全文获取类型
收费全文 | 77921篇 |
免费 | 391篇 |
国内免费 | 408篇 |
专业分类
化学 | 24115篇 |
晶体学 | 790篇 |
力学 | 6726篇 |
综合类 | 1篇 |
数学 | 31970篇 |
物理学 | 15118篇 |
出版年
2019年 | 26篇 |
2018年 | 10440篇 |
2017年 | 10261篇 |
2016年 | 6067篇 |
2015年 | 844篇 |
2014年 | 307篇 |
2013年 | 314篇 |
2012年 | 3782篇 |
2011年 | 10494篇 |
2010年 | 5630篇 |
2009年 | 6046篇 |
2008年 | 6581篇 |
2007年 | 8742篇 |
2006年 | 220篇 |
2005年 | 1307篇 |
2004年 | 1516篇 |
2003年 | 1965篇 |
2002年 | 1008篇 |
2001年 | 244篇 |
2000年 | 289篇 |
1999年 | 160篇 |
1998年 | 192篇 |
1997年 | 146篇 |
1996年 | 201篇 |
1995年 | 116篇 |
1994年 | 79篇 |
1993年 | 96篇 |
1992年 | 53篇 |
1991年 | 62篇 |
1990年 | 49篇 |
1989年 | 58篇 |
1988年 | 59篇 |
1987年 | 57篇 |
1986年 | 59篇 |
1985年 | 46篇 |
1984年 | 42篇 |
1983年 | 36篇 |
1982年 | 41篇 |
1981年 | 38篇 |
1980年 | 46篇 |
1979年 | 44篇 |
1978年 | 34篇 |
1973年 | 25篇 |
1914年 | 45篇 |
1913年 | 40篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
1907年 | 32篇 |
1904年 | 28篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
1.
Yuliang Zhao 《中国科学:化学(英文版)》2018,61(12):1481-1482
正Living organisms have developed their unique strategies during the natural evolution for building hard tissues with minerals, including silica, calcium carbonate, calcium phosphate, and ferric oxide [1]. Such biomineralized materials generally have complex hierarchical structures with excellent mechanical properties. Although bioinspired approaches have led to the creation of well-defined synthetic structural materials ranging from micro to macro scales, the rational design of discrete biomimetic structures at the nanoscale remains a grand challenge. 相似文献
2.
JuHong Ge 《Nonlinear dynamics》2018,94(1):87-98
A five-neuron network model with multiple delays is proposed. This paper presents the combined effect of different delays on the dynamics of the proposed network. Pitchfork bifurcation is discussed in detail with the variation of the value of coupled weight or attenuation rate of internal neurons. By analyzing the corresponding characteristic equation, some stable criteria on delay-dependence and delay-independence are derived including multiple delays and coupled weights and the periodic oscillation arises bifurcated from the trivial equilibrium after the network loses its stability. Stable regions on delay-dependence are displayed in the two delayed parameter plane. It is shown that multiple delays can produce stability switching between resting state and periodic activity. Finally, theoretical results are justified by providing two illustrative examples. 相似文献
3.
It is shown that the countably infinite dimensional pointed vector space (the vector space equipped with a constant) over a finite field has infinitely many first order definable reducts. This implies that the countable homogeneous Boolean-algebra has infinitely many reducts. 相似文献
4.
5.
Dan Xie Huan-Huan Li Yan-Hong Shi Wan-Yue Diao Ru Jiang Prof. Hai-Zhu Sun Prof. Xing-Long Wu Dr. Wenliang Li Dr. Chao-Ying Fan Prof. Jing-Ping Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(4):853-862
The Fe-based transition metal oxides are promising anode candidates for lithium storage considering their high specific capacity, low cost, and environmental compatibility. However, the poor electron/ion conductivity and significant volume stress limit their cycle and rate performances. Furthermore, the phenomena of capacity rise and sudden decay for α-Fe2O3 have appeared in most reports. Here, a uniform micro/nano α-Fe2O3 nanoaggregate conformably enclosed in an ultrathin N-doped carbon network (denoted as M/N-α-Fe2O3@NC) is designed. The M/N porous balls combine the merits of secondary nanoparticles to shorten the Li+ transportation pathways as well as alleviating volume expansion, and primary microballs to stabilize the electrode/electrolyte interface. Furthermore, the ultrathin carbon shell favors fast electron transfer and protects the electrode from electrolyte corrosion. Therefore, the M/N-α-Fe2O3@NC electrode delivers an excellent reversible capacity of 901 mA h g−1 with capacity retention up to 94.0 % after 200 cycles at 0.2 A g−1. Notably, the capacity rise does not happen during cycling. Moreover, the lithium storage mechanism is elucidated by ex situ XRD and HRTEM experiments. It is verified that the reversible phase transformation of α↔γ occurs during the first cycle, whereas only the α-Fe2O3 phase is reversibly transformed during subsequent cycles. This study offers a simple and scalable strategy for the practical application of high-performance Fe2O3 electrodes. 相似文献
6.
7.
Zinovy Reichstein 《Archiv der Mathematik》2018,111(5):449-455
We use a recent advance in birational geometry to prove new lower bounds on the essential dimension of some finite groups. 相似文献
8.
Mahmoud Roushani Zahra Saedi Fatemeh Hamdi Hamid Reza Rajabi 《Journal of the Iranian Chemical Society》2018,15(10):2241-2249
In this study, a new Cr(III)-imprinted polymer (Cr(III)-IIP) is prepared from CrCl3·6H2O, methacrylic acid functional monomer, ethyleneglycoldimethacrylate cross-linking agent, 2,2?-azobisisobutyronitrile radical initiator and 2,2-(azanediylbis (ethane-2,1-diyl))bis(isoindoline-1,3-dione) ligand. To obtain the maximum adsorption capacity, the optimum condition was studied through pH, type and concentration of eluent, IIP weight, sample volume as well as the adsorption and desorption times. The Cr(III) ion content was determined via flame atomic absorption spectrometer. In optimum conditions, the adsorption capacity of the IIP for Cr(III) was obtained to be 74.65 mg g?1, using 50 mg of IIP and the initial pH solution of 3.0. Both the adsorption and desorption times for quantitative analyses of Cr(III) ions were 15 and 5 min; respectively. After elution of the adsorbed ions by 3 mL of 4 mol L?1 HNO3 aqueous solution, the established IIP-based SPE procedure provides a reasonable pre-concentration factor of 100. The IIP-based pre-concentration method provides a low detection limit of 1.7 µg L?1 with good repeatability (RSD?=?3.22%). Reusability studies confirmed that synthesis IIP is reusable and recoverable up to six cycles. According to the selectivity experiments, it was concluded that the prepared sorbent possesses more affinity toward Cr(III) ions than other ions such as Al3+, Pb2+, Cu2+, Mn2+, Fe2+, Zn2+, and Ni2+ ions. To evaluate the potential applicability of the proposed separation method, the pre-concentration and determination of trace amounts of Cr(III) were performed successfully in food samples with complex matrices, a bestial sample (i.e. cow liver) and an herbal product (i.e., broccoli) as real samples. 相似文献
9.
Zenon Moszner 《Aequationes Mathematicae》2018,92(4):617-625
We give the form of the output function in Ginsburg’s machine in which the input and output dictionaries are abelian groups and the transition function is of a special form. 相似文献
10.
Rotating detonation combustors (RDC) are at the forefront of pressure gain combustion (PGC) research. The simplicity in design and the ease of assembly makes it a promising technology that could be integrated into existing combustor architectures. This is, however, coupled with the considerable complexities of the detonation-based flow field, and the associated modes and coupling mechanisms. The current paper is an overview of the research done at the University of Cincinnati to address some of the challenges and questions pertaining to the physics of RDC operation. Issues such as combustor geometry, injection schemes and mixing, varied reactants behavior and modes of RDC operation are discussed. The effects of pressurization of the combustor, along with other detonation enhancement strategies are also deliberated upon. When appropriate, parallels are drawn to the phenomena of high frequency combustion instabilities to address the similarities in observations between the two fields. 相似文献