全文获取类型
收费全文 | 1157篇 |
免费 | 35篇 |
国内免费 | 3篇 |
专业分类
化学 | 965篇 |
晶体学 | 11篇 |
力学 | 17篇 |
数学 | 58篇 |
物理学 | 144篇 |
出版年
2022年 | 7篇 |
2021年 | 6篇 |
2020年 | 10篇 |
2019年 | 13篇 |
2018年 | 8篇 |
2017年 | 15篇 |
2016年 | 14篇 |
2015年 | 19篇 |
2014年 | 45篇 |
2013年 | 71篇 |
2012年 | 64篇 |
2011年 | 87篇 |
2010年 | 38篇 |
2009年 | 51篇 |
2008年 | 80篇 |
2007年 | 72篇 |
2006年 | 75篇 |
2005年 | 73篇 |
2004年 | 70篇 |
2003年 | 54篇 |
2002年 | 47篇 |
2001年 | 17篇 |
2000年 | 16篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 14篇 |
1995年 | 15篇 |
1994年 | 15篇 |
1993年 | 12篇 |
1992年 | 8篇 |
1991年 | 10篇 |
1990年 | 7篇 |
1989年 | 9篇 |
1988年 | 10篇 |
1987年 | 5篇 |
1986年 | 9篇 |
1985年 | 11篇 |
1984年 | 9篇 |
1983年 | 8篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1978年 | 4篇 |
1977年 | 9篇 |
1976年 | 5篇 |
1975年 | 7篇 |
1974年 | 8篇 |
1970年 | 5篇 |
排序方式: 共有1195条查询结果,搜索用时 15 毫秒
1.
2.
3.
Dr. Tetsuo Tsuchiya Dr. Tomohiko Nakajima Yuko Uzawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(42):9261-9276
This review summarizes the use of photoreactions that replace conventional heating processes for growing oxide thin films from chemical solutions. In particular, this review outlines key variables in photoreactions that affect epitaxial and polycrystalline thin film growth, including precursor materials, laser wavelength, laser fluence, and carbon. In addition, the features of the photoreaction process that can be controlled at a low temperature by oxygen non-stoichiometry are examined. Likewise, functions that are neither achieved by developing a gradient structure nor controlled by a thermal equilibrium reaction are detailed. Two new concepts are presented, known as photoreaction of nanoparticles (PRNP) and photoreaction of a hybrid solutions (PRHS), in which crystal nuclei are pre-dispersed in a metal–organic compound film. This method has successfully produced flexible phosphor films used as resistor or thermistor electronic components. Finally, thin film growth using different light sources such as flash lamps and femtosecond lasers (fs) is explored. 相似文献
4.
5.
Anna G. Scott Diogo Alves Galico Isabel Bogacz Paul H. Oyala Junko Yano Elizaveta A. Suturina Muralee Murugesu Theodor Agapie 《Angewandte Chemie (International ed. in English)》2023,62(49):e202313880
Atomically defined large metal clusters have applications in new reaction development and preparation of materials with tailored properties. Expanding the synthetic toolbox for reactive high nuclearity metal complexes, we report a new class of Fe clusters, Tp*4W4Fe13S12 , displaying a Fe13 core with M−M bonds that has precedent only in main group and late metal chemistry. M13 clusters with closed shell electron configurations can show significant stability and have been classified as superatoms. In contrast, Tp*4W4Fe13S12 displays a large spin ground state of S=13. This compound performs small molecule activations involving the transfer of up to 12 electrons resulting in significant cluster rearrangements. 相似文献
6.
7.
A Triphenylamine with Two Phenoxy Radicals Having Unusual Bonding Patterns and a Closed‐Shell Electronic State 下载免费PDF全文
Dr. Daisuke Sakamaki Soichiro Yano Toshiyuki Kobashi Prof. Dr. Shu Seki Dr. Takuya Kurahashi Prof. Dr. Seijiro Matsubara Dr. Akihiro Ito Prof. Dr. Kazuyoshi Tanaka 《Angewandte Chemie (International ed. in English)》2015,54(28):8267-8270
Reported herein is the structure and the electronic properties of a novel triphenylamine derivative having two phenoxy radicals appended to the amino nitrogen atom. X‐ray single crystal analysis and the magnetic resonance measurements demonstrates the unexpected closed‐shell electronic structure, even at room temperature, of the molecule and two unusual C? N bonds with multiple‐bond character. The theoretical calculations support the experimentally determined molecular geometry with the closed‐shell electronic structure, and predicted a small HOMO–LUMO gap originating from the nonbonding character of the HOMO. The optical and electrochemical measurements show that the molecule has a remarkably small HOMO–LUMO gap compared with its triphenylamine precursor. 相似文献
8.
Katsuhito Suzuki Yoko Homma Yuko Igarashi Hiroaki Okumura Hiroyuki Yano 《Cellulose (London, England)》2017,24(9):3789-3801
Microfibrillated cellulose (MFC)-reinforced polypropylene (PP) was prepared via two engineering approaches: disintegration of the pulp by a bead mill followed by a melt-compounding process with PP (B-MFC-reinforced PP); and disintegration of the pulp mixed with PP by a twin screw extruder followed by a melt-compounding process (T-MFC-reinforced PP). The effects that the engineering process and the microfibrillation of the pulp had upon the dispersion and mechanical properties were investigated through tensile tests, rheological analysis and X-ray computed tomography. The bead-milling method enabled a uniform microfibrillation of the pulp to under 100 nm, which corresponded to a surface area of 133–146 m2/g for the pulp, found by the Brunauer–Emmett–Teller (BET) analysis. The T-MFC-reinforced PP with 30 wt% MFC content exhibited a tensile modulus of 5.3 GPa and a strength of 85 MPa, whereas the B-MFC-reinforced PP composites with the same content of MFC exhibited values of 4.1 GPa and 59.6 MPa, respectively. Rheological analysis revealed that the complex viscosity and storage modulus at 170 °C of T-MFC-reinforced PP with 30 wt% MFC content are 5–7 and 5–8 times higher than that of B-MFC-reinforced PP, respectively. This indicated that T-MFC was more dispersed in the PP than B-MFC. Therefore, T-MFC produced a more rigid interconnected network in the matrix during the melting state than B-MFC. 相似文献
9.
Yokokita Takuya Yano Shinya Komori Yukiko Haba Hiromitsu 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):1127-1134
Journal of Radioanalytical and Nuclear Chemistry - To investigate sulfate complex formation of Rf, we performed batch-wise ion-exchange experiments of its homologues Zr and Hf and its pseudo... 相似文献
10.
T. Yano 《Shock Waves》1996,6(6):313-322
A weakly nonlinear plane acoustic wave is emitted into an ideal gas of semi-infinite extent from an infinite plate by its
sinusoidal motion of single period. The wave develops into anN wave in the far field, as long as the energy dissipation is negligible everywhere except for discontinuous shock fronts.
The third-order effects at shock fronts are evaluated, i.e., the generation of reflected acoustic wave as a result of the
interaction of shock and expansion wave and the production of entropy by the energy dissipation at shock fronts. Consideration
of these effects enables one to estimate the whole mass, momentum and total excess energy (sum of the kinetic energy and excess
of internal energy over an initial undisturbed value) transported by theN wave to the accuracy of third order of wave amplitude. It is shown that the mass and total excess energy transported by theN wave increase and the momentum decreases to asymptotic limits as the wave propagates. The result shows good agreement with
a numerical result obtained by solving the Euler equations with a high-resolution TVD upwind scheme. 相似文献