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Photoisomerisation in Aminoazobenzene‐Substituted Ruthenium(II) Tris(bipyridine) Complexes: Influence of the Conjugation Pathway 下载免费PDF全文
Dr. Anissa Amar Dr. Paul Savel Dr. Huriye Akdas‐Kilig Dr. Claudine Katan Prof. Hacène Meghezzi Prof. Abdou Boucekkine Dr. Jean‐Pierre Malval Dr. Jean‐Luc Fillaut 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8262-8270
Transition‐metal complexes containing stimuli‐responsive systems are attractive for applications in optical devices, photonic memory, photosensing, as well as luminescence imaging. Amongst them, photochromic metal complexes offer the possibility of combining the specific properties of the metal centre and the optical response of the photochromic group. The synthesis, the electrochemical properties and the photophysical characterisation of a series of donor–acceptor azobenzene derivatives that possess bipyridine groups connected to a 4‐dialkylaminoazobenzene moiety through various linkers are presented. DFT and TD‐DFT calculations were performed to complement the experimental findings and contribute to their interpretation. The position and nature of the linker (ethynyl, triazolyl, none) were engineered and shown to induce different electronic coupling between donor and acceptor in ligands and complexes. This in turn led to strong modulations in terms of photoisomerisation of the ligands and complexes. 相似文献
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Gas‐phase conformations of capistruin – comparison of lasso,branched‐cyclic and linear topologies 下载免费PDF全文
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Mark R. Bortolus Dr. Hélène P. A. Mercier Prof. Gary J. Schrobilgen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(41):8935-8950
The reactions of the fluoride-ion donor, XeF6, with the fluoride-ion acceptors, M′OF4 (M′=Cr, Mo, W), yield [XeF5]+ and [Xe2F11]+ salts of [M′OF5]− and [M2O2F9]− (M=Mo, W). Xenon hexafluoride and MOF4 react in anhydrous hydrogen fluoride (aHF) to give equilibrium mixtures of [Xe2F11]+, [XeF5]+, [(HF)nF]−, [MOF5]−, and [M2O2F9]− from which the title salts were crystallized. The [XeF5][CrOF5] and [Xe2F11][CrOF5] salts could not be formed from mixtures of CrOF4 and XeF6 in aHF at low temperature (LT) owing to the low fluoride-ion affinity of CrOF4, but yielded [XeF5][HF2]⋅CrOF4 instead. In contrast, MoOF4 and WOF4 are sufficiently Lewis acidic to abstract F− ion from [(HF)nF]− in aHF to give the [MOF5]− and [M2O2F9]− salts of [XeF5]+ and [Xe2F11]+. To circumvent [(HF)nF]− formation, [Xe2F11][CrOF5] was synthesized at LT in CF2ClCF2Cl solvent. The salts were characterized by LT Raman spectroscopy and LT single-crystal X-ray diffraction, which provided the first X-ray crystal structure of the [CrOF5]− anion and high-precision geometric parameters for [MOF5]− and [M2O2F9]−. Hydrolysis of [Xe2F11][WOF5] by water contaminant in HF solvent yielded [XeF5][WOF5]⋅XeOF4. Quantum-chemical calculations were carried out for M′OF4, [M′OF5]−, [M′2O2F9]−, {[Xe2F11][CrOF5]}2, [Xe2F11][MOF5], and {[XeF5][M2O2F9]}2 to obtain their gas-phase geometries and vibrational frequencies to aid in their vibrational mode assignments and to assess chemical bonding. 相似文献
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Dr. Thomas G. Hayhow Rachel E. A. Borrows Dr. Coura R. Diène Gary Fairley Dr. Charlene Fallan Dr. Shaun M. Fillery Dr. James S. Scott Dr. David W. Watson 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(70):16818-16823
A palladium-catalysed Buchwald–Hartwig amination for lenalidomide-derived aryl bromides was optimised using high throughput experimentation (HTE). The substrate scope of the optimised conditions was evaluated for a range of alkyl- and aryl- amines and functionalised aryl bromides. The methodology allows access to new cereblon-based bifunctional proteolysis targeting chimeras with a reduced step count and improved yields. 相似文献
6.
Hélène Beucher Dr. Sudhir Kumar Dr. Roopender Kumar Dr. Estíbaliz Merino Wei-Hsu Hu Gerrit Stemmler Sergio Cuesta-Galisteo Dr. Jorge A. González Léonard Bezinge Dr. Jakub Jagielski Dr. Chih-Jen Shih Prof. Dr. Cristina Nevado 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(72):17604-17612
Efficient OLED devices have been fabricated using organometallic complexes of platinum group metals. Still, the high material cost and low stability represent central challenges for their application in commercial display technologies. Based on its innate stability, gold(III) complexes are emerging as promising candidates for high-performance OLEDs. Here, a series of alkynyl-, N-heterocyclic carbene (NHC)- and aryl-gold(III) complexes stabilized by a κ3-(N^C^C) template have been prepared and their photophysical properties have been characterized in detail. These compounds exhibit good photoluminescence quantum efficiency (ηPL) of up to 33 %. The PL emission can be tuned from sky-blue to yellowish green colors by variations on both the ancillary ligands as well as on the pincer template. Further, solution-processable OLED devices based on some of these complexes display remarkable emissive properties (ηCE 46.6 cd.A−1 and ηext 14.0 %), thus showcasing the potential of these motifs for the low-cost fabrication of display and illumination technologies. 相似文献
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Laurent Decreusefond Hélène Halconruy 《Stochastic Processes and their Applications》2019,129(8):2611-2653
On any denumerable product of probability spaces, we construct a Malliavin gradient and then a divergence and a number operator. This yields a Dirichlet structure which can be shown to approach the usual structures for Poisson and Brownian processes. We obtain versions of almost all the classical functional inequalities in discrete settings which show that the Efron–Stein inequality can be interpreted as a Poincaré inequality or that the Hoeffding decomposition of -statistics can be interpreted as an avatar of the Clark representation formula. Thanks to our framework, we obtain a bound for the distance between the distribution of any functional of independent variables and the Gaussian and Gamma distributions. 相似文献
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Ukrainian Mathematical Journal - We determine some classes of left modules satisfying the radical formula in a noncommutative ring. We also show that, under a certain condition, a finitely... 相似文献