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1.
Summary For a given fractional 2 m factorial (2 m -FF) designT, the constitution of a block plan to divideT intok (2 r−1<k≦2 r ) blocks withr block factors each at two levels is proposed and investigated. The well-known three norms of the confounding matrix are used as measures for determining a “good” block plan. Some theorems concerning the constitution of a block plan are derived for a 2 m -FF design of odd or even resolution. Two norms which may be preferred over the other norm are slightly modified. For each value ofN assemblies with 11≦N≦26, optimum block plans fork=2 blocks with block sizes [N/2] andN−[N/2] minimizing the two norms are presented forA-optimal balanced 24-FF designs of resolutionV given by Srivastava and Chopra (Technometrics,13, 257–269).  相似文献   
2.
Simultaneous two-dimensional imaging of an unburnt area and a reacting area was performed using laser-induced fluorescence. Acetone was added to fuel as a tracer, and OH radical was used as a marker of the reacting area. A narrow band tunable KrF excimer laser (248 nm) was employed to excite acetone and OH simultaneously. Two intensified CCD cameras with different wavelength filters were used to detect these two kinds of species respectively. Detecting 294-314 nm (A-X (3, 2), etc.) for OH and 335-410 nm for acetone, we obtained images of each species without interference of a signal from the other. The method was also successfully applied to flames in a pressurized combustion chamber under the pressure of 0.5 MPa.  相似文献   
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Inclusion complex formation of piromidic acid (PA) with dimethyl--cyclodextrin (DM--CD) in aqueous solution and in the solid state was confirmed by the solubility method, differential scanning calorimetry (DSC) and proton nuclear magnetic resonance (1H-NMR) spectroscopy. The apparent stability constant,K c , of the complex was estimated to be 244 M–1. The stoichiometry of the complex was given as the ratio 1:2 of PA to DM--CD. The dissolution rate of the PA/DM--CD complex was much greater than that of intact PA.Presented at the Fourth International Symposium on Inclusion Phenomena and the Third International Symposium on Cyclodextrins, Lancaster, U.K., 20–25 July 1986.  相似文献   
5.
A new method to investigate the initial protein folding dynamics is developed based on a pulsed laser light triggering method and a unique transient grating method. The side chain of the cysteine residue of apoplastocyanin (apoPC) was site-specifically modified with a 4,5-dimethoxy-2-nitrobenzyl derivative, where the CD and 2D NMR spectra showed that the modified apoPC was unfolded. The substituent was cleaved with a rate of about 400 ns by photoirradiation, which was monitored by the disappearance of the absorption band at 355 nm and the increase in the transient grating signal. After a sufficient time from the photocleavage reaction, the CD and NMR spectra showed that the native beta-sheet structure was recovered. Protein folding dynamics was monitored in the time domain with the transient grating method from a viewpoint of the molecular volume change and the diffusion coefficient, both of which reflect the global structural change, including the protein-water interaction. The observed volume decrease of apoPC with a time scale of 270 micros is ascribed to the initial hydrophobic collapse. The increase in the diffusion coefficient (23 ms) is considered to indicate a change from an intermolecular to an intramolecular hydrogen bonding network. The initial folding process of apoPC is discussed based on these observations.  相似文献   
6.
A simultaneous visualization technique of reacting and unburned zones using laser-induced fluorescence (LIF) was applied to a high-pressure combustion field in an engine cylinder. Crevice flow from a crevice between a piston and a cylinder wall of a spark ignition gas engine was visualized by LIF of OH and acetone. OH was excited simultaneously with acetone that was seeded into fuel as a tracer by an excitation light at 283.92 nm. Fluorescence signals from each species were detected individually by two intensified CCD cameras using optical band-pass filters which transmit fluorescence wavelength of OH and acetone, respectively. Pressure- and temperature-dependence of LIF signals from each species were evaluated. From the visualized images, it was clarified that oxidation of the crevice flow is stopped at the time of exhaust valve opening. Effects of exhaust port pressure on the oxidation process were investigated.  相似文献   
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The effect of -cyclodextrin (-CD) on the disposition of hexobarbital (HBA) and phenobarbital (PhBA) after intravenous administration, with the simultaneous administration with -CD, was investigated in mice.In the case of HBA, the whole blood concentration was slightly heightened, the brain and liver concentrations were significantly lowered, and the kidney concentration was significantly heightened. Moreover, -CD also influenced the disposition and formation of 3-hydroxy- and 3-keto-HBA. On the other hand, in the case of PhBA, the whole blood concentration was slightly lowered, the time at maximum brain concentration (t-max) was prolonged about 30 to 60 min, the kidney concentration was significantly heightened at the initial stage, while the liver concentration did not show a clear difference by the simultaneous administration with -CD. These results suggest that the disposition of drugs might be modified by the use of CD.  相似文献   
9.
The C-H bond of a terminal alkyne adds to a carbon-carbon double bond of 1,3-dienes, styrenes, and norbornene at room temperature in the presence of a nickel catalyst in regio- and stereoselective manners. Reaction of triisopropylsilylacetylene with 1-substituted 1,3-butadiene derivatives afforded hydroalkynylation products via introduction of a hydrogen atom and a triisopropylsilylethynyl group to 4- and 3-positions of the dienes, respectively. Likewise, 1-triisopropylsiloxy-1,3-butadiene, 1,3-pentadiene, 1-cyclohexen-1-yl-1,3-butadiene, and 1,3-cyclohexadiene underwent the hydroalkynylation reaction, giving the corresponding 1,4-enyne derivatives in good yields at room temperature. Reaction of p-substituted styrene with triisopropylsilylacetylene also proceeded in the presence of the nickel catalyst, giving the branched hydroalkynylation products in good yields. Norbornene gave a exo-addition product in good yield under the same reaction conditions.  相似文献   
10.
Takahashi  N.  Shimoda  T.  Miyatake  H.  Mitsuoka  S.  Mizoi  Y.  Kobayashi  H.  Sasaki  M.  Shirakura  T.  Ueno  H.  Asahi  K.  Morinobu  S. 《Hyperfine Interactions》1996,97(1):469-477
A novel method was tried successfully to trap ions and to freeze out their nuclear polarization inside aggregates of helium atoms, snowballs, in superfluid helium. Spin polarized12B (T 1/2=20.4 ms) ions were introduced into superfluid helium and snowballs were created around the impinged impurity ions. Beta-ray asymmetry was measured to obtain the nuclear polarization of decaying12B. The comparison with the initial value of12B polarization produces that no relaxation in polarization was observed throughout lifetime of12B.  相似文献   
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