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排序方式: 共有399条查询结果,搜索用时 15 毫秒
1.
Chromatographia - The present work deals with the optimization, validation and application of a versatile HPLC–DAD method for concurrent estimation of nine antimicrobials and proton pump... 相似文献
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Heavy metal ions are harmful to aquatic life and humans owing to their high toxicity and non‐biodegradability, so their removal from wastewater is an important task. Therefore, this work focuses on designing suitable, simple and economical nanosensors to detect and remove these metal ions with high selectivity and sensitivity. Based on this idea, different types of mesoporous materials such as hexagonal SBA‐15, cubic SBA‐16 and spherical MCM‐41, their chloro‐functionalized derivatives, as well as 4‐(4‐nitro‐phenylazo)‐naphthalen‐1‐ol (NPAN) azo dye have been synthesized, with the aim of designing some optical nanosensors for metal ions sensing applications. The mentioned azo dye has been anchored into the chloro‐functionalized mesoporous materials. The designed nanosensors were characterized using scanning and transmission electron microscopy as well as Fourier transform infrared and UV–visible spectral analysis, nitrogen adsorption–desorption isotherms, low‐angle X‐ray diffraction and thermogravimetric analyses. Their optical sensing to various toxic metal ions such as Cd (II), Hg (II), Mn (II), Fe (II), Zn (II) and Pb (II) at different values of pH (1.1, 4.9, 7 and 12) was investigated. The optimization of experimental conditions, including the effect of pH and metal ion concentration, was examined. The experimental results showed that the solution pH had a major impact on metal ion detection. The optical nanosensors respond well to the tested metal ions, as reflected by the enhancement in both absorption and emission spectra upon adding different concentrations of the metal salts and were fully reversible on adding ethylene diamine tetra acetic acid or citric acid to the formed complexes. High values of the binding constants for the designed nanosensors were observed at pHs 7 and 12, confirming the strong chelation of different metals to the nanosensor at these pHs. Also, high binding constants and sensitivity were observed for NPAN‐MCM‐41 as a nanosensor to detect the different metal ions. From the obtained results, we succeeded in transforming the harmful azo dye into an environmentally friendly form via designing of the optical nanosensors used to detect toxic metal ions in wastewater with high sensitivity. 相似文献
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An ultrasound-assisted nanoscaled supramolecular coordination polymer (nanosized 1′ ) has been synthesized using a self-assembly reaction of K3[Cu (CN)4] and hexamethylenetetramine in the presence of Me3SnCl under ambient conditions. Nanosized 1′ was examined using elemental analysis, Fourier transform–infrared, transmission electron microscopy, scanning electron microscopy and X-ray powder diffractions. It was structurally compared with the single crystal supramolecular coordination polymer ∞3[Cu6(CN)7(C6H12N4)2(OH3)]; SCP 1. The photocatalytic activities of nanosized 1′ and SCP 1 toward different hazardous organic dyes were determined under ambient, UV-light irradiation and ultrasonic conditions. SCP 1 and nanosized 1′ as heterogeneous nanoparticles catalysts exhibited high catalytic activity for degradation of Congo Red, Methyl Violet 2B and Methylene Blue dyes. The effects of operational parameters on catalytic degradation process, identification of the degradation products and recycling of the catalyst were also investigated. SCP 1 and nanosized 1′ are recyclable heterogeneous catalysts and can be reused with efficient activities. The mechanism of degradation using different scavenger techniques iss proposed and discussed. The catalytic oxidation process is mainly caused by •OH radicals. 相似文献
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Peter?ConstantinEmail authorView authors OrcID profile Tarek?Elgindi Mihaela?Ignatova Vlad?Vicol 《Journal of Nonlinear Science》2017,27(1):197-211
We consider a model of electroconvection motivated by studies of the motion of a two-dimensional annular suspended smectic film under the influence of an electric potential maintained at the boundary by two electrodes. We prove that this electroconvection model has global in time unique smooth solutions. 相似文献
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Marwa A. A. Ragab Hadir M. Maher Salma Tarek Hoda Mahgoub 《Journal of separation science》2023,46(4):2200951
Gastrointestinal tract disorders constitute a heavy burden to healthcare providers. To eradicate Helicobacter pylori infection, different triple therapy protocols have been proposed. Among which are combinations of proton pump inhibitors (e.g., omeprazole), histamine-2 receptor antagonists (e.g., famotidine), along with antibiotics (e.g., amoxicillin). In this work, a sensitive and accurate high-performance thin-layer chromatographic method was developed for the simultaneous determination of amoxicillin, metronidazole, and famotidine in bulk powder and laboratory-prepared combined-tablet mixtures. Complete separation of the cited compounds was achieved using pre-coated silica gel plates with a mixture of methanol:chloroform:toluene:water:glacial acetic acid (5:2:1.5:0.5:0.1 v/v/v/v/v) as the mobile phase. The method was fully validated as per the international conference of harmonization guidelines. Good linearity, a correlation coefficient of 0.9991, was obtained in the concentration ranges 0.1–1.6 μg/band (amoxicillin), 0.1–0.9 μg/band (metronidazole), and 0.1–0.9 μg/band (famotidine). Since the method allowed the determination of the three compounds in combined tablets with a high degree of selectivity, accuracy, precision, with cost-effectiveness, it could be used for regular quality control. Moreover, the applicability of the proposed method was extended to the determination of the ternary mixture in simulated gastric juice. Method greenness was assessed using different green metrics. 相似文献
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Several new pyridine derivatives were prepared via reaction of enaminoketones 1a , 1b , 1c , 1d with active hydrogen reagents. Reaction of the enaminoketones 1a , 1b , 1c with 4‐acetyl‐1,5‐dimethyl‐2‐phenyl‐1H‐pyrazol‐3(2H)‐one 2a yielded the pyridines 3a , 3b , 3c . Condensation of the enaminonitrile 1d with compounds 2b , 2c , 2d and compound 8 gave the pyridine derivatives 6a , 6b , 6c and 10 respectively. Also, (3‐(dimethylamino)acryloyl)‐2H‐chromen‐2‐one 1a reacted with active methylenes in diethyl 3‐oxopentanedioate 12 and 4‐methyl‐6‐oxo‐2‐thioxo‐1,2,5,6‐tetrahydropyridine‐3‐carbonitrile 15 to afford the pyridine derivatives 14 and 16 respectively. 相似文献
8.
Although, the effects of ultrasonic irradiation on multiphase flow through porous media have been studied in the past few
decades, the physics of the acoustic interaction between fluid and rock is not yet well understood. Various mechanisms may
be responsible for enhancing the flow of oil through porous media in the presence of an acoustic field. Capillary related
mechanisms are peristaltic transport due to mechanical deformation of the pore walls, reduction of capillary forces due to
the destruction of surface films generated across pore boundaries, coalescence of oil drops due to Bjerknes forces, oscillation
and excitation of capillary trapped oil drops, forces generated by cavitating bubbles, and sonocapillary effects. Insight
into the physical principles governing the mobilization of oil by ultrasonic waves is vital for developing and implementing
novel techniques of oil extraction. This paper aims at identifying and analyzing the influence of high-frequency, high-intensity
ultrasonic radiation on capillary imbibition. Laboratory experiments were performed using cylindrical Berea sandstone and
Indiana limestone samples with all sides (quasi-co-current imbibition), and only one side (counter-current imbibition) contacting
with the aqueous phase. The oil saturated cores were placed in an ultrasonic bath, and brought into contact with the aqueous
phase. The recovery rate due to capillary imbibition was monitored against time. Air–water, mineral oil–brine, mineral oil–surfactant
solution and mineral oil-polymer solution experiments were run each exploring a separate physical process governing acoustic
stimulation. Water–air imbibition tests isolate the effect of ultrasound on wettability, capillarity and density, while oil–brine
imbibition experiments help outline the ultrasonic effect on viscosity and interfacial interaction between oil, rock and aqueous
phase. We find that ultrasonic irradiation enhances capillary imbibition recovery of oil for various fluid pairs, and that
such process is dependent on the interfacial tension and density of the fluids. Although more evidence is needed, some runs
hint that wettability was not altered substantially under ultrasound. Preliminary analysis of the imbibition recoveries also
suggests that ultrasound enhances surfactant solubility and reduce surfactant adsorption onto the rock matrix. Additionally,
counter-current experiments involving kerosene and brine in epoxy coated Berea sandstone showed a dramatic decline in recovery.
Therefore, the effectiveness of any ultrasonic application may strongly depend on the nature of interaction type, i.e., co-
or counter-current flow. A modified form of an exponential model was employed to fit the recovery curves in an attempt to
quantify the factors causing the incremental recovery by ultrasonic waves for different fluid pairs and rock types. 相似文献
9.
Mass spectral studies on 1‐n‐pentyl‐3‐(1‐naphthoyl)indole (JWH‐018), three deuterium‐labeled analogues and the inverse isomer 1‐naphthoyl‐3‐n‐pentylindole 下载免费PDF全文
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