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排序方式: 共有199条查询结果,搜索用时 15 毫秒
1.
This article deals with the various heat source responses in a transversely isotropic hollow cylinder under the purview of three-phase-lag (TPL) generalized thermoelasticity theory. In presence of magnetic field and due to the rotating behavior of the cylinder, the governing equations are redefined for generalized thermoelasticity with thermal time delay. In order to obtain the stress, displacement and temperature field, the field functions are expressed in terms of modified Bessel functions in Laplace transformed domain. When the outer radius of hollow cylinder tends to infinity, the corresponding results are discussed. Finally an appropriate Laplace transform inversion technique is adopted. 相似文献
2.
Siddhartha Biswas 《Waves in Random and Complex Media》2020,30(4):759-775
ABSTRACT The article deals with the study of plane wave propagation in the thermoelastic medium in the presence of voids. The problem is considered in the context of three-phase-lag model of generalized thermoelasticity. There exists three longitudinal waves, namely elastic (E-mode), thermal (T-mode) and volume fraction (V-mode) in addition to transverse waves which get decoupled from the rest of motion and not affected by thermal and volume fraction fields. The fundamental solution of the system of differential equations in case of steady oscillations in terms of the elementary functions has been constructed. The phase velocity and attenuation coefficient of these waves are computed numerically and presented graphically. 相似文献
3.
Dr. Siddhartha De Dr. Alexandrine Flambard Dr. Delphine Garnier Patrick Herson Dr. Frank H. Köhler Dr. Abhishake Mondal Dr. Karine Costuas Dr. Béatrice Gillon Prof. Rodrigue Lescouëzec Dr. Boris Le Guennic Dr. Frédéric Gendron 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(52):12120-12136
The local magnetic structure in the [FeIII(Tp)(CN)3]− building block was investigated by combining paramagnetic Nuclear Magnetic Resonance (pNMR) spectroscopy and polarized neutron diffraction (PND) with first-principle calculations. The use of the pNMR and PND experimental techniques revealed the extension of spin-density from the metal to the ligands, as well as the different spin mechanisms that take place in the cyanido ligands: Spin-polarization on the carbon atoms and spin-delocalization on the nitrogen atoms. The results of our combined density functional theory (DFT) and multireference calculations were found in good agreement with the PND results and the experimental NMR chemical shifts. Moreover, the ab-initio calculations allowed us to connect the experimental spin-density map characterized by PND and the suggested distribution of the spin-density on the ligands observed by NMR spectroscopy. Interestingly, significant differences were observed between the pseudo-contact contributions of the chemical shifts obtained by theoretical calculations and the values derived from NMR spectroscopy using a simple point-dipole model. These discrepancies underline the limitation of the point-dipole model and the need for more elaborate approaches to break down the experimental pNMR chemical shifts into contact and pseudo-contact contributions. 相似文献
4.
5.
Ulrik S. Fjordholm Roger Käppeli Siddhartha Mishra Eitan Tadmor 《Foundations of Computational Mathematics》2017,17(3):763-827
Entropy solutions have been widely accepted as the suitable solution framework for systems of conservation laws in several space dimensions. However, recent results in De Lellis and Székelyhidi Jr (Ann Math 170(3):1417–1436, 2009) and Chiodaroli et al. (2013) have demonstrated that entropy solutions may not be unique. In this paper, we present numerical evidence that state-of-the-art numerical schemes need not converge to an entropy solution of systems of conservation laws as the mesh is refined. Combining these two facts, we argue that entropy solutions may not be suitable as a solution framework for systems of conservation laws, particularly in several space dimensions. We advocate entropy measure-valued solutions, first proposed by DiPerna, as the appropriate solution paradigm for systems of conservation laws. To this end, we present a detailed numerical procedure which constructs stable approximations to entropy measure-valued solutions, and provide sufficient conditions that guarantee that these approximations converge to an entropy measure-valued solution as the mesh is refined, thus providing a viable numerical framework for systems of conservation laws in several space dimensions. A large number of numerical experiments that illustrate the proposed paradigm are presented and are utilized to examine several interesting properties of the computed entropy measure-valued solutions. 相似文献
6.
Massimo Brochetta Tania Borsari Sukdev Bag Dr. Sadhan Jana Siddhartha Maiti Prof. Dr. Alessio Porta Prof. Dr. Daniel B. Werz Prof. Dr. Giuseppe Zanoni Prof. Dr. Debabrata Maiti 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(44):10323-10327
The development of efficient and mild methods for the synthesis of organofluorine compounds is of foremost interest in various fields of chemistry. A direct pyrimidine-based selective meta-C−H perfluoroalkenylation of arenes involving several commercially available perfluoroolefins is described. The synthetic versatility of the protocol is demonstrated by an extensive substrate scope including different benzylsulfonyl, alkylarene and phenylacetic acid scaffolds. The generality of this methodology including the meta-C−H perfluoroalkenylation of Ibuprofen, the facile cleavage of the directing group and gram-scale reactions are presented. 相似文献
7.
Krishna Dan Priya Rajdev Jolly Deb Siddhartha S. Jana Suhrit Ghosh 《Journal of polymer science. Part A, Polymer chemistry》2013,51(22):4932-4943
Synthesis of a library of amphiphilic random copolymers from a single reactive pre‐polymer and their self‐assembly is reported. Post‐polymerization modifications of the parent polymer containing pendant N‐hydroxy succinimide (NHS) ester groups with various oligooxyethylene (OE) amines produce amphiphilic random copolymers with same degree of polymerization and equal extent of randomness. 1H‐NMR and FT‐IR data indicate quantitative substitution in all cases. The critical aggregation concentration (CAC) for all the polymers is estimated to be in the range of 10?5 M. Stability of these nano‐aggregates is studied by photoluminescence using time dependent F—rster Resonance Energy Transfer (FRET) between co‐encapsulated lipophilic dyes namely DiO and DiI in the hydrophobic pocket of the aggregates. These studies suggest remarkably high stability for all systems. However those with shorter hydrophilic pendant chains are found to be even more robust. Morphology is examined by high resolution transmission electron microscopy (HRTEM) which reveals multi‐micellar clusters and vesicles for polymers containing short and longer OE segments, respectively. Encapsulation efficacy is tested with both hydrophobic and hydrophilic guest molecules. All of them can encapsulate hydrophobic guest pyrene while a hydrophilic dye Calcein can be sequestered only in vesicle forming polymers. Lower critical solution temperature (LCST) is exhibited by only one polymer that contains the shortest OE chains. All polymers exhibit excellent cell viability as determined by MTT assay. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4932–4943 相似文献
8.
Srivastava Nishi Verma Shikhar Pragyadeep Siddhartha Srivastava Sharad Rawat Ajay Kumar Singh 《平面色谱法杂志一现代薄层色谱法》2014,27(1):69-71
JPC – Journal of Planar Chromatography – Modern TLC - 相似文献
9.
We seek to develop network algorithms for function computation in sensor networks. Specifically, we want dynamic joint aggregation, routing, and scheduling algorithms that have analytically provable performance benefits due to in-network computation as compared to simple data forwarding. To this end, we define a class of functions, the Fully-Multiplexible functions, which includes several functions such as parity, MAX, and kth-order statistics. For such functions we characterize the maximum achievable refresh rate of the network in terms of an underlying graph primitive, the min-mincut. In acyclic wireline networks we show that the maximum refresh rate is achievable by a simple algorithm that is dynamic, distributed, and only dependent on local information. In the case of wireless networks we provide a MaxWeight-like algorithm with dynamic flow-splitting, which is shown to be throughput-optimal. 相似文献
10.
Baishali Chakraborty Kumar S. Gupta Siddhartha Sen 《The European Physical Journal B - Condensed Matter and Complex Systems》2015,88(6):155
We analyze the screening of an external Coulomb charge in gapless graphene cone, which is taken as a prototype of a topological defect. In the subcritical regime, the induced charge is calculated using both the Green’s function and the Friedel sum rule. The dependence of the polarization charge on the Coulomb strength obtained from the Green’s function clearly shows the effect of the conical defect and indicates that the critical charge itself depends on the sample topology. Similar analysis using the Friedel sum rule indicates that the two results agree for low values of the Coulomb charge but differ for the higher strengths, especially in the presence of the conical defect. For a given subcritical charge, the transport cross-section has a higher value in the presence of the conical defect. In the supercritical regime we show that the coefficient of the power law tail of polarization charge density can be expressed as a summation of functions which vary log periodically with the distance from the Coulomb impurity. The period of variation depends on the conical defect. In the presence of the conical defect, the Fano resonances begin to appear in the transport cross-section for a lower value of the Coulomb charge. For both sub and supercritical regime we derive the dependence of LDOS on the conical defect. The effects of generalized boundary condition on the physical observables are also discussed. 相似文献