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Qiu-Cheng Chen Zi-Ye Xiao Shachar Fite Dr. Amir Mizrahi Dr. Natalia Fridman Xuan Zhan Or Keisar Dr. Yair Cohen Prof. Dr. Zeev Gross 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(48):11383-11388
Although the affinity of metallocorroles to axial ligands is quite low, this is not the case when the chelated element is phosphorus. This work is hence focused on the mechanism of ligand exchange of six-coordinate phosphorus corroles as a tool for affecting their chemical and physical properties. These fundamental investigations allowed for the development of facile methodologies for the synthesis of a large series of complexes and the establishment of several new structure/activity profiles that may be used to understand and predict spectroscopic features and for tailor-made modification of photophysical and electrochemical properties. This is exemplified by the facile access to complexes with terminal groups that are of large potential for practical applications based on click chemistry, optical imaging, and surface science. 相似文献
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Alberta Terzi Nunzia Gallo Simona Bettini Teresa Sibillano Davide Altamura Marta Madaghiele Liberato De Caro Ludovico Valli Luca Salvatore Alessandro Sannino Cinzia Giannini 《Macromolecular bioscience》2020,20(5)
Collagen represents one of the most widely used biomaterial for scaffolds fabrication in tissue engineering as it represents the mechanical support of natural tissues. It also provides physical scaffolding for cells and it influences their attachment, growth, and tissue regeneration. Among all fibrillary collagens, type I is considered one of the gold standard for scaffolds fabrication, thanks to its high biocompatibility, biodegradability, and hemostatic properties. It can be extracted by chemical and enzymatic protocols from several collagen‐rich tissues, such as tendon and skin, of different animal species. Both the extraction processes and the manufacturing protocols for scaffolds fabrication provide structural and mechanical changes that can be tuned in order to deeply impact the properties of the final biomaterial. The aim of this review is to discuss the role of X‐rays to study structural changes of type I collagen from fresh collagen‐rich tissues (bovine, equine, fish) to the final scaffolds, with the aim to screen across available collagen sources and scaffolds fabrication protocols to be used in tissue regeneration. 相似文献
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Automatic recognition of visual objects using a deep learning approach has been successfully applied to multiple areas. However, deep learning techniques require a large amount of labeled data, which is usually expensive to obtain. An alternative is to use semi-supervised models, such as co-training, where multiple complementary views are combined using a small amount of labeled data. A simple way to associate views to visual objects is through the application of a degree of rotation or a type of filter. In this work, we propose a co-training model for visual object recognition using deep neural networks by adding layers of self-supervised neural networks as intermediate inputs to the views, where the views are diversified through the cross-entropy regularization of their outputs. Since the model merges the concepts of co-training and self-supervised learning by considering the differentiation of outputs, we called it Differential Self-Supervised Co-Training (DSSCo-Training). This paper presents some experiments using the DSSCo-Training model to well-known image datasets such as MNIST, CIFAR-100, and SVHN. The results indicate that the proposed model is competitive with the state-of-art models and shows an average relative improvement of 5% in accuracy for several datasets, despite its greater simplicity with respect to more recent approaches. 相似文献
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Journal of Solid State Electrochemistry - 相似文献
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Influence of Solution Volume on the Dissolution Rate of Silicon Dioxide in Hydrofluoric Acid 下载免费PDF全文
Boris Shvartsev Danny Gelman Ilia Komissarov Alon Epshtein Dr. David Starosvetsky Prof. Yair Ein‐Eli 《Chemphyschem》2015,16(2):370-376
Experimental data and modeling of the dissolution of various Si/SiO2 thermal coatings in different volumes of hydrofluoric acid (HF) are reported. The rates of SiO2‐film dissolution, measured by means of various electrochemical techniques, and alteration in HF activity depend on the thickness of the film coating. Despite the small volumes (0.6–1.2 mL) of the HF solution, an effect of SiO2‐coating thickness on the dissolution rate was detected. To explain alterations detected in HF activity after SiO2 dissolution, spectroscopic analyses (NMR and FTIR) of the chemical composition of the solutions were conducted. This is associated with a modification in the chemical composition of the HF solution, which results in either the formation of an oxidized species in solution or the precipitation of dissolution products. HF2? accumulation in the HF solution, owing to SiO2 dissolution was identified as the source of the chemical alteration. 相似文献