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1.
Crystallography Reports - The review presents the important unique results of the cycle of research led by M.V. Kovalchuk on the fundamental patterns of protein interactions and the protein...  相似文献   
2.
Journal of Applied Mechanics and Technical Physics - A method for determining the empirical dependence of the rheological properties of rocks on stresses has been developed and tested in...  相似文献   
3.
Russian Physics Journal - Using the methods of modern physical materials science, the structural phase state, the defect substructure and the fracture surface of low-carbon alloy steel welds formed...  相似文献   
4.
针对线性相控阵列在固体介质中的声场聚焦特性及参数优化问题,该文给出了一个线性阵列的纵波瞬态聚焦声场模型。数值结果表明,当阵元被短时脉冲信号激励时,瞬态聚焦声场中不会形成栅瓣,突破了传统稳态理论模型中对阵元间距的限制;同时由于横纵波在聚焦区域内可完全分离,声束旁瓣的幅值也得到了抑制。其次,增大阵元间距能够显著提高聚焦性能,但会导致聚焦声场能量减弱,综合考虑后,最佳的阵元间距为一个波长左右。并且发现,阵元宽度对于聚焦性能几乎没有影响,但宽阵元能够提高聚焦能量。此外,受到纵波激发特性的影响,使得相控阵只能在低偏转角处获得理想的纵波聚焦性能。最后,采用不同阵元间距的相控阵探头对试块进行成像实验,观察到大阵元间距可以显著改善缺陷成像分辨率,从而验证了理论分析的结果。  相似文献   
5.
Journal of Analytical Chemistry - A review of works in developing optical multisensor systems, a new class of specialized spectroscopic analyzers, is presented. The development and use of such...  相似文献   
6.
Saxifraga atrata is an important traditional Tibetan medicine used to treat cough and pneumonia, and has tremendous medicinal potential. In this study, we devised a technique to separate 1,1-diphenyl-2-picrylhydrazyl inhibitors from a methanol extract of S. atrata. The material was first processed using MCI GEL CHP20P medium-pressure liquid chromatography, yielding 1.1 g of the target fraction Fr2. Subsequently, online hydrophilic interaction liquid chromatography-1,1-diphenyl-2-picrylhydrazyl assay was used to identify prospective 1,1-diphenyl-2-picrylhydrazyl inhibitors, and two 1,1-diphenyl-2-picrylhydrazyl inhibitor fractions (Fr24 and Fr25) were identified from Fr2. Then, medium-pressure preparation was continued using an XIon column to separate two 1,1-diphenyl-2-picrylhydrazyl inhibitor fractions (Fr24 and Fr25). The target compound was concentrated in fractions Fr24 and Fr25 using reverse-phase liquid chromatography during further separation procedures. Finally, the purity, structure, and 1,1-diphenyl-2-picrylhydrazyl inhibitory activity of the isolated 1,1-diphenyl-2-picrylhydrazyl inhibitors were determined. Two 1,1-diphenyl-2-picrylhydrazyl inhibitors (adenosine with the half maximal inhibitory concentration of 66.87 ± 14.33 μM and (-)-4-O-(E)-caffeoyl-l -threonic acid with the half maximal inhibitory concentration of 59.06 ± 5.02 μM) were isolated with purities exceeding 95%. The results showed that this technology is effective in the targeted separation of antioxidants from natural products.  相似文献   
7.
The chiral separation of various analytes (dichlorprop, mecoprop, ibuprofen, and ketoprofen) was demonstrated with different cyclodextrins as mobile phase additives in open-tubular liquid chromatography using a stationary pseudophase semipermanent coating. The stable coating was prepared by a successive multiple ionic layer approach using poly(diallyldimethylammonium chloride), polystyrene sulfonate, and didodecyldimethyl ammonium bromide. Increasing concentrations (0–0.2 mM) of various native and derivatized cyclodextrins in 25 mM sodium tetraborate (pH 9.2) were investigated. Chiral separation was achieved for the four test analytes using 0.05–0.1 mM β-cyclodextrin (resolution between 1.11 and 1.34), γ-cyclodextrin (resolution between 0.78 and 1.27), carboxymethyl-β-cyclodextrin (resolution between 1.64 and 2.59), and 2-hydroxypropyl-β-cyclodextrin (resolution between 0.71 and 1.76) with the highest resolutions obtained with 0.1 mM carboxymethyl-β-cyclodextrin. %RSD values were <10%. This is the first demonstration of chiral open-tubular liquid chromatography using achiral chromatographic coatings and cyclodextrins as mobile phase additives.  相似文献   
8.
The rotator cuff repaired construct must establish a contiguous and functioning tendon-bone junction to provide adequate stability. However, fibrocartilage deficiency and bone loss were hardly reversed after physical suture, especially in chronic rotator cuff tears. In this study, we synthesized an injectable methylcellulose/polyvinyl alcohol/polyvinylpyrrolidone-based thermo-sensitive hydrogel, which delivered kartogenin-loaded mesoporous bioactive glass nanoparticles. Physicochemical studies the revealed phase transition temperatures of 35 °C and its ability to induce chondrogenesis and osteogenesis differentiation of tendon-derived stem cells. Furthermore, experiments in rabbit chronic rotator cuff tears model confirmed the fibrocartilage and bone layer regenerative capability of the injected bioactive hydrogel, which could, in turn, support the ultimate tensile stress of the repaired rotator cuff. The bioactive agents-loaded hydrogel reported in this study is a valuable addition to the arsenal of biomaterials in applications to chronic tendon-bone junction injuries.  相似文献   
9.
Bo  Luo  Gao  Wei  Yu  Yuguo  Chen  Xiaojun 《Nonlinear dynamics》2022,110(1):281-311
Nonlinear Dynamics - The perovskite solar cell (PSC) is one of the most promising photovoltaic candidates along with the highly increasing demand for green electricity. One of the main concerns...  相似文献   
10.
Journal of Nanoparticle Research - Polycrystalline metallic copper nanoparticle samples with the average particle sizes ranging from 53 to 80&nbsp;nm were controllably prepared by the wet...  相似文献   
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