全文获取类型
收费全文 | 1240篇 |
免费 | 198篇 |
国内免费 | 113篇 |
专业分类
化学 | 665篇 |
晶体学 | 17篇 |
力学 | 49篇 |
综合类 | 21篇 |
数学 | 186篇 |
物理学 | 613篇 |
出版年
2023年 | 30篇 |
2022年 | 32篇 |
2021年 | 40篇 |
2020年 | 44篇 |
2019年 | 26篇 |
2018年 | 35篇 |
2017年 | 40篇 |
2016年 | 50篇 |
2015年 | 44篇 |
2014年 | 57篇 |
2013年 | 65篇 |
2012年 | 87篇 |
2011年 | 99篇 |
2010年 | 78篇 |
2009年 | 76篇 |
2008年 | 77篇 |
2007年 | 57篇 |
2006年 | 51篇 |
2005年 | 52篇 |
2004年 | 46篇 |
2003年 | 50篇 |
2002年 | 37篇 |
2001年 | 35篇 |
2000年 | 24篇 |
1999年 | 47篇 |
1998年 | 47篇 |
1997年 | 38篇 |
1996年 | 31篇 |
1995年 | 30篇 |
1994年 | 23篇 |
1993年 | 21篇 |
1992年 | 13篇 |
1991年 | 11篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 11篇 |
1986年 | 14篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 7篇 |
1978年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1551条查询结果,搜索用时 46 毫秒
1.
Meccanica - In gear pair actual alternating meshing process, the comprehensive errors of the transmission system and the thermal elastic deformation of the teeth body cause the gears in the meshing... 相似文献
2.
3.
4.
讨论一类非齐次非线性椭圆边界值问题.利用极大值原理证明了该问题解的梯度估计.作为它的应用得到了解的效率比估计. 相似文献
5.
高能重带电粒子能直接穿透靶原子核外电子层,与原子核发生直接碰撞,发生散裂反应,产生一系列具有放射性的剩余产物核.重带电粒子诱发靶材放射性剩余核与辐射防护和人员安全有着密切联系,当前,大部分剩余核产额主要依靠蒙特卡罗粒子输运程序进行模拟计算,其准确程度亟需通过实验测量进行准确评估.本文利用能量为80.5 MeV/u的(12)^C6+粒子对薄铜靶开展了辐照实验与伽玛射线测量,结合伽玛谱学分析方法,得出了辐照产生的18种放射性剩余产物的初始活度和产生截面值,并与PHITS模拟结果进行对比.结果表明,PHITS模拟程序对放射性剩余核种类的估计具有较高可靠性,在其绝对产额方面,与实验测量仍具有较大偏差. 相似文献
6.
A novel tiled Ti:sapphire(Ti:S)amplifier was experimentally demonstrated with>1 J amplified chirped pulse output.Two Ti:S crystals having dimensions of 14 mm×14 mm×25 mm were tiled as the gain medium in a four-pass amplifier.Maximum output energy of 1.18 J was obtained with 2.75 J pump energy.The energy conversion efficiency of the tiled Ti:S amplifier was comparable with a single Ti:S amplifier.The laser pulse having the maximum peak power of 28 TW was obtained after the compressor.Moreover,the influence of the beam gap on the far field was discussed.This novel tiled Ti:S amplifier technique can provide a potential way for 100 PW or EW lasers in the future. 相似文献
7.
Dr. Hong Shang Yu Gu Prof. Yingbin Wang Dr. Zicheng Zuo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(24):5434-5440
Nonuniform nucleation is one of the major reasons for the dendric growth of metallic lithium, which leads to intractable problems in the efficiency, reversibility, and safety in Li-based batteries. To improve the deposition of metallic Li on Cu substrates, herein, a freestanding current collector (NGDY@CuNW) is formed by coating pyridinic nitrogen-doped graphdiyne (NGDY) nanofilms on 3D Cu nanowires (CuNWs). Theoretical predictions reveal that the introduction of nitrogen atoms in the 2D GDY can enhance the binding energy between the Li atom and GDY, therefore improving the lithiophilicity on the surface for uniform lithium nucleation and deposition. Accordingly, the deposited metallic Li on the NGDY@CuNW electrode exhibits a dendrite-free morphology, resulting in significant improvements in terms of the reversibility with a high coulombic efficiency (CE) and a long lifespan at high current density. Our research provides an efficient method to control the surface property of Cu, which also will be instructive for other metal batteries. 相似文献
8.
Tan Wei Ren Yuanlin Guo Yingbin Liu Yansong Liu Xiaohui Qu Hongqiang 《Cellulose (London, England)》2022,29(12):6941-6962
Cellulose - A novel DOPO derived multi-claw reactive flame retardant (DMCFR) was designed to improve the flame retardancy of lyocell fabric. The chemical structure of DMCFR was identified by proton... 相似文献
9.
Determination of diflubenzuron and chlorbenzuron in fruits by combining acetonitrile‐based extraction with dispersive liquid–liquid microextraction followed by high‐performance liquid chromatography 下载免费PDF全文
In this study, a simple and low‐organic‐solvent‐consuming method combining an acetonitrile‐partitioning extraction procedure followed by “quick, easy, cheap, effective, rugged and safe” cleanup with ionic‐liquid‐based dispersive liquid–liquid microextraction and high‐performance liquid chromatography with diode array detection was developed for the determination of diflubenzuron and chlorbenzuron in grapes and pears. Ionic‐liquid‐based dispersive liquid–liquid microextraction was performed using the ionic liquid 1‐hexyl‐3‐methylimidazolium hexafluorophosphate as the extractive solvent and acetonitrile extract as the dispersive solvent. The main factors influencing the efficiency of the dispersive liquid–liquid microextraction were evaluated, including the extractive solvent type and volume and the dispersive solvent volume. The validation parameters indicated the suitability of the method for routine analyses of benzoylurea insecticides in a large number of samples. The relative recoveries at three spiked levels ranged between 98.6 and 109.3% with relative standard deviations of less than 5.2%. The limit of detection was 0.005 mg/kg for the two insecticides. The proposed method was successfully used for the rapid determination of diflubenzuron and chlorbenzuron residues in real fruit samples. 相似文献
10.
Fuyou Du Lin Sun Xian Zhen Honggang Nie Yanjie Zheng Guihua Ruan Jianping Li 《Analytical and bioanalytical chemistry》2015,407(20):6071-6079
High-internal-phase-emulsion polymers (polyHIPEs) show great promise as solid-phase-extraction (SPE) materials because of the tremendous porosity and highly interconnected framework afforded by the high-internal-phase-emulsion (HIPE) technique. In this work, polyHIPE monolithic columns as novel SPE materials were prepared and applied to trace enrichment of cytokinins (CKs) from complex plant samples. The polyHIPE monoliths were synthesized via the in-situ polymerization of the continuous phase of a HIPE containing styrene (STY) and divinylbenzene (DVB) in a stainless column, and revealed highly efficient and selective enrichment ability for aromatic compounds. Under the optimized experimental conditions, a method using a monolithic polyHIPE column combined with liquid chromatography–electrospray tandem mass spectrometry (LC–MS–MS) was developed for the simultaneous extraction and sensitive determination of trans-zeatin (tZ), meta-topolin (mT), kinetin (K), and kinetin riboside (KR). The proposed method had good linearity, with correlation coefficients (R 2) from 0.9957 to 0.9984, and low detection limits (LODs, S/N?=?3) in the range 2.4–47 pg mL?1 for the four CKs. The method was successfully applied to the determination of CKs in real plant samples, and obtained good recoveries ranging from 68.8 % to 103.0 % and relative standard deviations (RSDs) lower than 16 %. 相似文献