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Journal of Nonlinear Science - We study ray optics in the context of double-mirror systems, in the limit as the two mirrors approach one another (thin films). This leads to a novel set of... 相似文献
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He Zhu Dr. Qiang Chen Dr. Igor Rončević Dr. Kirsten E. Christensen Prof. Harry L. Anderson 《Angewandte Chemie (International ed. in English)》2023,62(31):e202307035
π-Conjugated nanoribbons attract interest because of their unusual electronic structures and charge-transport behavior. Here, we report the synthesis of a series of fully edge-fused porphyrin-anthracene oligomeric ribbons (dimer and trimer), together with a computational study of the corresponding infinite polymer. The porphyrin dimer and trimer were synthesized in high yield, via oxidative cyclodehydrogenation of singly linked precursors, using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and trifluoromethanesulfonic acid (TfOH). The crystal structure of the dimer shows that the central π-system is flat, with a slight S-shaped wave distortion at each porphyrin terminal. The extended π-conjugation causes a dramatic red-shift in the absorption spectra: the absorption maxima of the fused dimer and trimer appear at 1188 nm and 1642 nm, respectively (for the nickel complexes dissolved in toluene). The coordinated metal in the dimer was changed from Ni to Mg, using p-tolylmagnesium bromide, providing access to free-base and Zn complexes. These results open a versatile avenue to longer π-conjugated nanoribbons with integrated metalloporphyrin units. 相似文献
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Majors J. Badgett Barry Boyes Ron Orlando 《Journal of the American Society for Mass Spectrometry》2017,28(5):818-826
Peptides with deamidated asparagine residues and oxidized methionine residues are often not resolved sufficiently to allow quantitation of their native and modified forms using reversed phase (RP) chromatography. The accurate quantitation of these modifications is vital in protein biotherapeutic analysis because they can affect a protein’s function, activity, and stability. We demonstrate here that hydrophilic interaction liquid chromatography (HILIC) adequately and predictably separates peptides with these modifications from their native counterparts. Furthermore, coefficients describing the extent of the hydrophilicity of these modifications have been derived and were incorporated into a previously made peptide retention prediction model that is capable of predicting the retention times of peptides with and without these modifications. 相似文献
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Reut Levi Guy Moshkovitz Dana Ron Ronitt Rubinfeld Asaf Shapira 《Random Structures and Algorithms》2017,50(2):183-200
Constructing a spanning tree of a graph is one of the most basic tasks in graph theory. Motivated by several recent studies of local graph algorithms, we consider the following variant of this problem. Let G be a connected bounded‐degree graph. Given an edge e in G we would like to decide whether e belongs to a connected subgraph consisting of edges (for a prespecified constant ), where the decision for different edges should be consistent with the same subgraph . Can this task be performed by inspecting only a constant number of edges in G ? Our main results are:
- We show that if every t‐vertex subgraph of G has expansion then one can (deterministically) construct a sparse spanning subgraph of G using few inspections. To this end we analyze a “local” version of a famous minimum‐weight spanning tree algorithm.
- We show that the above expansion requirement is sharp even when allowing randomization. To this end we construct a family of 3‐regular graphs of high girth, in which every t‐vertex subgraph has expansion . We prove that for this family of graphs, any local algorithm for the sparse spanning graph problem requires inspecting a number of edges which is proportional to the girth.
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The nucleophilic reaction of sodium cellulosate in the form of membrane or cotton fabric with 2, 4-dinitrohalo-benzenes, 2, 4, 6-trinitrochlorobenzene, 2, 4, 6-trinitrobenzyl bromide, and 2, 4, 6-trinitrostyrene was investigated. The degree of substitution attained with the dinitroaryl derivatives was much higher than that with the trinitroaryl derivatives. The reaction proceeded through Meisen-heimer complexes, which in the case of the trinitro derivatives could be isolated. The ability of the polynitro phenyl ether derivatives of the cellulose to form n- and π-complexes was investigated using naphthalene and p-toluidine. No -π- complex was formed with the former, and the latter gave complexes only with the 2, 4, 6-trinitrobenzyl or -phenethyl cellulose derivatives but not with the trinitrophenyl. The results were explained as due to steric hindrance from the polymeric cellulosic backbone. 相似文献
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Accurate quantification of polymer distributions is one of the main challenges in polymer analysis by liquid chromatography. The response of contemporary detectors is typically influenced by compositional features such as molecular weight, chain composition, end groups, and branching. This renders the accurate quantification of complex polymers of which there are no standards available, extremely challenging. Moreover, any (programmed) change in mobile‐phase composition may further limit the applicability of detection techniques. Current methods often rely on refractive index detection, which is not accurate when dealing with complex samples as the refractive‐index increment is often unknown. We review current and emerging detection methods in liquid chromatography with the aim of identifying detectors, which can be applied to the quantitative analysis of complex polymers. 相似文献
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