首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2224篇
  免费   247篇
  国内免费   182篇
化学   1654篇
晶体学   26篇
力学   99篇
综合类   10篇
数学   222篇
物理学   642篇
  2023年   39篇
  2022年   40篇
  2021年   59篇
  2020年   80篇
  2019年   97篇
  2018年   69篇
  2017年   55篇
  2016年   88篇
  2015年   81篇
  2014年   110篇
  2013年   152篇
  2012年   186篇
  2011年   202篇
  2010年   126篇
  2009年   108篇
  2008年   143篇
  2007年   135篇
  2006年   122篇
  2005年   117篇
  2004年   69篇
  2003年   55篇
  2002年   68篇
  2001年   45篇
  2000年   31篇
  1999年   34篇
  1998年   28篇
  1997年   29篇
  1996年   32篇
  1995年   32篇
  1994年   21篇
  1993年   18篇
  1992年   29篇
  1991年   12篇
  1990年   21篇
  1989年   16篇
  1988年   14篇
  1987年   14篇
  1986年   6篇
  1985年   10篇
  1984年   14篇
  1983年   9篇
  1982年   6篇
  1981年   7篇
  1980年   4篇
  1979年   5篇
  1978年   3篇
  1975年   3篇
  1962年   1篇
  1961年   1篇
  1954年   1篇
排序方式: 共有2653条查询结果,搜索用时 20 毫秒
1.
2.
In this paper, we investigate the permutation behavior of a class of quadrinomials. Each term of these quadrinomials has a Niho-type exponent, and two sets of coefficient triples making the quadrinomials to be permutations are obtained. We use a substitution to transform the permutation problem into the root distribution problem in the unit circle of certain quadratic and cubic equations.  相似文献   
3.
4.
The hydrothermal reaction of Zn2+ ions with a mixture of two ligands, Hcptpy and H3btc (Hcptpy=4‐(4‐carboxyphenyl)‐2,2′:4′,4′′‐terpyridine; H3btc=1,3,5‐benzenetricarboxylic acid), led to the formation of a 3D metal–organic framework (MOF) with 1D channels, [Zn2(cptpy)(btc)(H2O)]n ( 1 ), which was structurally characterized by using single‐crystal X‐ray diffraction (SXRD). In MOF 1 , two independent Zn2+ ions were interconnected by btc3? ligands to form a 1D chain, whilst adjacent Zn2+ ions were alternately bridged by cptpy? ligands to generate a 2D sheet, which was further linked by 1D chains to form a 3D framework with a new (3,3,4,4)‐connected topology. Furthermore, compound 1 also exhibited excellent stability towards air and water and, more importantly, luminescence experiments indicated that it could serve as a probe for the sensitive detection of paraquat (PAQ) and Fe3+ ions in aqueous solution.  相似文献   
5.
Tao  Wenyan  Tu  Xinman  Chen  Jian  Zhu  Qian  Zhu  Yongqian 《Journal of Solid State Electrochemistry》2019,23(5):1613-1619
Journal of Solid State Electrochemistry - Here, a nanoporous gold electrode (NAu) was reported with a unique cone-shape nanohole structure for electrochemical sensing of nitric oxide (NO), which...  相似文献   
6.
Bacterial biofilms are difficult to eradicate because they are less susceptible to antibiotics and more easily develop resistance. Therefore, there is an urgent need for new materials that can combat planktonic bacteria and disrupt established biofilms. To tackle this challenge, we design a multifunctional zwitterionic pillar[5]arene, which can self‐assemble into weakly positively charged nanoaggregates that exhibit antibacterial activity against Gram‐negative Escherichia coli (DH5α) and Gram‐positive Staphylococcus aureus (SH1000) bacterial strains in solution. In addition, the zwitterionic pillar[5]arene can efficiently disrupt pre‐existing Escherichia coli (DH5α) biofilms and kill the biofilm‐enclosed bacteria without rapid generation of resistance.  相似文献   
7.
Tu  Yi-Shu  Tseng  Yufeng J.  Appell  Michael 《Structural chemistry》2019,30(5):1749-1759
Structural Chemistry - Alternariol and alternariol monomethyl ether are mycotoxins occasionally found in food and beverages that have been contaminated by certain fungi of the Alternaria genus....  相似文献   
8.
A design of ultrathin crystalline silicon solar cell with Si3 N4 circular truncated cone holes(CTCs) arrays on the top is proposed. In this article, we perform an optical simulation of the structure. The finite-difference time-domain method is used to calculate the optical absorption of different periods, radius of top and bottom circles and depth of Si3 N4 CTCs. The short-circuit current density generated by the optimized cells(30.17 mA/cm~2) is 32.44% more than the value gained by control group(with flat Si3 N4). Then adding a layer of back silver to allow us to better analyze optical absorption. Later, we simulate the optimization of the same configuration of different silicon thicknesses andfind that our structure does enhance the light absorption. This work uses a combined path towards achieving higher photocurrent ultrathin crystalline silicon solar cells by constructing the texture of anti-reflection coating.  相似文献   
9.
In this paper, we study the Heinz type inequalities for mappings satisfying Poisson’s equation. Some results generalize the ones obtained by Partyka and Sakan.  相似文献   
10.
Micro and nanomotors (MNMs) are micro/nanoscale devices that are able to convert chemical or external energy into mechanical motion. Based on a multitude of propulsion mechanisms, synthetic MNMs have been developed over the past decades for diverse biomedical applications, particularly drug delivery. Herein, we set out the classification of drugs delivered by MNMs, such as small molecules, nucleic acid, peptides, antibodies, and other proteins, and discuss their current limitations and possibilities in in vivo applications. Challenges and future perspectives are also discussed. With the increasing research enthusiasm in this field and the strengthening of multidisciplinary cooperation, intelligent MNMs will appear in the near future, which will have a profound impact on all related fields.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号