首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   11904篇
  免费   2138篇
  国内免费   1602篇
化学   8680篇
晶体学   108篇
力学   809篇
综合类   113篇
数学   1228篇
物理学   4706篇
  2024年   8篇
  2023年   218篇
  2022年   226篇
  2021年   353篇
  2020年   530篇
  2019年   512篇
  2018年   367篇
  2017年   375篇
  2016年   575篇
  2015年   573篇
  2014年   656篇
  2013年   855篇
  2012年   1045篇
  2011年   1138篇
  2010年   779篇
  2009年   790篇
  2008年   860篇
  2007年   777篇
  2006年   744篇
  2005年   651篇
  2004年   477篇
  2003年   397篇
  2002年   388篇
  2001年   322篇
  2000年   268篇
  1999年   226篇
  1998年   194篇
  1997年   167篇
  1996年   187篇
  1995年   172篇
  1994年   143篇
  1993年   125篇
  1992年   105篇
  1991年   115篇
  1990年   86篇
  1989年   80篇
  1988年   50篇
  1987年   24篇
  1986年   25篇
  1985年   8篇
  1984年   16篇
  1983年   7篇
  1982年   10篇
  1981年   4篇
  1979年   2篇
  1977年   2篇
  1976年   2篇
  1974年   2篇
  1971年   2篇
  1966年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Zhang  Lei  Xu  Chao  Guo  Yaohao  Zhu  Guangpu  Cai  Shiyu  Wang  Xin  Jing  Wenlong  Sun  Hai  Yang  Yongfei  Yao  Jun 《Transport in Porous Media》2021,140(3):713-725
Transport in Porous Media - Pore scale immiscible displacement is crucial in oil industry. The surface roughness of throat is an important factor affecting water–oil interface movement. In...  相似文献   
2.
本文制备了三种在1,4-bis[2-(4-pyridyl)ethenyl]-benzene(bp-eb)上接枝不同烷基链长度的热致变色材料DC8、DC12、DC16. 在365 nm激发光下,随着温度升高,它们呈现出荧光颜色的改变,这种改变来自于晶体态与无定形态之间的转变. 此外,DC16也呈现出光致变色的性质. 通过差示扫描量热法测试得到的相转变温度高于实验过程中荧光颜色改变时的温度. 因此,这种变色行为来自于光与热共同作用的结果. 乙醇可以使粉末变回起始的晶体状态,从而使荧光颜色恢复,实现热致变色行为的可逆. 本研究对理解热致变色分子的结构-性质关系,指导热致变色分子设计具有重要意义.  相似文献   
3.
本文选用混杂的B3LYP密度泛函理论方法,在Lanl2dz水平上,对5,15-二(二茂铁基)-卟啉酞菁钇[Por(Fc)2]Y(Pc)的结构进行了优化,结果表明,5,15-二(二茂铁基)-卟啉酞菁钇呈现出三明治型构型,卟啉环与酞菁环呈穹型围绕在金属钇原子周围。对分子内主要的键长与键角进行了理论计算,通过频率计算,得到了5,15-二(二茂铁基)-卟啉酞菁钇[Por(Fc)2]Y(Pc)的红外光谱图,与实验所得的红外光谱图进行比对,将理论计算和实验所得的光谱主要振动峰进行了线性回归拟合,相关系数为0.992,标准偏差为16.96。理论计算与实验所获得的红外光谱图基本一致,说明本文所选用的DFT理论计算方法是可行的。通过GaussView软件对5,15-二(二茂铁基)-卟啉酞菁钇的红外谱带简正振动模式进行了指认。此外,分析讨论了5,15-二(二茂铁基)-卟啉酞菁钇[Por(Fc)2]Y(Pc)的分子静电势,确定了极大值与极小值的位置。对于研究5,15-二(二茂铁基)-卟啉酞菁钇分子的性质,提供了相应的理论基础。  相似文献   
4.
Denote a semisimple Banach algebra with an identity e by A.This paper studies the Fredholm,Weyl and Browder spectral theories in a semisimple Banach algebra,and meanwhile considers the properties of the Fredholm element,the Weyl element and the Browder element.Further,for a∈A,we give the Weyl's theorem and the Browder's theorem for a,and characterize necessary and sufficient conditions that both a and f(a) satisfy the Weyl's theorem or the Browder's theorem,where f is a complex-valued function analytic on a neighborhood of σ(a).In addition,the perturbations of the Weyl's theorem and the Browder's theorem are investigated.  相似文献   
5.
The ability of the radial basis function(RBF) approach to extrapolate the masses of nuclei in neutron-rich and superheavy regions is investigated in combination with the Duflo-Zuker(DZ31), Hartree–Fock-Bogoliubov(HFB27), finite-range droplet model(FRDM12) and Weizs?cker-Skyrme(WS4) mass models. It is found that when the RBF approach is employed with a simple linear basis function, different mass models have different performances in extrapolating nuclear masses in the same region, and a single mass model may have different performances when it is used to extrapolate nuclear masses in different regions. The WS4 and FRDM12 models(two macroscopic–microscopic mass models), combined with the RBF approach, may perform better when extrapolating the nuclear mass in the neutron-rich and superheavy regions.  相似文献   
6.
Liu  Yi-Huan  Yuan  Xin  Wu  Jia-Qi  Luo  Ming-Xuan  Hu  Xin  Zhu  Ning  Guo  Kai 《高分子科学》2022,40(5):456-461
Chinese Journal of Polymer Science - The emerging chemical recyclable polymers, such as poly(γ-butyrolactone) (PGBL) and poly((R)-3,4-trans six-membered ring-fused GBL) (P((R)-M)), provide a...  相似文献   
7.
Ning  Zuozhou  Zhang  Zhicheng  Yan  Qingsong  Zhou  Naifu  Wen  Linzi  Peng  Xichao  Tang  Yu  Feng  Pengju 《中国科学:化学(英文版)》2022,65(10):1962-1967
Science China Chemistry - A mild and practical protocol for selectively time-dependent dehydrogenative C-C coupling, as well as tandem coupling-cyclization reaction between indoles or/and other...  相似文献   
8.
The commonly used multi-center initiation methods always lead to the formation of quantities of homopolymer in the surface tailoring based on reverse atom transfer radical polymerization (ATRP) and reversible addition-fragmentation chain-transfer (RAFT) polymerization. In this study, a monocenter redox pair constructed of silica bearing tert-butyl hydroperoxide groups and ascorbic acid (SiO2-TBHP/AsAc) was applied to substitute the commonly used initiation method of R-supported RAFT grafting polymerization. All the propagating radicals were restricted on the surface of solid particles during the whole procedure theoretically, resulting in a higher grafting efficiency of 95.1% combined with the “controllable” feature at 10 h. This redox pair was also used to initiate the reverse ATRP in miniemulsion successfully with a grafting efficiency of 86.3% at 10 h. The grafting efficiency obtained under this monocenter initiation method was significantly higher than that of the frequently reported surface modification by reverse ATRP and RAFT polymerization. In addition, the high-efficient surface tailoring was traced and confirmed by nuclear magnetic resonance, Fourier transform infrared, X-ray photoelectron spectroscopy, thermogravimetric analysis, transmission electron microscopy, and other analysis tests. The advantage of this monocenter redox pair will open a new avenue for the potential “high-efficient” surface tailoring of various materials.  相似文献   
9.
We generalize the Heisenberg star consisting of a spin-1/2 central spin and a homogeneously coupled spin bath modeled by the XXX ring [Richter J and Voigt A 1994 J. Phys. A: Math. Gen. 27 1139-1149] to the case of arbitrary central-spin size S < N/2, where N is the number of bath spins. We describe how to block-diagonalize the model based on the Bethe ansatz solution of the XXX ring, with the dimension of each block Hamiltonian ≤ 2S + 1. We obtain all the eigenenergies and explicit expressions of the sub-ground states in each l-subspace with l being the total angular momentum of the bath. Both the eigenenergies and the sub-ground states have distinct structures depending whether Sl or l < S. The absolute ground-state energy and the corresponding l as functions of the intrabath coupling are numerically calculated for N = 16 and S = 1, 2, ⋯ ,7 and their behaviors are quantitatively explained in the weak and strong intrabath coupling limits. We then study the dynamics of the antiferromagnetic order within an XXX bath prepared in the Néel state. Effects of the initial state of the central spin, the value of S, and the system-bath coupling strength on the staggered magnetization dynamics are investigated. By including a Zeeman term for the central spin and the anisotropy in the intrabath coupling, we also study the polarization dynamics of the central spin for a bath prepared in the spin coherent state. Under the resonant condition and at the isotropic point of the bath, the polarization dynamics for S > 1/2 exhibit collapse-revival behaviors with fine structures. However, the collapse-revival phenomena are found to be fragile with respect to the anisotropy of the intrabath coupling.  相似文献   
10.
研究了一类特殊情形m=1的重心权Hermite有理插值,证明了该插值函数的二阶导数r1?x在插值节点和非插值节点处分别以Oh2d-1Oh2d-3的速度收敛于函数f?x。数值例子进一步验证了方法的有效性。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号