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2.
Nonlinear Dynamics - To describe the particular mechanical behaviors of beams with both uniform and non-uniform cross sections, such as the bidirectional bending, torsion-bending coupling, the... 相似文献
3.
First-principles study of the co-effect of carbon doping and oxygen vacancies in ZnO photocatalyst 下载免费PDF全文
Although tuning band structure of optoelectronic semiconductor-based materials by means of doping single defect is an important approach for potential photocatalysis application,C-doping or oxygen vacancy(Vo)as a single defect in ZnO still has limitations for photocatalytic activity.Meanwhile,the influence of co-existence of various defects in ZnO still lacks sufficient studies.Therefore,we investigate the photocatalytic properties of ZnOx C0.0625(x=0.9375,0.875,0.8125),confirming that the co-effect of various defects has a greater enhancement for photocatalytic activity driven by visible-light than the single defect in ZnO.To clarify the underlying mechanism of co-existence of various defects in ZnO,we perform systematically the electronic properties calculations using density functional theory.It is found that the coeffect of C-doping and Vo in ZnO can achieve a more controllable band gap than doping solely in ZnO.Moreover,the impact of the effective masses of ZnOxC0.0625(x=0.9375,0.875,0.8125)is also taken into account.In comparison with heavy Vo concentrations,the light Vo concentration(x=0.875)as the optimal component together with C-doping in ZnO,can significantly improve the visible-light absorption and benefit photocatalytic activity. 相似文献
4.
Qiang Chenxu Hao Yuxin Zhang Wei Li Jinqiang Yang Shaowu Cao Yuteng 《应用数学和力学(英文版)》2021,42(11):1555-1570
Applied Mathematics and Mechanics - The concept of local resonance phononic crystals proposed in recent years provides a new chance for theoretical and technical breakthroughs in the structural... 相似文献
5.
International Journal of Theoretical Physics - We consider the stationary state of a spin-orbit coupled (SOC) binary Bose-Einstein condensates with dipole-dipole interaction (DDI). Our results are... 相似文献
6.
以轻烧白云石粉、氯化铵和二氧化碳为原料,在未使用晶型控制剂的情况下,通过蒸氨-沉钙过程制备出了似立方体状碳酸钙。研究了反应温度、溶液中钙离子浓度、通气速率、搅拌速度以及陈化时间对碳酸钙中方解石相含量以及晶体形貌的影响,并探索了沉钙反应的晶型控制机理。结果表明,在反应温度40 ℃、钙离子浓度0.05 mol/L、通碳速率100 mL/min、搅拌速度400 r/min和陈化时间2 h的条件下,制备出形貌规整、粒径分布均匀的似立方体状碳酸钙,平均粒径为5~10 μm。该研究为提升白云石的使用价值、生产高附加价值的碳酸钙产品,以及提高白云石资源的利用率提供理论基础。 相似文献
7.
针对一线教师在设计硅酸盐材料一课时面对的困难,开发了与陶瓷、玻璃、水泥相对应的石家河红陶杯、洛阳浮法玻璃、白鹤滩大坝等3个教学素材。包含2个原创实验、7个资料、14个原创提问。开发的素材可用于硅酸盐材料高一新授课或以硅酸盐材料为情境的高三复习课中,也可为原创题的命制者提供参考。素材的选择遵循了立德树人的理念,培养了学生的爱国情怀,同时也提升了高级思维能力。 相似文献
8.
结晶动力学能够揭示结晶过程本质,通过测定溶液中Ca2浓度来确定硫酸钙晶须的转化率,从而确定硫酸钙晶须结晶动力学参数,得到转化率与时间的关系式:X=1/{1+e6^[-10.01977t(0.0956-c)+1.1188]},(0≤t≤6.0).研究了影响硫酸钙晶须结晶动力学的影响因素降温速率和陈化时间,利用SEM对制备的硫酸钙晶须进行表征.结果表明:自然冷却条件下,陈化时间6h,制备出的硫酸钙晶须结晶发育完整,晶须平均长径比达到150,平均直径为2.1 μm. 相似文献
9.
Programmed deformations are widespread in nature, providing elegant paradigms to design self‐morphing materials with promising applications in biomedical devices, flexible electronics, soft robotics, etc. In this emerging field, hydrogels are an ideal material to investigate the deformation principle and the structure‐deformation relationship. One crucial step is to construct heterogeneous structures in a facile yet effective way. Herein, we provide a focus review on different deformation modes and corresponding structural features of hydrogels. Photolithography is a versatile approach to control the outer shape of the hydrogel and spatial distribution of the component in the hydrogel, endowing the patterned hydrogels with programmed internal stress and thus controllable deformations. Specifically, cooperative deformations take place in periodically patterned hydrogels with in‐plane gradients, and multiple morphing structures are formed in one patterned hydrogel using selective preswelling to direct the buckling of each unit. The structural control strategy and deformation principles should be applicable to other materials with broad applications in diverse areas. 相似文献
10.
Qiang Wang Qingqing Chen Guoyu Jiang Mengting Xia Mengjiao Wang Yongdong Li Xiaoming Ma Jianguo Wang Xinggui Gu 《中国化学快报》2019,30(11):1965-1968
An AIEgen decorated porphyrin(TPETPyP) was easily obtained through a one-step reaction.The bulky TPE in TPETPyP greatly impeded the intermolecular π-π stacking of the porphyrin core,which significantly suppressed aggregation-caused quenching(ACQ) effect of TPETPyP in aqueous solution.The four pyridinium salts formed in TPETPyP also render the whole molecule water solubility,which eliminated its aggregation.TPETPyP exhibited ~1 O_2 quantum yield as high as 0.85 in PBS.Moreover,it also showed high binding affinity to proteins,the major biotarget of ~1 O_2.The high ~1 O_2 quantum yield plus the great binding ability of TPETPyP toward proteins makes it a highly-efficient protein photocleaving agent.Protein electrophoresis experiments demonstrated that TPETPyP can photocleave BSA upon visible light irradiation,indicating that TPETPy P can act as a promising photosensitizer(PS) in PDT.The work here will provide a facile strategy to utilize AIEgens modified traditional PSs for photodynamic therapy(PDT). 相似文献