献
6.
Del Sordo Filho Giovanni Torrecilha Jefferson Koyaishi Scapin Marcos Antônio Oliveira Sonia Maria Barros da Silva Paulo Sergio Cardoso 《Journal of Radioanalytical and Nuclear Chemistry》2021,329(1):61-70
Journal of Radioanalytical and Nuclear Chemistry - This study has evaluated chemical, radiological composition and determined the cation exchange capacity (CEC) for three commercially available... 相似文献
7.
Syam Sundar L. Misganaw A. H. Singh Manoj K. Sousa António C. M. Ali Hafiz Muhammad 《Journal of Thermal Analysis and Calorimetry》2021,143(2):959-972
Journal of Thermal Analysis and Calorimetry - In the present study, the thermal efficiency, convective heat transfer and friction factor analysis are investigated for a flat plate solar collector... 相似文献
8.
Moura Ramos Joaquim J. Diogo Hermínio P. 《Journal of Thermal Analysis and Calorimetry》2021,145(6):3077-3085
Journal of Thermal Analysis and Calorimetry - The thermal behavior of the two glass-forming drugs bifonazole and lamotrigine was studied by differential scanning calorimetry (DSC); we reported a... 相似文献
9.
Lidiane Diniz do Nascimento Sebastio Gomes Silva Mrcia Moraes Cascaes Kauê Santana da Costa Pablo Luis Baia Figueiredo Cristiane Maria Leal Costa Eloisa Helena de Aguiar Andrade Lênio Jos Guerreiro de Faria 《Molecules (Basel, Switzerland)》2021,26(9)
Leaves of Lippia thymoides (Verbenaceae) were dried in an oven at 40, 50 and 60 °C and the kinetic of drying and the influence of the drying process on the chemical composition, yield, and DPPH radical scavenging activity of the obtained essential oils were evaluated. The composition of the essential oils was determined with gas chromatography-mass spectrometry and gas chromatography-flame ionization detection analyses. The influence of drying on the chemical composition of the essential oils of L. thymoides was evaluated by multivariate analysis, and their antioxidant activity was investigated via the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay. The Midilli model was the most appropriate to describe the behavior of drying kinetic data of L. thymoides leaves. Thymol was the major compound for all analyzed conditions; the maximum content was obtained from fresh leaves (62.78 ± 0.63%). The essential oils showed DPPH radical scavenging activity with an average of 73.10 ± 12.08%, and the fresh leaves showed higher inhibition (89.97 ± 0.31%). This is the first study to evaluate the influence of drying on the chemical composition and antioxidant activity of L. thymoides essential oils rich in thymol. 相似文献
10.
Celeste de Jesus Pereira Franco Oberdan Oliveira Ferreira ngelo Antnio Barbosa de Moraes Everton Luiz Pompeu Varela Lidiane Diniz do Nascimento Sandro Percrio Mozaniel Santana de Oliveira Eloisa Helena de Aguiar Andrade 《Molecules (Basel, Switzerland)》2021,26(11)
Essential oils (EOs) were extracted from Eugenia patrisii, E. punicifolia, and Myrcia tomentosa, specimens A and B, using hydrodistillation. Gas chromatography coupled with mass spectrometry (GC/MS) was used to identify the volatile constituents present, and the antioxidant capacity of EOs was determined using diphenylpicryl-hydrazyl (DPPH) and trolox equivalent antioxidant capacity (TEAC) assays. For E. patrisii, germacrene D (20.03%), bicyclogermacrene (11.82%), and (E)-caryophyllene (11.04%) were identified as the major constituents of the EOs extracted from specimen A, whereas specimen B primarily comprised γ-elemene (25.89%), germacrene B (8.11%), and (E)-caryophyllene (10.76%). The EOs of E. punicifolia specimen A contained β-Elemene (25.12%), (E)-caryophyllene (13.11%), and bicyclogermacrene (9.88%), while specimen B was composed of (E)-caryophyllene (11.47%), bicyclogermacrene (5.86%), β-pinene (5.86%), and γ-muurolene (5.55%). The specimen A of M. tomentosa was characterized by γ-elemene (12.52%), germacrene D (11.45%), and (E)-caryophyllene (10.22%), while specimen B contained spathulenol (40.70%), α-zingiberene (9.58%), and γ-elemene (6.89%). Additionally, the chemical composition of the EOs was qualitatively and quantitatively affected by the collection period. Furthermore, the EOs of the studied specimens, especially specimen A of E. punicifolia, showed a greater antioxidant activity in DPPH rather than TEAC, as represented by a significantly high inhibition percentage (408.0%). 相似文献