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1.
Extraction of cesium-137 from nitric acid medium in the presence of macrocyclic polyethers 总被引:2,自引:0,他引:2
A. Kumar P. K. Mohapatra V. K. Manchanda 《Journal of Radioanalytical and Nuclear Chemistry》1998,229(1-2):169-172
Extraction behavior of137Cs was studied from nitric acid medium using dibenzo 18 crown 6 (DB18C6), 4,4'(5')di-acetylbenzo 18 crown 6 (DAB18C6), 4,
4'(5')di-hexanoylbenzo 18 crown 6 (DHB18C6), 4,4'(5')di-nonanoylbenzo 18 crown 6 (DNB18C6) and 4,4'(5')di-t-butylbenzo 18
crown 6 (DTBB18C6) in nitrobenzene medium. The stoichiometry of the species extracted with dibenzo 18 crown 6 (L) conformed
to ML+. NO3
− TheD
Cs values were found not to be affected by the presence of aluminium nitrate in the aqueous phase. The separation behavior of
fission products obtained from an irradiated natural uranium target was also studied. Presence of 0.004M phosphotungstic acid
found to enhance theD
Cs
values at lower acidities. 相似文献
2.
The extraction behaviour of thorium(IV) from aqueous nitric acid employing 3-phenyl-4-benzoyl-5-isoxazolone (HPBI) in the presence of tri-n-octyl phosphine oxide (TOPO) as well as tri-n-butyl phosphate (TBP) in xylene medium was investigated. The extraction constant (log k(ex)) for the binary organic phase species Th(PBI)(4) was determined to be 8.26 which is by far the largest amongst the corresponding values known for other beta-diketones. The overall extraction constant (log K) for the ternary species Th(PBI)(4) TBP and Th(PBI)(4).2TOPO were estimated to be 14.96 and 20.96 respectively. An inverse correlation of the adduct formation constant (log K(s)) with the pK(a) of the beta-diketones, 2-thenoyltrifluoroacetone, 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone and HPBI, was observed. The steric as well as the electronic effects of adduct formation have been discussed. Analytical application of HPBI for the separation of (234)Th radiotracer from natural uranium (99.3% (238)U) has been suggested. 相似文献
3.
J. P. Shukla V. K. Manchanda M. S. Subramanian 《Journal of Radioanalytical and Nuclear Chemistry》1976,29(1):61-68
A rapid method for the synergistic extraction and spectrophotometric determination of plutonium(VI) in milligram amounts using
a mixture of thenoyltrifluoroacetone (TTA) and tributyl phosphate (TBP) in benzene has been developed. Quantitative extraction
is obtained from aqueous solutions of pH=2 affording separation from many commonly occurring impurities, viz., thorium, fission
products and cladding materials. The precision and accuracy of the method has been found to be∼1%. The study of the solid
product isolated from the extraction system indicates the stoichiometry of the extracted species as PuO2(TTA)2 TBP. 相似文献
4.
A novel chelating polymeric material was synthesized by chemical anchoring of N,N′-dimethyl-N,N′-dibutyl malonamide (DMDBMA) with chloromethylated polystyrene-divinyl benzene polymer. The polymeric material thus prepared was characterized by 13C NMR, FT-IR spectroscopy and CHN elemental analysis. The fabricated polymeric material exhibited superior binding for hexa-valent and tetra-valent metal ions such as U(VI) and Th(IV). Various physico-chemical properties of the functionalized polymer like phase adsorption kinetics, metal sorption mechanism and metal sorption capacity was studied in the static method. Adsorption kinetics studies show that <20 min was sufficient for >99.99% adsorption of Th(IV) and U(VI). The kinetics for adsorption of U(VI) and Th(IV) was found to follow the first order Lagergren rate kinetics. Adsorption of U(VI) on the malonamide functionalized polymer followed the Langmuir adsorption isotherm. The Langmuir monolayer adsorption phenomenon was also confirmed by the theoretical approach calculated based on the adsorption kinetics. The metal sorption capacities for uranium and thorium were found to be 18.78 ± 1.53 mg and 15.74 ± 1.59 mg/g of the chelating polymer at 3 M HNO3, respectively. 相似文献
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8.
Haladhara Naik Guinyun Kim Ashok Goswami Sarbjit Singh Vijay Kumar Manchanda Devesh Raj Srinivasan Ganesan Young Do Oh Hee-Seock Lee Kyung Sook Kim Man-Woo Lee Moo-Hyun Cho In Soo Ko Won Namkung 《Journal of Radioanalytical and Nuclear Chemistry》2010,283(2):439-445
The mass–yield distributions of various fission products have been determined in the 50-, 60- and 70-MeV end point bremsstrahlung induced fission of natPb using off-line γ-ray spectrometric technique in the electron linac at Pohang Accelerator Laboratory, Korea. The mass–yield distributions are symmetric with average mass of 102.34, 102.25 and 102.03 and FWHM of 21, 22 and 23 mass unit, respectively. From the present data and literature data in the 50–85 MeV bremsstrahlung induced fission of 209Bi the following observations were obtained: (i) The average masses of the yield distributions in the 50–85 MeV bremsstrahlung induced fission of natPb and 209Bi are around 102.25 ± 0.25 and 103 ± 0.5, respectively. (ii) The FWHM of the mass–yield distributions increases from about 21 mass units at 50 MeV to 23 mass units at 70–85 MeV, which is explained from the point of increase in multi-chance fission probability with increasing excitation energy. (iii) Within the bremsstrahlung energy range of 50–85 MeV, the role of nuclear structure effect in the mass–yield distribution was observed in the photo-fission of 209Bi, whereas it was not seen in case of natPb. This may be due to the presence of so many isotopes in natPb unlike mono-isotopic 209Bi. 相似文献
9.
S. Chowta P. K. Mohapatra S. C. Tripathi B. S. Tomar V. K. Manchanda 《Journal of Radioanalytical and Nuclear Chemistry》2010,285(2):309-314
Radiochemical results of U isotopes (234U, 235U and 238U) and their activity ratios are reported for well waters as local sources of drinking waters collected from the ten settlements
around the Semipalatinsk Nuclear Test Site (SNTS), Kazakhstan. The results show that 238U varies widely from 3.6 to 356 mBq/L (0.3–28.7 μg/L), with a factor of about 100. The 238U concentrations in some water samples from Dolon, Tailan, Sarzhal and Karaul settlements are comparable to or higher than
the World Health Organization’s restrictive proposed guideline of 15 μg (U)/L. The 234U/238U activity ratios in the measured water samples are higher than 1, and vary between 1.1 and 7.9, being mostly from 1.5 to
3. The measured 235U/238U activity ratios are around 0.046, indicating that U in these well waters is of natural origin. It is probable that the elevated
concentration of 238U found in some settlements around the SNTS is not due to the close-in fallout from nuclear explosions at the SNTS, but rather
to the intensive weathering of rocks including U there. The calculated effective doses to adults resulting from consumption
of the investigated waters are in the range 1.0–18.7 μSv/y. Those doses are lower than WHO and IAEA reference value (100 μSv/y)
for drinking water. 相似文献
10.
H. Naik P. M. Prajapati S. V. Suryanarayana P. N. Pathak D. R. Prabhu V. Chavan D. Raj P. C. Kalsi A. Goswami S. Ganesan V. K. Manchanda 《The European Physical Journal A - Hadrons and Nuclei》2011,47(8):1-5
The νp process is a primary nucleosynthesis process which occurs in core-collapse supernovae. An essential role in this process is being played by electron antineutrinos. They generate, by absorption on protons, a supply of neutrons which, by (n, p) reactions, allow to overcome waiting point nuclei with rather long beta-decay and proton-capture lifetimes. The synthesis of heavy elements by the νp process depends sensitively on the $\bar \nu _e$ luminosity and spectrum. As has been shown recently, the latter are affected by collective neutrino flavor oscillations which can swap the $\bar \nu _e$ and $\bar \nu _{\mu ,\tau }$ spectra above a certain split energy. Assuming such a swap scenario, we have studied the impact of collective neutrino flavor oscillations on the νp-process nucleosynthesis. Our results show that the production of light p-nuclei up to mass number A = 108 is very sensitive to collective neutrino oscillations. 相似文献