全文获取类型
收费全文 | 906篇 |
免费 | 14篇 |
国内免费 | 9篇 |
专业分类
化学 | 285篇 |
晶体学 | 2篇 |
力学 | 16篇 |
数学 | 307篇 |
物理学 | 319篇 |
出版年
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 13篇 |
2017年 | 14篇 |
2016年 | 21篇 |
2015年 | 9篇 |
2014年 | 18篇 |
2013年 | 42篇 |
2012年 | 33篇 |
2011年 | 36篇 |
2010年 | 22篇 |
2009年 | 14篇 |
2008年 | 30篇 |
2007年 | 36篇 |
2006年 | 47篇 |
2005年 | 44篇 |
2004年 | 27篇 |
2003年 | 29篇 |
2002年 | 23篇 |
2001年 | 7篇 |
2000年 | 16篇 |
1999年 | 13篇 |
1998年 | 8篇 |
1997年 | 12篇 |
1996年 | 20篇 |
1995年 | 15篇 |
1994年 | 21篇 |
1993年 | 19篇 |
1992年 | 23篇 |
1991年 | 13篇 |
1990年 | 21篇 |
1989年 | 15篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1986年 | 13篇 |
1985年 | 19篇 |
1984年 | 21篇 |
1983年 | 13篇 |
1982年 | 18篇 |
1981年 | 16篇 |
1980年 | 10篇 |
1979年 | 15篇 |
1978年 | 10篇 |
1977年 | 11篇 |
1976年 | 8篇 |
1975年 | 15篇 |
1974年 | 11篇 |
1973年 | 7篇 |
1972年 | 4篇 |
1967年 | 5篇 |
排序方式: 共有929条查询结果,搜索用时 109 毫秒
1.
The Note is concerned with a feasibility study of time reversal in a non-homogeneous elastic medium, from data recorded in an acoustic medium. Our aim here is to determine the presence and some physical properties of elastic “inclusions” (unknown, not observable solid objects, characterized by their elastic properties) from partial observations of acoustic waves scattered by these inclusions. A finite element numerical method, based on a variational acousto-elastodynamics formulation, is derived and used to solve the forward, and then, the time-reversed problem. A criterion, derived from the reverse time migration framework, is introduced, to help construct images of the inclusions to be determined. Numerical illustrations on configurations that mimic the breast cancer configuration are proposed, and show that one can differentiate between two inclusions, even with different properties. 相似文献
2.
3.
Victor Oxman Moshe Stupel 《International Journal of Mathematical Education in Science & Technology》2018,49(3):442-455
A geometrical task is presented with multiple solutions using different methods, in order to show the connection between various branches of mathematics and to highlight the importance of providing the students with an extensive ‘mathematical toolbox’. Investigation of the property that appears in the task was carried out using a computerized tool. 相似文献
4.
Neil Rosenfeld Chih-Gang Chao Christopher B. Watson Manyam P. Kumar Sherzod T. Madrahimov David E. Bergbreiter 《Journal of polymer science. Part A, Polymer chemistry》2020,58(8):1144-1152
Covalent and noncovalent chemical methods that use oligomeric lipophilic agents to solubilize silica nanoparticles in heptane and poly(α-olefin) (EPAO) solvents are described. While only modest solubilization efficiencies are seen with an octadecyl group, a variety of terminally functionalized polyisobutylene (PIB) derivatives are more efficient. Both covalent and noncovalent chemistry was found to be effective. Covalent modification solubilized up to 34 wt% of silica nanoparticles (SiNPs) as stable solutions in heptane or PAOs. Noncovalent modification was however more effective, solubilizing up to 70% of SiNPs in heptane or PAOs. The most successful covalent approach used PIB oligomers containing terminal triethoxysilane groups to covalently modify SiNPs. Alternatively, SiNPs that were first functionalized with amine groups could be solubilized in heptane or PAOs with polyisobutylene containing sulfonic acid groups using acid–base chemistry. Studies of these and other solubilization chemistry was also carried out using fluorescent labels, studies that confirmed the gravimetric analyses of the heptane-solubilized SiNPs. Transmission electron microscopy of a PAO solution of these solutions showed that these SiNPs were present as small aggregates dispersed in the PAOs. 相似文献
5.
Mechanistic Insight into the Stereochemical Control of Lactide Polymerization by Salan–Aluminum Catalysts 下载免费PDF全文
Konstantin Press Prof. Israel Goldberg Prof. Moshe Kol 《Angewandte Chemie (International ed. in English)》2015,54(49):14858-14861
Alkyl aluminum complexes of chiral salan ligands assembled around the 2,2′‐bipyrrolidine core form as single diastereomers that have identical configurations of the N donors. Active catalysts for the polymerization of lactide were formed upon the addition of benzyl alcohol. Polymeryl exchange between enantiomorphous aluminum species had a dramatic effect on the tacticity of the poly(lactic acid) (PLA) in the polymerization of racemic lactide (rac‐LA): The enantiomerically pure catalyst of the nonsubstituted salan ligand led to isotactic PLA, and the racemic catalyst exhibited lower stereocontrol. The enantiomerically pure catalyst of the chloro‐substituted salan ligand led to PLA with a slight tendency toward heterotacticity, whereas the racemic catalyst led to PLA of almost perfect heterotacticity following an insertion/auto‐inhibition/exchange mechanism. 相似文献
6.
Moshe Stupel Victor Oxman Avi Sigler 《International Journal of Mathematical Education in Science & Technology》2017,48(1):149-161
We present a geometrical investigation of the process of creating an infinite sequence of triangles inscribed in a circle, whose areas, perimeters and lengths of radii of the inscribed circles tend to a limit in a monotonous manner.First, using geometrical software, we investigate four theorems that represent interesting geometrical properties, after which we present formal proofs that rest on a combination between different fields of mathematics: trigonometry, algebra and geometry, and the use of the concept of standard deviation that is taken from statistics. 相似文献
7.
Comparison of phantom materials for use in quality assurance of microbeam radiation therapy 下载免费PDF全文
Matthew Cameron Iwan Cornelius Dean Cutajar Jeremy Davis Anatoly Rosenfeld Michael Lerch Susanna Guatelli 《Journal of synchrotron radiation》2017,24(4):866-876
Microbeam radiation therapy (MRT) is a promising radiotherapy modality that uses arrays of spatially fractionated micrometre‐sized beams of synchrotron radiation to irradiate tumours. Routine dosimetry quality assurance (QA) prior to treatment is necessary to identify any changes in beam condition from the treatment plan, and is undertaken using solid homogeneous phantoms. Solid phantoms are designed for, and routinely used in, megavoltage X‐ray beam radiation therapy. These solid phantoms are not necessarily designed to be water‐equivalent at low X‐ray energies, and therefore may not be suitable for MRT QA. This work quantitatively determines the most appropriate solid phantom to use in dosimetric MRT QA. Simulated dose profiles of various phantom materials were compared with those calculated in water under the same conditions. The phantoms under consideration were RMI457 Solid Water (Gammex‐RMI, Middleton, WI, USA), Plastic Water (CIRS, Norfolk, VA, USA), Plastic Water DT (CIRS, Norfolk, VA, USA), PAGAT (CIRS, Norfolk, VA, USA), RW3 Solid Phantom (PTW Freiburg, Freiburg, Germany), PMMA, Virtual Water (Med‐Cal, Verona, WI, USA) and Perspex. RMI457 Solid Water and Virtual Water were found to be the best approximations for water in MRT dosimetry (within ±3% deviation in peak and 6% in valley). RW3 and Plastic Water DT approximate the relative dose distribution in water (within ±3% deviation in the peak and 5% in the valley). PAGAT, PMMA, Perspex and Plastic Water are not recommended to be used as phantoms for MRT QA, due to dosimetric discrepancies greater than 5%. 相似文献
8.
Ad Cohen Geoffrey W. Coates Moshe Kol 《Journal of polymer science. Part A, Polymer chemistry》2013,51(3):593-600
The activities of C1‐symmetric dibenzyl zirconium complexes of Salan ligands that bear a halo‐substituted phenolate ring and an alkyl‐substituted phenolate ring in propylene polymerization with methylaluminoxane as cocatalyst were studied. These {ONNO′}ZrBn2‐type catalysts exhibited moderate‐to‐high activities and yielded polypropylene of low molecular weight. The degree of tacticity was found to depend on the steric bulk of the substituents on both phenolate rings and ranged from practically atactic to substantially isotactic (74–78% [mmmm] for polymerizations at room temperature by Lig5ZrBn2). Hemi‐isotactic polypropylene was not obtained, despite the diastereotopicity of the two positions. The pattern of stereo errors was consistent with the enantiomorphic site control of propylene insertion typically observed for C2‐symmetric catalysts and implied a facile site‐averaging mechanism. A regular 1,2‐insertion and a β‐H transfer to an incoming monomer correspond to the main propagation and termination processes, respectively. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
9.
Moshe Goldberg Robert Guralnick W. A. J. Luxemburg 《Linear and Multilinear Algebra》2013,61(2):209-219
In this paper we continue our study of stability properties of subnorms on subsets of finite-dimensional, power-associative algebras over the real or the complex numbers. 相似文献
10.
In this paper we investigate spectral matrices, i.e., matrices with equal spectral and numerical radii. Various characterizations and properties of these matrices are given. 相似文献