Journal of Radioanalytical and Nuclear Chemistry - There is an urgent need to develop more specific targeted therapies for lung cancer treatment due to the its low survival rate. EGFR is a... 相似文献
Journal of Thermal Analysis and Calorimetry - Polyethylene glycol (PEG) is widely used as phase change materials (PCMs). However, the leakage and low thermal conductivity issues restrict its... 相似文献
The designs of efficient and inexpensive Pt-based catalysts for methanol oxidation reaction (MOR) are essential to boost the commercialization of direct methanol fuel cells. Here, the highly catalytic performance PtFe alloys supported on multiwalled carbon nanotubes (MWCNTs) decorating nitrogen-doped carbon (NC) have been successfully prepared via co-engineering of the surface composition and electronic structure. The Pt1Fe3@NC/MWCNTs catalyst with moderate Fe3+ feeding content (0.86 mA/mgPt) exhibits 2.26-fold enhancement in MOR mass activity compared to pristine Pt/C catalyst (0.38 mA/mgPt). Furthermore, the CO oxidation initial potential of Pt1Fe3@NC/MWCNTs catalyst is lower relative to Pt/C catalyst (0.71 V and 0.80 V). Benefited from the optimal surface compositions, the anti-corrosion ability of MWCNT, strong electron interaction between PtFe alloys and MWCNTs and the N-doped carbon (NC) layer, the Pt1Fe3@NC/MWCNTs catalyst presents an improved MOR performance and anti-CO poisoning ability. This study would open up new perspective for designing efficient electrocatalysts for the DMFCs field. 相似文献
Nonlinear Dynamics - In order to solve the constrained-input problem and reduce the computing resources, a novel event-triggered optimal control method is proposed for a class of discrete-time... 相似文献
Various Higgs factories are proposed to study the Higgs boson precisely and systematically in a model- independent way. In this study, the Particle Flow Network and ParticleNet techniques are used to classify the Higgs decays into multicategories, and the ultimate goal is to realize an "end-to-end" analysis. A Monte Carlo simulation study is performed to demonstrate the feasibility, and the performance looks rather promising. This result could be the basis of a "one-stop" analysis to measure all the branching fractions of the Higgs decays simultaneously. 相似文献
By chemical cross‐linking the amidoxime group onto dual‐surfaces of natural ore materials, namely halloysite nanotubes (HNTs), an efficient adsorbent, AO‐HNTs, is developed. AO‐HNTs show high uranium adsorption capacity of 456.24 mg g?1 in 32 ppm uranium‐spiked simulated seawater. In natural seawater, AO‐HNTs reach the high uranium extraction capacity of 9.01 mg g?1 after 30 days’ field test. The dual‐surface amidoximated hollow nanotubular AO‐HNTs exhibit more coordination active sites for uranium adsorption, which is attributed to the high and fast uranium adsorption capacity. Because of the stable natural ore structure, AO‐HNTs also show long service life. Benefiting from the low cost of HNTs, the cost for uranium extraction from seawater is close to the uranium price in the spot uranium market, suggesting that AO‐HNTs could be used for economical extraction of uranium from the oceans. 相似文献
The incorporation of synthetic molecules as corner units in DNA structures has been of interest over the last two decades. In this work, we present a facile method for generating branched small molecule‐DNA hybrids with controllable valency, different sequences, and directionalities (5′–3′) using a “printing” process from a simple 3‐way junction structure. We also show that the DNA‐imprinted small molecule can be extended asymmetrically using polymerase chain reaction (PCR) and can be replicated chemically. This strategy provides opportunities to achieve new structural motifs in DNA nanotechnology and introduce new functionalities to DNA nanostructures. 相似文献
The high level of fluorine and low sulfur in the ore could significantly undermine the bioleaching effectiveness. Here, a strategy to improve the bioleaching efficiency by introducing fluoride-resistant mesophilic eosinophils coupled with pyrite supplement was investigated in a bioleaching system with such ore. The results of column and heap bioleaching showed that 89.25% and 90.40% of uranium were recovered with the consortium and pyrite addition, which increased the uranium leaching rates by 13.22% and 8.96% as compared with the sulfuric acid leaching. Hence, it provides a method to improve uranium bioleaching efficiency of the high-fluorine and low-sulfur uranium ore by the consortium adding pyrite.
Herein we report a novel visible-light-mediated external reductant-free reductive cross coupling for the construction of C sp~2–C sp~3 bonds. A variety of benzylammonium salts underwent selective coupling with(hetero)aryl nitriles to deliver important diarylmethanes under mild reaction conditions. Importantly, photocatalysts can be omitted for many cases, which might involve the electron donor acceptor(EDA) complex. Mechanistic studies indicated benzylic radicals might be involved as the key intermediates. Moreover, the in situ generated NMe_3 via cleavage of C–N bond in ammonium salts acts as the electron donor,thus avoiding the use of external-reductant. 相似文献