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1.
Herein, we report a Mott-Schottky catalyst by entrapping cobalt nanoparticles inside the N-doped graphene shell (Co@NC). The Co@NC delivered excellent oxygen evolution activity with an overpotential of merely 248 mV at a current density of 10 mA cm–2 with promising long-term stability. The importance of Co encapsulated in NC has further been demonstrated by synthesizing Co nanoparticles without NC shell. The synergy between the hexagonal close-packed (hcp) and face-centered cubic (fcc) Co plays a major role to improve the OER activity, whereas the NC shell optimizes the electronic structure, improves the electron conductivity, and offers a large number of active sites in Co@NC. The density functional theory calculations have revealed that the hcp Co has a dominant role in the surface reaction of electrocatalytic oxygen evolution, whereas the fcc phase induces the built-in electric field at the interfaces with N-doped graphene to accelerate the H+ ion transport.  相似文献   
2.
正Living organisms have developed their unique strategies during the natural evolution for building hard tissues with minerals, including silica, calcium carbonate, calcium phosphate, and ferric oxide [1]. Such biomineralized materials generally have complex hierarchical structures with excellent mechanical properties. Although bioinspired approaches have led to the creation of well-defined synthetic structural materials ranging from micro to macro scales, the rational design of discrete biomimetic structures at the nanoscale remains a grand challenge.  相似文献   
3.
A five-neuron network model with multiple delays is proposed. This paper presents the combined effect of different delays on the dynamics of the proposed network. Pitchfork bifurcation is discussed in detail with the variation of the value of coupled weight or attenuation rate of internal neurons. By analyzing the corresponding characteristic equation, some stable criteria on delay-dependence and delay-independence are derived including multiple delays and coupled weights and the periodic oscillation arises bifurcated from the trivial equilibrium after the network loses its stability. Stable regions on delay-dependence are displayed in the two delayed parameter plane. It is shown that multiple delays can produce stability switching between resting state and periodic activity. Finally, theoretical results are justified by providing two illustrative examples.  相似文献   
4.
It is shown that the countably infinite dimensional pointed vector space (the vector space equipped with a constant) over a finite field has infinitely many first order definable reducts. This implies that the countable homogeneous Boolean-algebra has infinitely many reducts.  相似文献   
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We use a recent advance in birational geometry to prove new lower bounds on the essential dimension of some finite groups.  相似文献   
8.
In this study, a new Cr(III)-imprinted polymer (Cr(III)-IIP) is prepared from CrCl3·6H2O, methacrylic acid functional monomer, ethyleneglycoldimethacrylate cross-linking agent, 2,2?-azobisisobutyronitrile radical initiator and 2,2-(azanediylbis (ethane-2,1-diyl))bis(isoindoline-1,3-dione) ligand. To obtain the maximum adsorption capacity, the optimum condition was studied through pH, type and concentration of eluent, IIP weight, sample volume as well as the adsorption and desorption times. The Cr(III) ion content was determined via flame atomic absorption spectrometer. In optimum conditions, the adsorption capacity of the IIP for Cr(III) was obtained to be 74.65 mg g?1, using 50 mg of IIP and the initial pH solution of 3.0. Both the adsorption and desorption times for quantitative analyses of Cr(III) ions were 15 and 5 min; respectively. After elution of the adsorbed ions by 3 mL of 4 mol L?1 HNO3 aqueous solution, the established IIP-based SPE procedure provides a reasonable pre-concentration factor of 100. The IIP-based pre-concentration method provides a low detection limit of 1.7 µg L?1 with good repeatability (RSD?=?3.22%). Reusability studies confirmed that synthesis IIP is reusable and recoverable up to six cycles. According to the selectivity experiments, it was concluded that the prepared sorbent possesses more affinity toward Cr(III) ions than other ions such as Al3+, Pb2+, Cu2+, Mn2+, Fe2+, Zn2+, and Ni2+ ions. To evaluate the potential applicability of the proposed separation method, the pre-concentration and determination of trace amounts of Cr(III) were performed successfully in food samples with complex matrices, a bestial sample (i.e. cow liver) and an herbal product (i.e., broccoli) as real samples.  相似文献   
9.
We give the form of the output function in Ginsburg’s machine in which the input and output dictionaries are abelian groups and the transition function is of a special form.  相似文献   
10.
Rotating detonation combustors (RDC) are at the forefront of pressure gain combustion (PGC) research. The simplicity in design and the ease of assembly makes it a promising technology that could be integrated into existing combustor architectures. This is, however, coupled with the considerable complexities of the detonation-based flow field, and the associated modes and coupling mechanisms. The current paper is an overview of the research done at the University of Cincinnati to address some of the challenges and questions pertaining to the physics of RDC operation. Issues such as combustor geometry, injection schemes and mixing, varied reactants behavior and modes of RDC operation are discussed. The effects of pressurization of the combustor, along with other detonation enhancement strategies are also deliberated upon. When appropriate, parallels are drawn to the phenomena of high frequency combustion instabilities to address the similarities in observations between the two fields.  相似文献   
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