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1.
Different colloidal particle characterization methods are examined for their suitability to determine the particle size distribution of particles extracted from steels. Microalloyed steels are dissolved to extract niobium and titanium carbonitride particles that are important for the mechanical properties of these steels. Such particles have sizes ranging from several nanometers to hundreds of nanometers depending on the precipitation stage during the thermomechanically controlled rolling process. The size distribution of the particles is analyzed by dynamic light scattering (DLS), analytical ultracentrifugation (AUC), and hollow fiber flow field-flow fractionation (HF5) and compared to data obtained for reference particles as well as data from electron microscopy, the standard sizing technique used in metallurgy today. AUC and HF5 provide high-quality size distributions, average over large particle numbers that enables statistical analysis, and yield useful insights for alloy design; however, DLS fails due to a lack of resolution. Important aspects in the conversion and comparison of size distributions obtained for broadly distributed particle systems with different measurement principles and the role of surfactants used in sample preparation are discussed.  相似文献   
2.
A theoretical analysis on the electric double layer formed near the surface of an infinite cylinder with an elliptical cross section and a prescribed electric potential in an ionic conductor was performed using the linearized Gouy–Chapman theory. A semi-analytical solution in terms of the Mathieu functions was obtained. The distributions of the electric potential, cations, anions, and electric field were calculated. The effects of various physical and geometric parameters were examined. The fields vary rapidly near the elliptical boundary and are nearly uniform at far field. Electric field concentrations were found at the ends of the semi-major and semi-minor axes of the ellipse. These concentrations are sensitive to the physical and geometric parameters.  相似文献   
3.
This paper investigates quasi-periodic vibration-based energy harvesting in a delayed nonlinear MEMS device consisting of a delayed Mathieu–van der Pol–Duffing type oscillator coupled to a delayed piezoelectric coupling mechanism. We use the multiple scales method to approximate the quasi-periodic response and the related power output near the principal parametric resonance. The effect of time delay on the energy harvesting performance is studied. It is shown that for appropriate combination of time delay parameters, there exists an optimum range of excitation frequency beyond the resonance where quasi-periodic vibration-based energy harvesting is maximum. Numerical simulations are performed to confirm the analytical predictions.  相似文献   
4.
The present article is devoted to find some invariant solutions of the \((2+1)\)-dimensional Bogoyavlenskii equations using similarity transformations method. The system describes \((2+1)\)-dimensional interaction of a Riemann wave propagating along y-axis with a long wave along x-axis. All possible vector fields, commutative relations and symmetry reductions are obtained by using invariance property of Lie group. Meanwhile, the method reduces the number of independent variables by one, which leads to the reduction of Bogoyavlenskii equations into a system of ordinary differential equations. The system so obtained is solved under some parametric restrictions and provides invariant solutions. The derived solutions are much efficient to explain the several physical properties depending upon various existing arbitrary constants and functions. Moreover, some of them are more general than previously established results (Peng and Shen in Pramana 67:449–456, 2006; Malik et al. in Comput Math Appl 64:2850–2859, 2012; Zahran and Khater in Appl Math Model 40:1769–1775, 2016; Zayed and Al-Nowehy in Opt Quant Electron 49(359):1–23, 2017). In order to provide rich physical structures, the solutions are supplemented by numerical simulation, which yield some positons, negatons, kinks, wavefront, multisoliton and asymptotic nature.  相似文献   
5.
Metal halide perovskite nanomaterials emerged as attractive emitting materials for light-emitting diodes (LEDs) devices due to their high photoluminescence quantum yield (PLQY), narrow bandwidth, high charge-carrier mobility, bandgap tunability, and facile synthesis. In the past few years, it has been witnessed an unprecedented advance in the field of metal halide perovskite nanomaterials based LEDs (PeLEDs) with a rapid external quantum efficiency (EQE) increase from 0.1% to 14.36%. From the viewpoint of material chemistry, the chemical regulation of metal halide perovskite nanomaterials made a great contribution to the efficiency improvement of PeLEDs. In this review, we categorize the strategies of chemical regulation as A-site cation engineering, B-site ion doping, X-site ion exchange, dimensional confinement, ligand exchange, surface passivation and interface optimization of transport layers for improving the EQEs of PeLEDs. We also show the potentials of chemical regulation strategies to enhance the stability of PeLEDs. Finally, we present insight toward future research directions and an outlook to further improve EQEs and stabilities of PeLEDs aiming to practical applications.  相似文献   
6.
In the present study, a simple versatile extraction method based on supramolecular solvent microextraction followed by inductively coupled plasma atomic emission spectrometry was developed for the extraction, separation and determination of zirconium (Zr) from hafnium (Hf). Zr and Hf were complexed with bis(2,4,4-trimethylpentyl) phosphinic acid, to obtain hydrophobic complex, and extracted into supramolecular solvent phase. The effective parameters on the supramolecular solvent microextraction efficiency were studied and optimized by using two different optimization methods: one variable at a time and central composite design. Under the optimum conditions, the linear range of 0.3–200.0 and 2.0–200.0 µg L?1, detection limits (S/N = 3) of 0.1 and 0.6 µg L?1, and precisions (n = 5) of 3.2–4.9% and 3.0–5.1% were obtained for Zr and Hf, respectively. Finally, the proposed method has been successfully applied for the extraction and separation of these cations in zirconium ore sample.  相似文献   
7.
In this paper we study the limit cycles of some classes of piecewise smooth vector fields defined in the two dimensional torus. The piecewise smooth vector fields that we consider are composed by linear, Ricatti with constant coefficients and perturbations of these one, which are given in (3). Considering these piecewise smooth vector fields we characterize the global dynamics, studying the upper bound of number of limit cycles, the existence of non-trivial recurrence and a continuum of periodic orbits. We also present a family of piecewise smooth vector fields that posses a finite number of fold points and, for this family we prove that for any 2k number of limit cycles there exists a piecewise smooth vector fields in this family that presents k number of limit cycles and prove that some classes of piecewise smooth vector fields presents a non-trivial recurrence or a continuum of periodic orbits.  相似文献   
8.
It is unclear whether turbulent flame speed scalings established in low speed regimes are applicable to supersonic flames. To investigate this question, the canonical flame kernel is investigated in a scramjet-like channel having a one degree wall divergence. The growth, shape and internal kernel dynamics are investigated. Results are presented for three Mach numbers, four equivalence ratios, and three turbulence generators. Schlieren photography provides flame images for growth rate statistics and particle image velocimetry (PIV) provides turbulence statistics and investigation of internal kernel dynamics. Supersonic flame kernels are self-propagating and respond to the equivalence ratio in a fashion that is similar to low speed flames. However, supersonic flame kernels have features that are not present in subsonic flame kernels. Baroclinicity, resulting from pressure-density misalignment, creates a reacting vortex ring structure. Further, the mean kernel shape has a Mach number dependence and the vortex ring enhances the turbulent flame speed through entrainment of reactants and augmented flame surface growth. Hence, the previously established (low speed) flame speed scalings are inappropriate for supersonic flame kernels. Drawing motivation from vortex ring literature, the ring propagation velocity is used as the characteristic velocity and a new flame speed scaling is proposed.  相似文献   
9.
Exploration of novel organic luminophores that exhibit thermally activated delayed fluorescence (TADF) in the aggregated state is very crucial for advance of delayed luminescence-based applications such as time-gated bio-sensing and temperature sensing. We report herein that synthesis, photophysical properties, molecular and crystal structures, and theoretical calculations of 2,6-bis (diarylamino)benzophenones. Absorption spectra in solution and calculations using density functional theory (DFT) method revealed that the optical excitation took place through intramolecular charge-transfer from one diarylamino moiety to an aroyl group. While the benzophenones did not luminesce in solution, the solids of the benzophenones emitted green light with moderate-to-good quantum yields. Thus, the benzophenones exhibit aggregation-induced emission. Based on the lifetime measurement, the green emission of the solids was found to include TADF. The emergence of the TADF is supported by the small energy gap between the excited singlet and triplet states, which was estimated by time-dependent DFT calculations. Thin films of poly(methyl methacrylate) doped by the benzophenones also showed green prompt and delayed fluorescence whose lifetimes were in the order of microseconds. Linear correlation between logarithm value of TADF lifetime and temperature was observed with the benzophenone in powder, suggesting that the benzophenones can serve as molecular thermometers workable under aqueous conditions.  相似文献   
10.
The starting material 2-furan-2-yl-4-mercapto-6-methylpyrimidine-5-carbonitrile 3 was reacted with various reagents resulting in the formation of a group of new pyrimidines and condensed pyrimidines including quinazoline 6 tetrazolopyrimidine 12, pyrazolopyrimidines 14, 18, and 19, triazolopyrimidine 16, and pyrimidopyridazine 20. The antibacterial activity was evaluated for a group of the synthesized compounds against examples of Gram-positive and Gram-negative bacteria.  相似文献   
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