Electroosmosis modulated peristaltic biorheological flow through an asymmetric microchannel: mathematical model

A theoretical study is presented of peristaltic hydrodynamics of an aqueous electrolytic non-Newtonian Jeffrey bio-rheological fluid through an asymmetric microchannel under an applied axial electric field. An analytical approach is adopted to obtain the closed form solution for velocity, volumetric flow, pressure difference and stream function. The analysis is also restricted under the low Reynolds number assumption (Stokes flow) and lubrication theory approximations (large wavelength). Small ionic Peclét number and Debye–Hückel linearization (i.e. wall zeta potential ≤ 25 mV) are also considered to simplify the Nernst–Planck and Poisson–Boltzmann equations. Streamline plots are also presented for the different electro-osmotic parameter, varying magnitudes of the electric field (both aiding and opposing cases) and for different values of the ratio of relaxation to retardation time parameter. Comparisons are also included between the Newtonian and general non-Newtonian Jeffrey fluid cases. The results presented here may be of fundamental interest towards designing lab-on-a-chip devices for flow mixing, cell manipulation, micro-scale pumps etc. Trapping is shown to be more sensitive to an electric field (aiding, opposing and neutral) rather than the electro-osmotic parameter and viscoelastic relaxation to retardation ratio parameter. The results may also help towards the design of organ-on-a-chip like devices for better drug design.     

Effect of rotation in magneto-thermoelastic transversely isotropic hollow cylinder with three-phase-lag model

This article deals with the various heat source responses in a transversely isotropic hollow cylinder under the purview of three-phase-lag (TPL) generalized thermoelasticity theory. In presence of magnetic field and due to the rotating behavior of the cylinder, the governing equations are redefined for generalized thermoelasticity with thermal time delay. In order to obtain the stress, displacement and temperature field, the field functions are expressed in terms of modified Bessel functions in Laplace transformed domain. When the outer radius of hollow cylinder tends to infinity, the corresponding results are discussed. Finally an appropriate Laplace transform inversion technique is adopted.     

Path to achieving molecular dispersion in a dense reactive mixture

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multicomponents. In this study, we have examined the role of plasticizer in the reaction of two seemingly unlikely reactants: a highly crystalline hexamethylenetetramine (HMTA) and a strongly hydrogen bonded phenol formaldehyde resin. By combining information from NMR, infrared spectroscopy and differential scanning calorimetry, we were able to determine the role of specific intermolecular interactions necessary for the plasticizer to dissolve the highly crystalline HMTA and to plasticize the phenol formaldehyde resin in this crosslinking reaction. The presence of the plasticizer increased the segmental mobility, disrupted the hydrogen bonded matrix, and freed the hydroxyl units, which further increased the solubility of the HMTA. Both the endothermic and exothermic transitions are accounted for in the calorimetric data obtained. For the first time, it is possible to obtain the effective molar ratio of each component needed to complete the crosslinking reaction efficiently. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1519–1526     

Palladium(II)-catalyzed intramolecular aminoacetoxylation of sugar derived alkenyl tosylsulfonamide: Total synthesis of l-deoxyallonojirimycin

Palladium catalyzed intramolecular aminoacetoxylation of d-ribose derived alkenyl tosylsulfonamide to deliver l-deoxyallonojirimycin in an overall yield of 19%. The preliminary screening of l-deoxyallonojirimycin against carbohydrate processing enzymes showed moderate inhibitory activity against α-glucosidase (yeast) and α-mannosidases.     

A Review of Bacteriochlorophyllides: Chemical Structures and Applications

Generally, bacteriochlorophyllides were responsible for the photosynthesis in bacteria. Seven types of bacteriochlorophyllides have been disclosed. Bacteriochlorophyllides a/b/g could be synthesized from divinyl chlorophyllide a. The other bacteriochlorophyllides c/d/e/f could be synthesized from chlorophyllide a. The chemical structure and synthetic route of bacteriochlorophyllides were summarized in this review. Furthermore, the potential applications of bacteriochlorophyllides in photosensitizers, immunosensors, influence on bacteriochlorophyll aggregation, dye-sensitized solar cell, heme synthesis and for light energy harvesting simulation were discussed.     

A bis(rhodamine 6G)-based fluorescent sensor for Hg2+: microwave-assisted synthesis,photophysical properties,and computational studies

A fluorescent and colorimetric sensor based on rhodamine 6 g (RD6g) was designed, synthesized, and characterized using microwave irradiation. The sensing behavior of this compound was studied by UV–visible and fluorescence spectroscopy. Sensor RD6g exhibits a high selectivity and an excellent sensitivity and is a dual-responsive colorimetric and fluorescent Hg²⁺-specific sensor in aqueous buffer solution. Mercury ions give rise to the development of a very fluorescent ring-open amide spirolactam system. The detection limit for Hg²⁺ was found to be 1.2?×?10^?8 M. The binding ratio of RD6g-Hg²⁺ complex was determined to be 1:1 according to the Job’s plot. The reversibility of RD6g?Hg²⁺ complex has been achieved with CN^? anions. The test strip based on RD6g was developed, which could be used as a suitable and methodical Hg²⁺ test kit.

     

Averaging methods for numerical simulations of flows through heterogeneous porous media

Many natural rock systems contain small patches of different permeability which affect the flow of fluids through them. As these heterogeneities become smaller and more numerous, they become harder to model numerically. We consider how to reduce the computational effort required in simulations by incorporating their effects in the boundary conditions at the edges of each grid block. This is in contrast with current methods which involve often arbitrary changes in the fluid properties. The method is restricted to the case of widely-spaced patches, which simplifies interaction effects. The system then reduces to an array of dipoles, and two averaging methods are proposed for finite grid blocks. Several infinite systems, including vertical and horizontal bands, are also considered as further approximations. There is a great wealth of existing results from different fields which lead to identical mathematical problems and which can be used in these cases. Finally, we consider how to use these techniques when the precise configuration of the grid block is not known, but only its statistical properties. This can lead to results which are very different from the deterministic case.     

The formation of a liquid bridge during the coalescence of drops

This paper examines a mathematical model for the coalescence of two viscous liquid volumes in an inviscid gas or in a vacuum which removes the pressure singularity at the instant of impact inherent in the classical formulation of the continuum model. The very early stages of coalescence are examined in order to study the formation of the liquid bridge in two cases: (i) for two infinitely long, coalescing liquid cylinders; and (ii) for two coalescing spheres. Numerical solutions are computed for the velocity and pressure fields in the flow in both cases, and they confirm the removal of the pressure singularity. Also, the free-surface position at small times is determined.     

Natural convection in a partitioned enclosure heated from below

Cubic spline collection numerical method has been developed to determine two dimensional natural convection in a partitioned enclosure heated from below. The both sides of impermeable partition are considered to have continuity in heat flux and temperatures. The governing equations are solved with aid of the SADI procedure. Parametric studies of the effects of the partition and Rayleigh number on the fluid flow and temperature fields have been performed. Results show that the location of the partition and Rayleigh number have a significant influence on the flow and heat transfer characteristics.

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Freie Konvektion in einem von unten beheizten, unterteiltem Hohlraum

Zusammenfassung Eine numerische dreidimensionale SplineMethode zur Berechnung der zweidimensionalen Naturkonvektion in einem von unten beheizten, unterteiltem Hohlraum wird vorgestellt. Der Wärmestrom und die Temperatur auf beiden Seiten der undurchlässigen Trennwand werden als konstant betrachtet. Mit Hilfe der SADI-Prozedur werden die beschreibenden Gleichungen gelöst. Über den Einfluß der Unterteilung und der Rayleigh-Zahl auf die Strömung des Fluids und das Temperaturfeld wird eine Parameter-Studie durchgeführt. Die Ergebnisse zeigen, daß die Anordnung der Unterteilung und die Rayleigh-Zahl einen entscheidenden Einfluß auf das Wärmeübertragungsverhalten haben.

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Nomenclature A aspect ratio=L/H - g gravitational acceleration - H enclosure height - H₁ distance between the top wall of enclosure and the partition - H₂ distance between the bottom wall of enclosure and the partition - k thermal conductivity of fluid - L enclosure length - m number of vertical grid lines - n number of horizontal grid lines - Nu Nusselt number - P pressure - Pr Prandtl number - Q heat transfer across enclosure - Ra Rayleigh number based onH - t time - T dimensional temperature - T _H temperature of warm horizontal wall - T _L temperature of cold horizontal wall - T ₀ average temperature=T(_H+T_L)/2 - T temperature difference between the hot and cold wall =T _H–T_L - u, U dimensional and dimensionless horizontal velocity - , V dimensional and dimensionless vertical velocity - x, X dimensional and dimensionless horizontal coordinate - y, Y dimensional and dimensionless vertical coordinate - fluid thermal diffusivity - coefficient of thermal expansion - viscosity - kinematic viscosity=/g9 - density - , dimensional and dimensionless stream function - dimensionless temperature - , dimensional and dimensionless vorticity - dimensionless time